Effect of defect complex on magnetic properties of (Fe,Mn)-doped ZnO thin films

稀有金属（英文版）, 2012, 31(2): 154-157. doi: 10.1007/s12598-012-0482-y

^1, , ^2, , ^3, , ^4, , ^5, , ^6, , ^7,

1.State Key Laboratory for Advanced Metals and Materials, School of Materials Science and Engineering, University of Science and Technology Beijing. Beijing 100083,China

2.State Key Laboratory for Advanced Metals and Materials, School of Materials Science and Engineering, University of Science and Technology Beijing. Beijing 100083,China

3.State Key Laboratory for Advanced Metals and Materials, School of Materials Science and Engineering, University of Science and Technology Beijing. Beijing 100083,China

4.State Key Laboratory for Advanced Metals and Materials, School of Materials Science and Engineering, University of Science and Technology Beijing. Beijing 100083,China

5.State Key Laboratory for Advanced Metals and Materials, School of Materials Science and Engineering, University of Science and Technology Beijing. Beijing 100083,China

6.State Key Laboratory for Advanced Metals and Materials, School of Materials Science and Engineering, University of Science and Technology Beijing. Beijing 100083,China

7.State Key Laboratory for Advanced Metals and Materials, School of Materials Science and Engineering, University of Science and Technology Beijing. Beijing 100083,China

Effect of defect complex on magnetic properties of (Fe,Mn)-doped ZnO thin films

YANG Hailing ^1, , XU Xiaoguang ^2, , ZHANG Guoqing ^3, , MIAO Jun ^4, , ZHANG Xin ^5, , WU Shizhe ^6, , JIANG Yong ^7,

1.State Key Laboratory for Advanced Metals and Materials, School of Materials Science and Engineering, University of Science and Technology Beijing. Beijing 100083,China

2.State Key Laboratory for Advanced Metals and Materials, School of Materials Science and Engineering, University of Science and Technology Beijing. Beijing 100083,China

3.State Key Laboratory for Advanced Metals and Materials, School of Materials Science and Engineering, University of Science and Technology Beijing. Beijing 100083,China

4.State Key Laboratory for Advanced Metals and Materials, School of Materials Science and Engineering, University of Science and Technology Beijing. Beijing 100083,China

5.State Key Laboratory for Advanced Metals and Materials, School of Materials Science and Engineering, University of Science and Technology Beijing. Beijing 100083,China

6.State Key Laboratory for Advanced Metals and Materials, School of Materials Science and Engineering, University of Science and Technology Beijing. Beijing 100083,China

7.State Key Laboratory for Advanced Metals and Materials, School of Materials Science and Engineering, University of Science and Technology Beijing. Beijing 100083,China

Keywords： diluted magnetic semiconductors

We have observed room temperature ferromagnetism in Mn-doped and (Fe, Mn)-codoped ZnO thin films grown under different oxygen partial pressures by pulsed laser deposition. The X-ray diffraction and optical transmission spectra studies demonstrate the natural incorporation of Fe and Mn cations into wurtzite ZnO lattices. The effects of transition metal doping and defects on the magnetic properties was investigated. It is found that room temperature ferromagnetism is sensitive to oxygen vacancy and Zn vacancy. The absence of ferromagnetism in pure ZnO films grown under different oxygen partial pressures reveals that the transition metal ions should also play an important role in inducing the ferromagnetism.

参考文献

[1]	Ohno H .Making nonmagnetic semiconductors ferromagnetic[J].Science,1998,281(5739):951.
[2]	Dietl T;Ohno H;Matsukura F;Cibert J and Ferrand D .Zener model description of ferromagnetism in zinc-blende magnetic semiconductors[J].Science,2000,287(5455):1019.
[3]	Parmanand Sharma;Amita Gupta;Amita Gupta;K.V.Rao;Frank J.Owens;Renu Sharma;Rajeev Ahuja;J.M.Osorio Guillen;Borje Johansson;G.A.Gehring .Ferromagnetism above room temperature in bulk and transparent thin films of Mn-doped ZnO[J].Nature materials,2003(10):673-677.
[4]	S. Ramachandran;J. Narayan;J. T. Prater .Effect of oxygen annealing on Mn doped ZnO diluted magnetic semiconductors[J].Applied physics letters,2006(24):242503-1-242503-3-0.
[5]	Rao CNR;Deepak FL .Absence of ferromagnetism in Mn- and Co-doped ZnO[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2005(5):573-578.
[6]	Tiwari A.;Jin C.;Kvit A.;Kumar D.;Muth JF.;Narayan J. .Structural, optical and magnetic properties of diluted magnetic semiconducting Zn1-xMnxO films[J].Solid State Communications,2002(6/7):371-374.
[7]	T. M. Souza;I. C. da Cunha Lima;M. A. Boselli .Carrier induced ferromagnetism in Mn-doped ZnO: Monte Carlo simulations[J].Applied physics letters,2008(15):152511-1-152511-3-0.
[8]	Ivill M;Pearton SJ;Heo YW;Kelly J;Hebard AF;Norton DP .Magnetization dependence on carrier doping in epitaxial ZnO thin films co-doped with Mn and P[J].Journal of Applied Physics,2007(12):23909-1-23909-5-0.
[9]	Ren L.L;Jeung W.Y .Effects of temperature and Nickel content on magnetic properties of Ni-doped ZnO[J].Rare Metals,2006,25(06):24.
[10]	Kim D;Yang J;Hong J .Feromagnetism induced by Zn vacancy defect and lattice distortion in ZnO[J].Journal of Applied Physics,2009,106(01):013908.
[11]	U. Ozgur;Ya. I. Alivov;C. Liu;A. Teke;M. A. Reshchikov;S. Dogan;V. Avrutin;S.-J. Cho;H. Morkoc .A comprehensive review of ZnO materials and devices[J].Journal of Applied Physics,2005(4)
[12]	Ohtomo A.;Koida T.;Masubuchi K.;Koinuma H.;Sakurai Y. Yoshida Y.;Yasuda T.;Segawa Y.;Kawasaki M. .MgxZn1-xO as a II-VI widegap semiconductor alloy[J].Applied physics letters,1998(19):2466-2468.
[13]	Koidl P .Optical absorption of Co2+in ZnO[J].Physical Review B,1977,15(05):2493.
[14]	Fukumura T;Jin Z.W;Kawasaki M .Magnetic properties of Mn-doped ZnO[J].Applied Physics Letters,2001,78(07):958.
[15]	J.M.D.COEY;M.VENKATESAN;C.B.FITZGERALD .Donor impurity band exchange in dilute ferromagnetic oxides[J].Nature materials,2005(2):173-179.
[16]	Karmakar D;Mandal SK;Kadam RM;Paulose PL;Rajarajan AK;Nath TK;Das AK;Dasgupta I;Das GP .Ferromagnetism in Fe-doped ZnO nanocrystals: Experiment and theory[J].Physical review, B. Condensed matter and materials physics,2007(14):4404-1-4404-14-0.
[17]	Sreetama Dutta;S. Chattopadhyay;A. Sarkar;Mahuya Chakrabarti;D. Sanyal;D.Jana .Role Of Defects In Tailoring Structural, Electrical And Optical Properties Of Zno[J].Progress in materials science,2009(1):89-136.
[18]	Bixia Lin;Zhuxi Fu;Yunbo Jia .Green luminescent center in undoped zinc oxide films deposited on silicon substrates[J].Applied physics letters,2001(7):943-945.

上一张下一张

计量

下载量()
访问量()

作者相关

在本站搜索
在百度学术搜索
在万方数据库搜索
在CNKI搜索

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

Effect of defect complex on magnetic properties of (Fe,Mn)-doped ZnO thin films

参考文献