A long time immersion experiment of mortar specimens is carried out to investigate their degradation mechanism by sulfuric acid. Water-cement ratios of mortar are ranging from 0.5 to 0.7 and the pH value of sulfuric acid is 3.5 and 4.0 respectively. The pH meter is used to monitor the soak solution and the titration sulfuric acid with given concentration is added to maintain original pH value, through which the acid consumption of mortar is recorded. A theoretical reaction rate model is also proposed based on concentration boundary layer model. The results show that theoretical model fits the experimental results well and the corrosion mechanism can be modeled by a diffusion process accompanied with an irreversible chemical reaction when pH value of soak solution is no less than 3.5.
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