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  4. Preparation of Nano-sized Zirconium Carbide Powders through a Novel Active Dilution Self-propagating High Temperature Synthesis Method

武汉理工大学学报-材料科学版(英文版), 2015, (4): 740-745. doi: 10.1007/s11595-015-1220-8

DA Aoyun 1, , LONG Fei 2, , WANG Jilin 3, , XING Weihong 4, , WANG Yang 5, , ZHANG Fan 6, , WANG Weimin 7, , FU Zhengyi 8,

1.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China

2.Key Lab of New Processing Technology for Nonferrous Metals & Materials Ministry of Education, China, Guilin University of Technology, Guilin 541004, China

3.Key Lab of New Processing Technology for Nonferrous Metals & Materials Ministry of Education, China, Guilin University of Technology, Guilin 541004, China

4.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China

5.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China

6.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China

7.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China

8.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China

基金项目:   the Self-determined and Innovative Research Funds of WUT(.136643002 and 2013IV058)   the Program for New Century Excellent Talents in University(NCET-12-0655)   the Guangxi Natural Science Foundation(2014GXNSFFA118004)  

Preparation of Nano-sized Zirconium Carbide Powders through a Novel Active Dilution Self-propagating High Temperature Synthesis Method

Keywords： zirconium carbide

High quality nano-sized zirconium carbide (ZrC) powders were successfully fabricated via a developed chemical active dilution self-propagating high-temperature synthesis (SHS) method assisted by ball milling pretreatment process using traditional cheap zirconium dioxide powder (ZrO2), magnesium powder (Mg) and sucrose (C12H22O11) as raw materials. FSEM, TEM, HRTEM, SAED, XRD, FTIR and Raman, ICP-AES, laser particle size analyzer, oxygen and nitrogen analyzer, carbon/sulfur determinator and TG-DSC were employed for the characterization of the morphology, structure, chemical composition and thermal stability of the as-synthesized ZrC samples. The as-synthesized samples demonstrated high purity, low oxygen content and evenly distributed ZrC nano-powders with an average particle size of 50nm. In addition, the effects of endothermic rate and the possible chemical reaction mechanism were also discussed.

参考文献

[1] Xiaohong Zhang;Gregory E. Hilmas;William G. Fahrenholtz .Hot Pressing of Tantalum Carbide With and Without Sintering Additives[J].Journal of the American Ceramic Society,2007(2):393-401.
[2] Ji-Xuan Liu;Yan-Mei Kan;Guo-Jun Zhang .Synthesis of Ultra-Fine Hafnium Carbide Powder and itsPressureless Sintering[J].Journal of the American Ceramic Society,2010(4):980-986.
[3] Chidambaram Nachiappan;Lingappa Rangaraj;Canchi Divakar .Synthesis and Densification of Monolithic Zirconium Carbide by Reactive Hot Pressing[J].Journal of the American Ceramic Society,2010(5):1341-1346.
[4] M.S. Song;B. Huang;M.X. Zhang;J.G. Li .Formation and growth mechanism of ZrC hexagonal platelets synthesized by self-propagating reaction[J].Journal of Crystal Growth,2008(18):4290-4294.
[5] S. C. Zhang;G. E. Hilmas;W. G. Fahrenholtz .Pressureless Densification of Zirconium Diboride with Boron Carbide Additions[J].Journal of the American Ceramic Society,2006(5):1544-1550.
[6] Ryu HY;Nersisyan HH;Lee JH .Preparation of Zirconium-based Ceramic and Composite Fine-grained Powders[J].International Journal of Refractory Metals & Hard Materials,2012,30(01):133-138.
[7] Tao XY;Wei XY;Chen Q et al.Synthesis,Characterisation and Thermal Behaviour of New Preceramic Polymers for Zirconium Carbide[J].ADVANCES IN APPLIED CERAMICS,2013,112(05):301-305.
[8] Chen Z;Wu WP;Chen ZF et al.Microstructural Characterization on ZrC Doped Carbon/Carbon Composites[J].CERAMICS INTERNATIONAL,2012,38(01):761-767.
[9] Beatriz NG;Ortiz AL;Guiberteau F et al.Effect of MoSi2 Content on the Lubricated Sliding-wear Resistance of ZrC-MoSi2 Composites[J].Journal of the European Ceramic Society,2011,31(05):877-882.
[10] Song MS;Ran MW;Kong YY .In situFabrication of ZrC Powder Obtained by Self-propagating High-temperature Synthesis from Al-Zr-C Elemental Powders[J].International Journal of Refractory Metals & Hard Materials,2011,29(03):392-396.
[11] 李静,傅正义,王为民,王皓,李秀完,新原浩一.自蔓延高温技术制备ZrC粉体[J].硅酸盐学报,2010(05):979-985.
[12] Zhang SM;Wang S;Zhu YL et al.Fabrication of ZrB2-ZrC-based Composites by Reactive Melt Inifltration at Relative Low Temperature[J].Scripta Materialia,2011,65(02):139-142.
[13] Yan C;Liu R;Cao Y et al.Carbothermal Synthesis of Submicrometer Zirconium Carbide from Polyzirconoxane and Phenolic Resin by the Facile One-pot Reaction[J].Journal of the American Ceramic Society,2012,95(11):3366-3369.
[14] Seo M;Kang S;Kim Y et al.Preparation of Highly Dispersed Ultra-fine ZrC by Combination of Carbothermal Reduction of Ball-milled ZrO2 and C Mixture and Bead Milling[J].International Journal of Refractory Metals & Hard Materials,2013,41:345-350.
[15] Jian Dong;Wanci Shen;Xuan Liu .A new method synthesizing the encapsulated ZrC with graphitic layers[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2001(5/6):933-938.
[16] Yan C;Liu R;Cao Y et al.Synthesis of Zirconium Carbide Powders Using Chitosan as Carbon Source[J].CERAMICS INTERNATIONAL,2013,39(03):3409-3412.
[17] Mickael Dolle;Dominique Gosset;Christine Bogicevic .Synthesis of nanosized zirconium carbide by a sol-gel route[J].Journal of the European Ceramic Society,2007(1):2061-2067.
[18] Zhao D;Hu H;Zhang C et al.A Simple Way to Prepare Precursors for Zirconium Carbide[J].Journal of Materials Science,2010,45(23):6401-6405.
[19] Xie J;Fu Z;Wang Y et al.Synthesis of Nanosized Zirconium Carbide Powders by a Combinational Method of Sol-gel and Pulse Current Heating[J].Journal of the European Ceramic Society,2014,34(23):13e1-13e7.
[20] Lee D;Jin S;Yu J;Lee H .Synthesis of Ultraifne ZrC Powders by Novel Reduction Process[J].MATERIALS TRANSACTIONS,2010,51(12):2266-2268.
[21] Xiang JY;Liu SC;Hu WT et al.Mechanochemically Activated Synthesis of Zirconium Carbide Nanoparticles at Room Temperature:a Simple Route to Prepare Nanoparticles of Transition Metal Carbides[J].Journal of the European Ceramic Society,2011,31(08):1491-1496.
[22] Jalaly M;Tamizifar M;Bafghi M et al.Mechanochemical Synthesis of ZrB2-SiC-ZrC Nanocomposite Powder by Metallothermic Reduction of Zircon[J].Journal of Alloys and Compounds,2013,581:782-787.
[23] Tsuchida T;Kawaguchi M;Kodaira K.Synthesis of ZrC and ZrN in air from Mechanically Activated Zr-C Powder Mixtures[J].Solid State Ionicis,1997(101-103):149-154.
[24] Nartowski AM;Parkin IP;MacKenzie M et al.Solid State Metathesis Routes to Transition Metal Carbides[J].Journal of Materials Chemistry,1999,9:1275-1281.
[25] Zhang M;Hu QD;Huang B et al.Fabrication of ZrC Particles and Its Formation Mechanism by Self-propagating High-temperature Synthesis from Fe-Zr-C Elemental Powders[J].Journal of Alloys and Compounds,2011,509(31):8120-8125.
[26] Zhang M;Huang B;Hu QD et al.Study of Formation Behavior of ZrC in the Cu-Zr-C System during Combustion Synthesis[J].International Journal of Refractory Metals & Hard Materials,2012,31:230-235.
[27] M.S. Song;B. Huang;M.X. Zhang .In situ synthesis of ZrC particles and its formation mechanism by self-propagating reaction from Al-Zr-C elemental powders[J].Powder Technology: An International Journal on the Science and Technology of Wet and Dry Particulate Systems,2009(1/2):34-38.
[28] Fu ZY;Wang WM;Wang H et al.Fabrication of Cermets by SHS/QP Methed[J].Int J SHS,1993,2(03):307-313.
[29] Yuan R;Fu ZY;Wang WM et al.SHS TiB2-based multiphase ceramics and composites[J].Int J SHS,2001,10:435.
[30] 李静,傅正义,王为民,王皓,李秀完,新原浩一.自蔓延高温技术制备ZrC粉体[J].硅酸盐学报,2010(05):979-985.
[31] Wang J;Gu Y;Li Z et al.Synthesis of Nano-sized Amorphous Boron Powders Through Active Dilution Self-propagating High-temperature Synthesis Method[J].Materials Research Bulletin,2013,48(06):2018-2022.
[32] 翟林峰,史铁钧,王华林.低pH值条件下纤维状ZrO2水合物的制备及其形成机理研究[J].无机材料学报,2007(02):223-226.
[33] Xueyu Tao;Wenfeng Qiu;Hao Li;Tong Zhao .Synthesis of nanosized zirconium carbide from preceramic polymers by the facile one-pot reaction[J].Polymers for advanced technologies,2010(4):300-304.
[34] S. Urbonaite;L. Halldahl;G. Svensson .Raman spectroscopy studies of carbide derived carbons[J].Carbon: An International Journal Sponsored by the American Carbon Society,2008(14):1942-1947.
[35] R.K.Dash;G.Yushin;Y.Gogotsi .Synthesis,structure and porosity analysis of microporous and mesoporous carbon derived from zirconium carbide[J].Microporous and Mesoporous Materials,2005(1/3):50-57.
[36] Rapagna S;Tempesti E;Foscolo P et al.Continuous Fast Pyrolysis of Biomass at High Temperature in a Fluidized Bed Reactor[J].Journal of Thermal Analysis and Calorimetry,1992,38(12):2621-2629.
[37] Zhang L;Gu Y;Wang W et al.A Fast-pyrolysis Self-propagating High Temperature Synthesis Route to Single Phase of Boron Carbide B13C2 Ultraifne Powders[J].J Japan Ceram Soc,2011,119(1392):631-634.
[38] Maitre A;Lefort P .Solid State Reaction of Zirconia with Carbon[J].Solid State Ionicis,1997,104(1-2):109-122.
[39] Wang L;Si L;Zhu Y et al.Solid-state Reaction Synthesis of ZrC from Zirconium Oxide at Low Temperature[J].International Journal of Refractory Metals & Hard Materials,2013,38:134-136.
[40] Shimada S .A Thermoanalytical Study on the Oxidation of ZrC and HfC Powders with Formation of Carbon[J].Solid State Ionicis,2002,149(3-4):319-326.
[41] Bellucci A;Gozzi D;Kimura T et al.Zirconia Growth on Zirconium Carbide Single Crystals by Oxidation[J].Surface and Coatings Technology,2005,197(2-3):294-302.
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