武汉理工大学学报-材料科学版(英文版), 2008, 23(6): 893-900. doi: 10.1007/s11595-007-6893-1
1, , 2, , 3, {"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以自制的六(4-羟基苯氧基)环三磷腈(Ⅰ)、苯胺、甲醛为原料,甲苯为溶剂合成了高支化环三磷腈型苯并(噁)嗪(Ⅱ),收率68.9％.采用傅里叶变换红外光谱、核磁氢谱、差示扫描量热法、热重分析、极限氧指数(LOI)和水平-垂直燃烧试验对(Ⅱ)及其固化物(Ⅲ)的结构和性能进行了表征,并对比了其与传统苯并(噁)嗪的热性能与阻燃性能.结果表明,(Ⅱ)的开环聚合起始温度为186.0℃,峰值温度为235.4℃,具有比传统苯并(噁)嗪更低的开环聚合起始温度;(Ⅲ)的5％和10％热失重温度分别为344.1℃和392.7℃,800℃残炭率为64.97％,LOI值可达43.5％,UL-94等级为V-0,具有比传统苯并(噁)嗪更为优异的热稳定性和阻燃性,可应用于阻燃要求较高的场合.","authors":[{"authorName":"柏帆","id":"28c846f6-6f70-4bed-a400-375c914fad98","originalAuthorName":"柏帆"},{"authorName":"黄杰","id":"6e5e274d-3bea-4911-9efe-c5b52cacc1c4","originalAuthorName":"黄杰"},{"authorName":"支肖琼","id":"becf8910-58f1-446b-9203-8e010619a719","originalAuthorName":"支肖琼"},{"authorName":"马寒冰","id":"dfaed6e8-a238-49ba-86ec-68772c843566","originalAuthorName":"马寒冰"},{"authorName":"唐安斌","id":"0877eae5-3dca-4e1d-a8db-0013c40f1013","originalAuthorName":"唐安斌"}],"doi":"10.16865/j.cnki.1000-7555.2016.05.007","fpage":"33","id":"46d29e69-0f92-4f2f-a493-d2e0891b2fd1","issue":"5","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"93f9bc64-12a5-420a-8833-5515efe468ca","keyword":"环三磷腈","originalKeyword":"环三磷腈"},{"id":"aff518e0-48b0-474c-8c99-a21a4519801a","keyword":"苯并(噁)嗪","originalKeyword":"苯并(噁)嗪"},{"id":"8e928311-eb10-4d1e-80a6-141a692dea43","keyword":"热性能","originalKeyword":"热性能"},{"id":"ec3effe1-97a3-4060-9362-0d868a311fde","keyword":"阻燃","originalKeyword":"阻燃"}],"language":"zh","publisherId":"gfzclkxygc201605007","title":"高支化环三磷腈型苯并(噁)嗪的合成表征及性能","volume":"32","year":"2016"},{"abstractinfo":"以六氯环三磷腈(HCCP)、苯酚和2-烯丙基苯酚为原料,合成了新型含烯丙基的环磷腈阻燃单体(2-烯丙基苯氧基)五苯氧基环三磷腈(APPCP),用红外光谱、核磁氢谱、质谱和元素分析表征其组成和结构.将APPCP与丙烯酸酯单体共聚制备了阻燃丙烯酸酯树脂,测试了共聚丙烯酸酯树脂的热稳定性和阻燃性,当APPCP用量为20％时,共聚丙烯酸酯树脂燃烧等级(UL-94)可达Ⅴ-0级,极限氧指数(LOI)高达31.2％,在空气中600℃时残留质量提高至23.2％.","authors":[{"authorName":"元东海","id":"b19342f6-f3f9-4931-996d-b20af5d7c00c","originalAuthorName":"元东海"},{"authorName":"唐安斌","id":"5fa355e5-01d0-4544-a063-35cefa97d0da","originalAuthorName":"唐安斌"},{"authorName":"黄杰","id":"9c559279-4e00-424f-bb48-b40c679c92c1","originalAuthorName":"黄杰"},{"authorName":"马寒冰","id":"441614b5-ae8b-492c-8934-26399e73b44f","originalAuthorName":"马寒冰"}],"doi":"10.3724/SP.J.1095.2012.00464","fpage":"1090","id":"13027efd-48ca-4ab7-9a78-ab6895f64714","issue":"9","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"7ead949e-451a-4e7c-8499-155718ff89c9","keyword":"环三磷腈","originalKeyword":"环三磷腈"},{"id":"bb24d7c6-b8bd-4a3d-8d2f-0d2bd8eb2d3c","keyword":"阻燃","originalKeyword":"阻燃"},{"id":"ef7d8aec-4286-4253-a87b-761db90f26a1","keyword":"丙烯酸酯","originalKeyword":"丙烯酸酯"},{"id":"b6215973-69db-47cb-9fd3-4178c82259f4","keyword":"共聚","originalKeyword":"共聚"}],"language":"zh","publisherId":"yyhx201209021","title":"含烯丙基六苯氧基环三磷腈的合成及其在阻燃丙烯酸酯树脂中的应用","volume":"29","year":"2012"},{"abstractinfo":"以自制的六(4-羟基苯氧基)环三磷腈(Ⅰ)、苯胺、甲醛为原料合成了高支化环三磷腈型苯并噁嗪(Ⅱ),采用红外光谱、差示扫描量热分析(DSC)、热失重分析(TGA)对Ⅱ进行了表征,并制备了苯并噁嗪树脂玻璃布层压板.结果表明:由Ⅱ阻燃改性的层压板的综合性能优于由氢氧化铝(ATH)和六苯氧基环三磷腈(HPCTP)阻燃改性的层压板,当Ⅱ的添加量为10％时,层压板的燃烧等级达到UL 94 V-0级,热态弯曲强度达到610 MPa,平行层向冲击强度达到98.3 kJ/m2,介电常数和介质损耗因数分别为3.97和0.009 8,5％热失重温度和800℃残炭率分别为407.1℃和82.61％.","authors":[{"authorName":"柏帆","id":"8357d11e-9025-4cd0-b93d-3f9137f55670","originalAuthorName":"柏帆"},{"authorName":"黄杰","id":"58efce4b-b1f1-4ffc-bbcc-73658b9a0bb1","originalAuthorName":"黄杰"},{"authorName":"支肖琼","id":"b183c048-6dd9-4d52-bd13-aee7fc565038","originalAuthorName":"支肖琼"},{"authorName":"李秀云","id":"a265bf9a-26e3-4e47-ba81-f84e48806aae","originalAuthorName":"李秀云"},{"authorName":"唐安斌","id":"730a7cfb-77fa-4845-8942-d3e6cb9f6afb","originalAuthorName":"唐安斌"}],"doi":"10.16790/j.cnki.1009-9239.im.2016.08.007","fpage":"35","id":"8986fbab-4167-4f64-a734-973ce23b5b3c","issue":"8","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"9522b5c9-c21b-406a-9096-9973c8b68497","keyword":"环三磷腈","originalKeyword":"环三磷腈"},{"id":"33ea8c49-ae52-48ba-af29-d2850d3f093c","keyword":"苯并噁嗪","originalKeyword":"苯并噁嗪"},{"id":"2f58e840-02ce-4789-aa60-e957ea5ac604","keyword":"玻璃布层压板","originalKeyword":"玻璃布层压板"},{"id":"f2cda0f5-d9d1-4b24-ae39-7530f9ffb3aa","keyword":"无卤阻燃","originalKeyword":"无卤阻燃"}],"language":"zh","publisherId":"jycltx201608007","title":"新型含磷腈苯并噁嗪树脂玻璃布层压板的研制","volume":"49","year":"2016"},{"abstractinfo":"简要介绍了制备环三磷腈类阻燃剂所需起始原料六氯环三磷腈的合成方法、合成及取代反应机理;介绍了环三磷腈阻燃剂的阻燃机理;着重阐述了近20年间反应型的羟基/氨基环三磷腈、环氧基环三磷腈、含不饱和双键的环三磷腈、羧基环三磷腈阻燃剂,以及添加型烷氧基环三磷腈、芳氧基环三磷腈的合成及阻燃应用,同时综述了其应用材料的热稳定性能和阻燃性能,并对其发展趋势作了总结和展望.","authors":[{"authorName":"游歌云","id":"f66ae500-689b-435c-bcb5-8ab114d53418","originalAuthorName":"游歌云"},{"authorName":"程之泉","id":"288908cb-26bd-4b3b-9ec5-829d39cddef9","originalAuthorName":"程之泉"},{"authorName":"彭浩","id":"eb55e831-e999-4e9f-9db0-4d698cf13793","originalAuthorName":"彭浩"},{"authorName":"贺红武","id":"67a53e96-87e2-4c26-be33-5a8c60a433a1","originalAuthorName":"贺红武"}],"doi":"10.3724/SP.J.1095.2014.30536","fpage":"993","id":"b3a73415-a719-4308-84de-484bba1910bc","issue":"9","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"a5b59782-3441-4b7a-9c1d-df6c2005ded8","keyword":"有机磷阻燃剂","originalKeyword":"有机磷阻燃剂"},{"id":"c65402c2-eaee-4949-9b0f-6ea33f7caaa8","keyword":"六氯环三磷腈","originalKeyword":"六氯环三磷腈"},{"id":"0792bfc4-6ec7-457b-9e1f-dcc74c9b4a40","keyword":"阻燃机理","originalKeyword":"阻燃机理"},{"id":"9cc0f8f3-5ca9-4ace-bb08-6e48549fa4f6","keyword":"反应型","originalKeyword":"反应型"},{"id":"bf6ec977-ca0d-4bc2-bfcf-ed1547827b18","keyword":"添加型","originalKeyword":"添加型"}],"language":"zh","publisherId":"yyhx201409001","title":"环三磷腈类阻燃剂的合成及应用研究进展","volume":"31","year":"2014"},{"abstractinfo":"介绍了六氯环三磷腈的历史沿革、性质及合成方法.综述了其应用进展情况.","authors":[{"authorName":"张亨","id":"c7367f41-d5d5-4c72-8f4c-6508775a8b31","originalAuthorName":"张亨"}],"doi":"10.3969/j.issn.1671-5381.2011.05.009","fpage":"42","id":"30f7b820-1466-461d-807a-b19c963adb92","issue":"5","journal":{"abbrevTitle":"HCCLLHYYY","coverImgSrc":"journal/img/cover/HCCLLHYYY.jpg","id":"42","issnPpub":"1671-5381","publisherId":"HCCLLHYYY","title":"合成材料老化与应用"},"keywords":[{"id":"0dc69aef-ec20-4ade-8ac1-6b8e3f695c16","keyword":"六氯环三磷腈","originalKeyword":"六氯环三磷腈"},{"id":"680c8989-353b-4bba-aa88-2b8500c5118c","keyword":"性质","originalKeyword":"性质"},{"id":"8348c622-6011-4632-9285-be04a20e2942","keyword":"合成","originalKeyword":"合成"},{"id":"bb9a59e2-9390-4d9b-9c5f-44b839cf274c","keyword":"应用","originalKeyword":"应用"}],"language":"zh","publisherId":"hccllhyyy201105009","title":"六氯环三磷腈的应用研究进展","volume":"40","year":"2011"},{"abstractinfo":"采用复式催化剂/缚酸剂体系,合成了六氯环三磷腈。研究了反应溶剂、投料比例、催化剂、反应时间和原料粒径对六氯环三磷腈产率的影响,优化了合成条件和纯化方法,并确定了最佳反应条件。采用熔点测试、元素分析、红外光谱、X射线衍射、核磁共振等测试手段对产物进行了表征。结果表明,所得产物为目标化合物。产率可稳定在75%～80%之间,产物纯度达到98%。在聚合反应前,需要用重结晶结合升华的方法对六氯环三磷腈单体进行精制,以使聚合反应顺利进行。","authors":[{"authorName":"宝冬梅","id":"22577a9d-c4fa-4e63-b603-d2346ea0ed76","originalAuthorName":"宝冬梅"},{"authorName":"刘吉平","id":"d7407610-0bfb-4f9a-b219-8b0e92faade7","originalAuthorName":"刘吉平"}],"doi":"","fpage":"1960","id":"827f25ac-ae3a-47eb-9512-f85e61b9b3e9","issue":"14","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"a79f5db4-7f10-4422-bdbe-03ad5f68d82d","keyword":"六氯环三磷腈","originalKeyword":"六氯环三磷腈"},{"id":"aeba2165-61a8-4bed-9783-b4e7fa5ff24d","keyword":"合成","originalKeyword":"合成"},{"id":"07366e54-0cc0-4e94-90cb-508942f9d1aa","keyword":"精制","originalKeyword":"精制"}],"language":"zh","publisherId":"gncl201214034","title":"六氯环三磷腈的合成与精制研究","volume":"43","year":"2012"},{"abstractinfo":"以六氯环三磷腈(HCTP)、氢化钠、苯酚为原料,以四氢呋喃(THF)为溶剂,在没有N2保护的情况下合成了六苯氧基环三磷腈(HPCTP),并利用红外光谱(IR)、核磁共振波谱(NMR)、质谱(MS)、X射线衍射(XRD)、热重分析(TG)和热裂解气相色谱质谱(PY-GC-MS)对合成的六苯氧基环三磷腈进行了分析表征,确证合成的化合物为HPCTP;首次对HPCTP的晶胞结构进行了计算;初步探索了HPCTP的热解机理,发现HPCTP是一种膨胀型阻燃剂.","authors":[{"authorName":"高岩立","id":"2a955196-0984-4596-9675-273d022ffef2","originalAuthorName":"高岩立"},{"authorName":"冀克俭","id":"c9ce709f-40e5-4a24-874a-7c7b01554859","originalAuthorName":"冀克俭"},{"authorName":"刘元俊","id":"912f4e41-994b-41f2-a97f-01fdb5feee63","originalAuthorName":"刘元俊"},{"authorName":"李艳玲","id":"34bafc98-b8b9-4167-a0bf-0f92fa13ecd3","originalAuthorName":"李艳玲"},{"authorName":"周彤","id":"b7076636-5337-4009-983c-55511d6b6653","originalAuthorName":"周彤"},{"authorName":"赵晓刚","id":"cd56eeab-4849-40a6-ae8b-91bece975bfb","originalAuthorName":"赵晓刚"},{"authorName":"邓卫华","id":"39a10372-2fb1-49a5-b745-a768b5df392d","originalAuthorName":"邓卫华"},{"authorName":"华兰","id":"6a4d8426-64d2-4a1c-9245-bd8ec1724291","originalAuthorName":"华兰"},{"authorName":"邵鸿飞","id":"73adef3c-011b-4ee9-ac2f-1e56b2901b33","originalAuthorName":"邵鸿飞"}],"doi":"","fpage":"237","id":"ec1279b2-3169-43db-80e5-932049a4a7a4","issue":"z2","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"b73cc0a3-9123-420d-aa1b-9192570ae079","keyword":"六苯氧基环三磷腈","originalKeyword":"六苯氧基环三磷腈"},{"id":"0536164b-27f4-4dde-b9ea-8ae14d84d0d9","keyword":"表征","originalKeyword":"表征"},{"id":"ebe7f49b-227f-492f-8c6c-e3f1285a6b37","keyword":"热解","originalKeyword":"热解"}],"language":"zh","publisherId":"cldb2013z2065","title":"六苯氧基环三磷腈的合成及表征改进研究","volume":"27","year":"2013"},{"abstractinfo":"采用两步法合成了六对羧基苯氧基环三磷腈(HCPCP). 以六氯环三磷腈和对羟基苯甲醛为原料,利用亲核取代反应制得六对醛基苯氧基环三磷腈(HAPCP),再用KMnO4氧化法合成HCPCP. 通过红外光谱仪、高效液相色谱仪、核磁共振仪及元素分析确证了产物的结构;用TGA和DSC测试技术对其热性能进行分析. 结果表明,HCPCP对ABS树脂有良好的阻燃作用,添加量30%时,阻燃ABS树脂氧指数提高至25%.","authors":[{"authorName":"邴柏春","id":"676babe9-4e74-4e21-a33b-017090159bb5","originalAuthorName":"邴柏春"},{"authorName":"李斌","id":"b800902e-d1be-4ca4-ba30-5eba5f309d72","originalAuthorName":"李斌"},{"authorName":"贾贺","id":"407261af-8eb4-4726-bbe8-495ca405aeb2","originalAuthorName":"贾贺"},{"authorName":"杨明非","id":"97025660-162b-418b-bb34-eb07267fcc8a","originalAuthorName":"杨明非"}],"doi":"10.3969/j.issn.1000-0518.2009.07.002","fpage":"753","id":"459df748-f552-49a7-962e-868eb9e314a6","issue":"7","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"a0445214-a0ea-43e6-87de-18a034dd103f","keyword":"六氯环三磷腈","originalKeyword":"六氯环三磷腈"},{"id":"a4b19a36-b796-4486-99a3-9546f2c7c7ed","keyword":"六对羧基苯氧基环三磷腈","originalKeyword":"六对羧基苯氧基环三磷腈"},{"id":"7ea8c2be-79f3-460d-9588-34b58bd896b3","keyword":"合成","originalKeyword":"合成"},{"id":"afd1c6af-3b6d-4dab-adc8-1190450c05f1","keyword":"热性能","originalKeyword":"热性能"}],"language":"zh","publisherId":"yyhx200907002","title":"六对羧基苯氧基环三磷腈的合成及其热性能","volume":"26","year":"2009"},{"abstractinfo":"六对醛基苯氧基环三磷腈(HAPCP)是一种重要的无卤高效阻燃剂和精细化工中间体,因具有良好的耐热性和阻燃性而备受关注.以六氯环三磷腈(HCCP)和对羟基苯甲醛为原料制备HAPCP,经红外光谱(IR)、核磁共振(NMR)、元素分析、差热(DSC)和热重(TG)等测试分析手段对产物的结构和热性能进行了表征,并考察了溶剂、缚酸剂、原料配比、反应时间和反应温度对HAPCP收率的影响.结果表明,在四氢呋喃中,以无水碳酸钾为缚酸剂,n(对羟基苯甲醛):n(六氯环三磷腈)=7.2:1,65℃下反应24h,HAPCP的收率可达92.5％.热性能研究表明,HAPCP在N2气氛下的起始分解温度为270℃,800℃时残炭率仍有78.5％,是一种耐热性和热稳定性好的无机-有机杂环化合物,在绝热材料和阻燃材料领域呈现出良好的应用前景.","authors":[{"authorName":"宝冬梅","id":"59dbd4ed-2e3a-4762-a3ae-6a462726f6dd","originalAuthorName":"宝冬梅"},{"authorName":"刘吉平","id":"bc47d965-0778-4e6c-846a-2f1a593bcc55","originalAuthorName":"刘吉平"}],"doi":"","fpage":"396","id":"5613a7f6-07d2-4514-89a0-f0944794fe4c","issue":"3","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"bcb02ec2-4a1c-4992-b9a5-2bf77285437b","keyword":"六对醛基苯氧基环三磷腈","originalKeyword":"六对醛基苯氧基环三磷腈"},{"id":"d26dcc8a-cb84-4d2b-b005-6af6aa6a8a3b","keyword":"合成","originalKeyword":"合成"},{"id":"7da8bcb5-549c-456f-a8bc-32538bc8a448","keyword":"热性能","originalKeyword":"热性能"}],"language":"zh","publisherId":"gncl201303023","title":"六对醛基苯氧基环三磷腈的合成及其热性能研究","volume":"44","year":"2013"},{"abstractinfo":"以六氯环三磷腈为原料合成聚环三磷腈-砜(PCPS)微球,用其对环氧树脂进行填充改性,采用空气喷涂方法在钢板表面制备复合涂层,通过XRD、SEM和滑动摩擦磨损试验机等研究了PCPS微球及其复合涂层的结构,考察了微球含量对复合涂层摩擦学性能的影响.结果表明:PCPS微球为非晶结构,平均粒径约为493 nm,在涂层中分散均匀;涂层的摩擦因数和磨损量均随微球含量的增多而先减小然后略微增大,微球质量分数为3％时涂层的摩擦因数最低且磨损量最小,分别为0.37和1.8×10-6 mm3,其磨损以粘着磨损机理为主.","authors":[{"authorName":"刘海彬","id":"73f3edae-3973-47e9-a1d2-53b1758e76c4","originalAuthorName":"刘海彬"},{"authorName":"钱君质","id":"9097e9bf-356a-4fbd-8e20-371c6ca755f0","originalAuthorName":"钱君质"},{"authorName":"张天骄","id":"7f445595-1eec-4d3e-847a-f81adfc2904b","originalAuthorName":"张天骄"},{"authorName":"郭强","id":"8fb32591-c606-4302-8585-eb5eb836e6c8","originalAuthorName":"郭强"},{"authorName":"刘隽","id":"41f4de1c-fc67-4b81-b7e8-2a4f24ed1fcb","originalAuthorName":"刘隽"},{"authorName":"张四刚","id":"69d7653e-60cc-4220-b973-710ef9484217","originalAuthorName":"张四刚"}],"doi":"","fpage":"38","id":"935b9a86-d5cb-47ec-bb4e-84c9b38e561a","issue":"12","journal":{"abbrevTitle":"JXGCCL","coverImgSrc":"journal/img/cover/JXGCCL.jpg","id":"45","issnPpub":"1000-3738","publisherId":"JXGCCL","title":"机械工程材料"},"keywords":[{"id":"e2d829d0-3e82-4a38-83ca-1d0edfb529dd","keyword":"环氧树脂","originalKeyword":"环氧树脂"},{"id":"4d94bf97-ea4b-4e44-990a-6af16cb5fdef","keyword":"聚环三磷腈-砜微球","originalKeyword":"聚环三磷腈-砜微球"},{"id":"62c9aeca-8ffb-44e1-9818-557aaffd7e1f","keyword":"涂层","originalKeyword":"涂层"},{"id":"47651d5f-2a9d-4a1c-ab85-3ed1e78f3507","keyword":"摩擦学性能","originalKeyword":"摩擦学性能"}],"language":"zh","publisherId":"jxgccl201312009","title":"聚环三磷腈-砜微球/环氧树脂复合涂层的摩擦学性能","volume":"37","year":"2013"}],"totalpage":3085,"totalrecord":30850}