Synthesis, X-ray structure and luminescent properties of Sm3+ ternary complex with novel heterocyclic β-diketone and 1,10-phenanthroline (Phen)

稀土学报(英文版), 2011, 29(8): 719-722. doi: 10.1016/S1002-0721(10)60529-7

^1, , ^2, , ^3, , ^4,

1.G. S. Petrov Institute of Plastics, JSC, Perovskiy proezd 35, Moscow 111024. Russian Federation

2.People's Friendship University of Russia. Miklukho-Maklaya str. 9,Moscow 117198, Russian Federation

3.People's Friendship University of Russia. Miklukho-Maklaya str. 9,Moscow 117198, Russian Federation

4.A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova str. 28, Moscow 119991, Russian Federation

Synthesis, X-ray structure and luminescent properties of Sm3+ ternary complex with novel heterocyclic β-diketone and 1,10-phenanthroline (Phen)

Ilya V. Taydakov ^1, , Boris E. Zaitsev ^2, , Sergey S. Krasnoselskiy ^3, , Zoya A. Starikova ^4,

1.G. S. Petrov Institute of Plastics, JSC, Perovskiy proezd 35, Moscow 111024. Russian Federation

2.People's Friendship University of Russia. Miklukho-Maklaya str. 9,Moscow 117198, Russian Federation

3.People's Friendship University of Russia. Miklukho-Maklaya str. 9,Moscow 117198, Russian Federation

4.A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova str. 28, Moscow 119991, Russian Federation

Keywords： samarium

A new neutral ternary samarium complex Sm(Phen)HL3 in which Phen is 1,10-phenanthroline and HL is (1,3-bis(1,3-dimethyl1H-pyrazol-4-yl)-1,3-propanedione) was synthesized.Molecular structure of this complex was determined by X-ray diffraction.Under UV-light this complex is demonstrated bright red luminescence (λmax=647 nm),which was corresponding to the electric dipole 4G5/2→,6H9/2 transition in Sm3+ ion.UV-absorption,excitation and emission spectra of the title compound were investigated.

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Synthesis, X-ray structure and luminescent properties of Sm3+ ternary complex with novel heterocyclic β-diketone and 1,10-phenanthroline (Phen)

参考文献