A new cathode using CeO2/MWNT for hydrogen peroxide synthesis through a fuel cell

稀土学报(英文版), 2009, 27(1): 128-133. doi: 10.1016/S1002-0721(08)60206-9

^1, , ^2, , ^3, , ^4, , ^5, , ^6,

1.National Engineering Research Centre for Biochemistry, Nanjing University of Technology, Nanjing 210009, China

2.National Engineering Research Centre for Biochemistry, Nanjing University of Technology, Nanjing 210009, China

3.National Engineering Research Centre for Biochemistry, Nanjing University of Technology, Nanjing 210009, China

4.National Engineering Research Centre for Biochemistry, Nanjing University of Technology, Nanjing 210009, China

5.College of Materials Science and Engineering Nanjing University of Technology Nanjing 210009 China

6.National Engineering Research Centre for Biochemistry, Nanjing University of Technology, Nanjing 210009, China

基金项目: 国家高技术研究发展计划(863计划)(2006AA02Z211) Jiangsu Province Pollution Prevention Fundament Research(2006-1-W-19)

A new cathode using CeO2/MWNT for hydrogen peroxide synthesis through a fuel cell

XU Fuyuan ^1, , SONG Tianshun ^2, , XU Yuan ^3, , CHEN Yingwen ^4, , ZHU Shemin ^5, , SHEN Shubao ^6,

1.National Engineering Research Centre for Biochemistry, Nanjing University of Technology, Nanjing 210009, China

2.National Engineering Research Centre for Biochemistry, Nanjing University of Technology, Nanjing 210009, China

3.National Engineering Research Centre for Biochemistry, Nanjing University of Technology, Nanjing 210009, China

4.National Engineering Research Centre for Biochemistry, Nanjing University of Technology, Nanjing 210009, China

5.College of Materials Science and Engineering Nanjing University of Technology Nanjing 210009 China

6.National Engineering Research Centre for Biochemistry, Nanjing University of Technology, Nanjing 210009, China

Keywords： hydrogen peroxide

Catalyst using CeO2/MWNT (multi-walled carbon nanotube) was prepared by chemical deposition method and was applied to prepare the cathode of fuel cell for hydrogen peroxide synthesis. Effect of catalyst loading, flow rate of aqueous solution, and KOH concentration on hydrogen peroxide synthesis were investigated. Experimental results indicated that hydrogen peroxide concentration approached 275 mmol/L given 25% of CeO2/MWNT, 18 ml/h of aqueous solution, and 5 mol/L of KOH concentration. Moreover, the reaction mechanism was further discussed. The results indicated that MWNT and cerium oxide were the synergism to produce hydrogen peroxide. Increase of KOH concentration not only reduced the apparent cell resistance but also increased the open-circuit voltage.

参考文献

[1]	宋天顺,徐源,徐夫元,陈英文,沈树宝.燃料电池型反应器生产过氧化氢的研究进展[J].现代化工,2007(07):9-12.
[2]	Li Jun;Zhao Ling;Zhang Xinsheng;Zhu Zhongnan .The production of hydrogen peroxide in fuel cell reactions I Experiment and research[J].Chemical Reaction Engineering and Technology,2001,17(03):222.
[3]	Otsuka K;Yamanaka I .One step synthesis of hydrogen peroxide through fuel cell reaction[J].Electrochimica Acta,1990,35(02):319.
[4]	Yamanaka I;Onizawa T;Takenaka S;Otsuka K .Direct and continuous production of hydrogen peroxide with 93% selectivity using a fuel-cell system[J].Angewandte Chemie International Edition,2003,42(01):3653.
[5]	Francisco Alcaide;Enric Brillas;Pere-Lluis Cabot;Juan Casado .Electrogeneration of hydroperoxide ion using an alkaline fuel cell[J].Journal of the Electrochemical Society,1998(10):3444-3449.
[6]	Francisco Alcaide;Enrich Brillas;Pere-Lluis Cabot .Oxygen Reduction on Uncatalyzed Carbon-PTFE Gas Diffusion Cathode in Alkaline Medium[J].Journal of the Electrochemical Society,2002(2):E64-E70.
[7]	Piotr Piela;Piotr K. Wrona .Modeling the Electrical Behavior Of An Alkaline Hydrogen Peroxide Generating Flow-Through Electrochemical Reactor[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2001(7):1494-1502.
[8]	Francisco Alcaide;Enric Brillas;Pere-Lluis Cabot .An Impedance Study of the O_2\|HO_2~- System in Equilibrium on a Gas Diffusion Electrode[J].Journal of the Electrochemical Society,2003(1):E52-E58.
[9]	Piela Piotr;Wrona Piotr K .Some anion-transport properties of Nafion117 from fuel cell hydrogen peroxide generation data[J].Journal of Power Sources,2006,158(22):1262.
[10]	Foller PC.;Bombard RT. .PROCESSES FOR THE PRODUCTION OF MIXTURES OF CAUSTIC SODA AND HYDROGEN PEROXIDE VIA THE REDUCTION OF OXYGEN [Review][J].Journal of Applied Electrochemistry,1995(7):613-627.
[11]	李梅,柳召刚,胡艳宏,刘铃声,熊晓柏,邱巨峰.Preparation and Characterization of CeO2 Superfine Powder[J].稀土学报(英文版),2003(06):654-656.
[12]	Yeager E;Krouse P;Rao K V .The kinetics of the oxygen-peroxide couple on carbon[J].Electrochimica Acta,1964,8:1057.
[13]	Wang Jinan;Chen Lifang;Li Chenglie .Roles of cerium oxide and the reducibility and recoverability of the surface oxygen species in the CeO2/MgAl2O4 catalysts[J].Journal of Molecular Catalysis A:Chemical,1999,2:315.
[14]	Enric Brillas;Francisco Alcaide;Pere-Lluis Cabot .A small-scale flow alkaline fuel cell for on-site production of hydrogen peroxide[J].Electrochimica Acta,2002(4):331-340.

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A new cathode using CeO2/MWNT for hydrogen peroxide synthesis through a fuel cell

参考文献