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Novel visible light-induced Cr-doped SrTiO3-g-C3N4 composite photocatalysts were synthesized by introducing polymeric g-C3N4. The composite photocatalyst was characterized by X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), Fourier transform infrared (FT-IR) spectroscopy, UV-vis diffuse reflection spectroscopy, photoluminescence (PL) spectroscopy and BET surface area measurements. The photocatalytic oxidation ability of the novel composite photocatalyst was evaluated using methyl orange (MO) as a target pollutant. The photocatalysts exhibited a significantly enhanced photocatalytic performance in degrading MO. The optimal g-C3N4 content for the photodegradation activity of the composite photocatalysts was determined. The as-prepared composite photocatalyst exhibits an improved photocatalytic activity due to enhancement of photo-generated electron-hole separation at the interface.

参考文献

[1] C.M. Tank;Y.S. Sakhare;N.S. Kanhe .Electric field enhanced photocatalytic properties of TiO_2 nanoparticles immobilized in porous silicon template[J].Solid state sciences,2011(8):1500-1504.
[2] Wei Wei;Ying Dai;Meng Guo .Density Functional Characterization of the Electronic Structure and Optical Properties of N-Doped, La-Doped, and N/La-Codoped SrTiO3[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(33):15046-15050.
[3] Umebayashi T.;Yamaki T.;Itoh H.;Asai K. .Analysis of electronic structures of 3d transition metal-doped TiO2 based on band calculations[J].The journal of physics and chemistry of solids,2002(10):1909-1920.
[4] He Yu;Shuxin Ouyang;Shicheng Yan .Sol-gel hydrothermal synthesis of visible-light-driven Cr-doped SrTiO3 for efficient hydrogen production[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2011(30):11347-11351.
[5] Frank E.Osterloh .Inorganic Materials as Catalysts for Photochemical Splitting of Water[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(1):35-54.
[6] Xinping Lin;Jingcheng Xing;Wendeng Wang .Photocatalytic Activities of Heterojunction Semiconductors Bi2O3/BaTiO3: A Strategy for the Design of Efficient Combined Photocatalysts[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(49):18288-18293.
[7] S. C. Yan;S. B. Lv;Z. S. Li;Z. G. Zou .Organic–inorganic composite photocatalyst of g-C3N4 and TaON with improved visible light photocatalytic activities[J].Dalton transactions: An international journal of inorganic chemistry,2010(6):1488-1491.
[8] Lei Ge;Changcun Han;Jing Liu.Novel visible light-induced g-C3N4/Bi2WO6 composite photocatalysts for efficient degradation of methyl orange[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2011:100-107.
[9] Quanjun Xiang;Jiaguo Yu;Mietek Jaroniec .Preparation and Enhanced Visible-Light Photocatalytic H2-Production Activity of Graphene/C3N4 Composites[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2011(15):7355-7363.
[10] Li, X.-H.;Chen, J.-S.;Wang, X.;Sun, J.;Antonietti, M. .Metal-free activation of dioxygen by graphene/g-C_3N_4 nanocomposites: Functional dyads for selective oxidation of saturated hydrocarbons[J].Journal of the American Chemical Society,2011(21):8074-8077.
[11] Chengsi Pan;JingXu;Yajun Wang;Di Li;Yongfa Zhu .Dramatic Activity of C_3N_4/BiPO_4 Photocatalyst with Core/ Shell Structure Formed by Self-Assembly[J].Advanced functional materials,2012(7):1518-1524.
[12] Lei Ge;Changcun Han.Synthesis of MWNTs/g-C3N4 composite photocatalysts with efficient visible light photocatalytic hydrogen evolution activity[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2012:268-274.
[13] Facile synthesis of g-C3N4/ZnO composite with enhanced visible light photooxidation and photoreduction properties[J].Chemical engineering journal,2012:386-393.
[14] Jie Fu;Yanlong Tian;Binbin Chang .BiOBr-carbon nitride heterojunctions: synthesis, enhanced activity and photocatalytic mechanism[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2012(39):21159-21166.
[15] Yan, S. C.;Li, Z. S.;Zou, Z. G. .Photodegradation Performance of g-C3N4 Fabricated by Directly Heating Melamine[J].Langmuir,2009(17):10397-10401.
[16] Tan S.;Yue S.;Zhang YH. .Jahn-Teller distortion induced by Mg/Zn substitution on Mn sites in the perovskite manganites[J].Physics Letters, A,2003(5/6):530-538.
[17] Yan, SC;Li, ZS;Zou, ZG .Photodegradation of Rhodamine B and Methyl Orange over Boron-Doped g-C3N4 under Visible Light Irradiation[J].Langmuir: The ACS Journal of Surfaces and Colloids,2010(6):3894-3901.
[18] Ming Yang;Qiao Huang;XiaoqiJin .ZnGaNO solid solution-C_3N_4 composite for improved visible light photocatalytic performance[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2012(8):600-605.
[19] SUNG-HWAN YOON;JAI H. LEE .Oxidation Mechanism of As(III) in the UV/TiO_2 System: Evidence for a Direct Hole Oxidation Mechanism[J].Environmental Science & Technology: ES&T,2005(24):9695-9701.
[20] Liu GM.;Zhao JC.;Horikoshi S.;Hidaka H.;Li XZ. .Photooxidation mechanism of dye alizarin red in TiO2 dispersions under visible illumination: an experimental and theoretical examination[J].Journal of molecular catalysis, A. Chemical,2000(1/2):221-229.
[21] Hideki Kato;Akihiko Kudo .Visible-Light-Response and Photocatalytic Activities of TiO_2 and SrTiO_3 Photocatalysts Codoped with Antimony and Chromium[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2002(19):5029-5034.
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