The microstructures and magnetic properties of Ce32.15Co49.36Cu9.84Fe9.65 magnet sintered at the temperatures ranging from 1005 to 1105 ℃ were investigated.The results on scanning electron microscopy and X-ray diffraction analysis indicate that the remanence Br of the magnets is mainly influenced by the degree of the easy-axis orientation when sintering temperature is less than 1085 ℃,the rapidly increasing amount of the secondly phase (5∶19 phase) gives rise to the deterioration of the magnetic properties of the magnet above 1085 ℃.Moreover,it is found that intrinsic coercivity Hci is strongly related to the content of copper in the matrix of the sintered magnets.The optimal sintering temperature is located in 1025~1055 ℃,the corresponding magnetic properties of the magnets are Br=0.685 T,Hci=350 kA·m-1,and maximum energy product (BH)m=85.6 kJ.m-3.
参考文献
[1] | Bartashevich M.I;Goto T;Radwanski R.J;Korolyov A.V .Magnetic anisotropy and high-field magnetization process of CeCo5[J].Journal of Magnetism and Magnetic Materials,1994,131:61. |
[2] | Nesbitt E.A .Rare earth permanent magnets[J].Physics Today,1973,26(12):59. |
[3] | Vogel R;Fülling W .The systems of cerium-nickel,lanthanum-nickel,praseodymium-nickel and cerium-cobalt[J].Metallforschung,1947,2:97. |
[4] | Ma B.M;Liu W.L;Liang Y.L;Scott D.W and Bounds C.O .Comparison of the improvement of thermal stability of NdFeB sintered magnets:intrinsic and/or microstructural[J].Journal of Applied Physics,1994,75:6628. |
[5] | Strnat K;Hoffer G;Olson J;Ostertag W and Becker J.J .A family of new cobalt-base permanent magnet materials[J].Journal of Applied Physics,1967,38:3. |
[6] | Jin S;Brason D;Mahajan S .Coercivity mechanisms in Fe-Cr-Co magnet alloys[J].Journal of Applied Physics,1982,53:4300. |
[7] | Koichiro Inomata;Teruo Oshima;Tadashi Ido;Masakazu Yamada .Sintered Ce-Co-Cu-Fe-Ti magnets[J].Applied Physics Letters,1977,30(669) |
[8] | Treves D;Jacobs J.T;Sawatzky E .Platinum-cobalt films for digital magneto-optic recording[J].Journal of Applied Physics,1975,46:2760. |
[9] | LI Zhi,DING Hao,ZHANG Jun,WANG Hanbin,WANG Hao.Effects of annealing temperature and time on microstructure and magnetic properties of Pr-Co thin films[J].稀有金属(英文版),2012(02):121-124. |
[10] | Liu J;Deng J.The researches on the mining integration of China[J].China Mining Magazine,2011(z1):019. |
[11] | Anhua Li;Wei Li;Shengzhi Dong .Sintered Nd-Fe-B magnets with high strength[J].Journal of Magnetism and Magnetic Materials,2003(3):331-336. |
[12] | Zhang W.C;Fang Y.K;Zhu M.G;Zhao R and Wang J.D .Effect of powder size on magnetic properties and microstructures of sintered 2:17-type SmCo magnet[J].Functional Materials,2011,3(42):498. |
[13] | Kim AS.;Lizzi T.;Camp FE. .HYDROGEN INDUCED CORROSION MECHANISM IN NDFEB MAGNETS[J].Journal of Applied Physics,1996(8 Pt.2a):4840-4842. |
[14] | Chin T.S;Hung M.P;Tsai D.S .Compaction and sintering behaviors of a Nd-Fe-B permanent magnet alloy[J].Journal of Applied Physics,1988,64(10):5531. |
[15] | Nesbitt E.A;Willens R.H;Sherwood R.C;Buehler E Wernick J.H .New permanent magnet materials[J].Applied Physics Letters,1968,12:361. |
[16] | Tawara Y;Senno H .Cerium,cobalt and copper alloy as a permanent magnet material[J].Japanese Journal of Applied Physics,1968,7:966. |
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