Luminescent properties of Eu3+ doped Gd2WO6 and Gd2(WO4)3 nanophosphors prepared via co-precipitation method

稀土学报(英文版), 2011, 29(9): 815-821. doi: 10.1016/S1002-0721(10)60566-2

^1, , ^2, , ^3, , ^4, , ^5, , ^6,

1.Heilongjiang Laboratory Low Dimensional Mesoscopic Physics, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, China

2.Heilongjiang Laboratory Low Dimensional Mesoscopic Physics, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, China

3.Heilongjiang Laboratory Low Dimensional Mesoscopic Physics, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, China

4.Heilongjiang Laboratory Low Dimensional Mesoscopic Physics, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, China

5.Heilongjiang Laboratory Low Dimensional Mesoscopic Physics, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, China

6.Heilongjiang Laboratory Low Dimensional Mesoscopic Physics, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, China

Luminescent properties of Eu3+ doped Gd2WO6 and Gd2(WO4)3 nanophosphors prepared via co-precipitation method

ZHANG Qing ^1, , MENG Qingyu ^2, , TIAN Yue ^3, , FENG Xiaohui ^4, , SUN Jiangting ^5, , L(U) Shuchen ^6,

1.Heilongjiang Laboratory Low Dimensional Mesoscopic Physics, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, China

2.Heilongjiang Laboratory Low Dimensional Mesoscopic Physics, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, China

3.Heilongjiang Laboratory Low Dimensional Mesoscopic Physics, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, China

4.Heilongjiang Laboratory Low Dimensional Mesoscopic Physics, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, China

5.Heilongjiang Laboratory Low Dimensional Mesoscopic Physics, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, China

6.Heilongjiang Laboratory Low Dimensional Mesoscopic Physics, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, China

Keywords： red nanophosphors

Eu3+ doped Gd2WO6 and Gd2(WO4)3 nanophosphors with different concentrations were prepared via a co-precipitation method.The structure and morphology of the nanocrystal samples were characterized by using X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM),respectively.The emission spectra and excitation spectra of samples were measured.J-O parameters and quantum efficiencies of Eu3+ 5D0 energy level were calculated,and the concentration quenching of Eu3+ luminescence in different matrixes were studied.The results indicated that effective Eu3+∶5D0-7F2 red luminescence could be achieved while excited by 395 nm near-UV light and 465 nm blue light in Gd2WO6 host,which was similar to the familiar Gd2(WO4)3∶Eu.Therefore,the Gd2WO6∶Eu red phosphors might have a potential application for white LED.

参考文献

[1]	Ryu J H;Bang S Y;Kim W S;Park G S Kim K M Yoon J W Shim K B Koshizaki N .Microstructure and optical properties of nanocrystalline CaWO4 thin films deposited by pulsed laser ablation in room temperature[J].Journal of Alloys and Compounds,2007,441(1-2):146.
[2]	Luo Z J;Li H M;Xia J X;Zhu W H Guo J X Zhang B B .Microwave-assisted synthesis of barium tungstate nanosheets and nanobelts by using polymer PVP micelle as templates[J].Materials Letters,2007,61(8-9):1845.
[3]	A.I. Vodchits;V.A. Orlovich;P.A. Apanasevich;T.T. Basiev;P.G. Zverev .Nonlinear optical properties of BaWO_4 crystal[J].Optical materials,2007(12):1616-1619.
[4]	Jinping Huang;Hongshan Luo;Pingle Zhou;Xibin Yu;Yikang Li .Synthesis and luminescent properties of Y_6W_2O_(15):Eu~(3+) phosphors[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2007(2):881-885.
[5]	Sitthisuntorn Supothina;Panpailin Seeharaj;Sorachon Yoriya .Synthesis of tungsten oxide nanoparticles by acid precipitation method[J].CERAMICS INTERNATIONAL,2007(6):931-936.
[6]	Longo VM;Orhan E;Cavalcante LS;Porto SL;Espinosa JWM;Varela JA;Longo E .Understanding the origin of photoluminescence in disordered Ca0.60Sr0.40WO4: An experimental and first-principles study[J].Chemical Physics: A Journal Devoted to Experimental and Theoretical Research Involving Problems of Both a Chemical and Physical Nature,2007(1-3):180-188.
[7]	Bhargava R N;Gallagher D;Hong X;Nurmikko A .Optical properties of manganese-doped nanocrystals of ZnS[J].Physical Review Letters,1994,72(03):416.
[8]	Bhargava R N .Doped nanocrystalline materials-Physics and applications[J].Journal of Luminescence,1996,70:85.
[9]	Jia ML.;Zhang JH.;Lu SZ.;Sun JT.;Luo YS.;Ren XG.;Song HW.;Wang XJ. .UV excitation properties of Eu3+ at the S-6 site in bulk and nanocrystalline cubic Y2O3[J].Chemical Physics Letters,2004(1/3):193-196.
[10]	Hongwei Song;Baojiu Chen;Hongshang Peng;Jisen Zhang .Light-induced change of charge transfer band in nanocrystalline Y_(2)O_(3):Eu~(3+)[J].Applied physics letters,2002(10):1776-1778.
[11]	Kodaira CA.;Brito HF.;Malta OL.;Serra OA. .Luminescence and energy transfer of the europium (III) tungstate obtained via the Pechini method[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2003(1/2):11-21.
[12]	Kodaira C A;Brito H F;Felinto M C F C .Luminescence investigation of Eu3+ ion in the RE2(WO4)3 matrix (RE=La and Gd) produced using the Pechiin method[J].Journal of Solid State Chemistry,2003,171:401.
[13]	Jia PY;Liu XM;Yu M;Luo Y;Fang J;Lin J .Luminescence properties of sol-gel derived spherical SiO2@Gd-2(WO4)(3): Eu3+ particles with core-shell structure[J].Chemical Physics Letters,2006(4-6):358-363.
[14]	Pullar R C;Farrah S;Alford N McN .MgWO4,ZnWO4,NiWO4 and CoWO4 microwave dielectric ceramics[J].Journal of the European Ceramic Society,2007,27(2-3):1059.
[15]	Kodaira CA;Brito HF;Teotonio EES;Claudia M;Felinto MCFC;Malta OL;Brito GES .Photoluminescence behavior of the Sm3+ and Tb3+ ions doped into the Gd-2(WO4)(3) matrix prepared by the Pechini and ceramic methods[J].Journal of the Brazilian Chemical Society,2004(6):890-896.
[16]	Yonggang Wang;Junfeng Ma;Jiantao Tao .Low-temperature synthesis of CdWO_4 nanorods via a hydrothermal method[J].CERAMICS INTERNATIONAL,2007(6):1125-1128.
[17]	Hongbo Fu;Chengsi Pan;Liwu Zhang;Yongfa Zhu .Synthesis, characterization and photocatalytic properties of nanosized Bi_2WO_6, PbWO_4 and ZnWO_4 catalysts[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2007(4):696-706.
[18]	Di W H;Wang X J;Chert B J;Lu S Z Zhao X X .Effect of OH-on the luminescent efficiency and lifetime of Tb3+-doped yttrium orthophosphate synthesized by solution precipitation[J].Journal of Physical Chemistry B,2005,109(27):13154.
[19]	Chuan He;Yongfeng Guan;Lianzeng Yao;Weili Cai;Xiaoguang Li;Zhe Yao .Synthesis and photoluminescence of nano-Y_2O_3:Eu~(3+) phosphors[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2003(6):973-979.
[20]	Zhou YH.;Lin J.;Wang SB. .Energy transfer and upconversion luminescence properties of Y2O3 : Sm and Gd2O3 : Sm phosphors[J].International Journal of Quantum Chemistry,2003(1/2):391-395.
[21]	Li YH;Hong GY .Synthesis and luminescence properties of nanocrystalline YVO4 : Eu3+[J].International Journal of Quantum Chemistry,2005(3):645-649.
[22]	Judd B R .Optical absorption intensities of me-earth ions[J].Physical Review,1962,127(03):750.
[23]	Ofelt G S .Intensities of crystal spectra of rare earth ions[J].Journal of Chemical Physics,1962,37(03):511.
[24]	Ray S;Pramanik P;Singha A;Roy A .Optical properties of nanocrystalline Y2O3 : Eu3+[J].Journal of Applied Physics,2005(9):4312-1-4312-6-0.
[25]	Nishimura G;Kushida T .Local field in glass probed by laser-induced fluorescence-line narrowing in Ca(PO3)2:Eu3+[J].Physical Review B,1988,37(15):9075.
[26]	Reisfeld R;Greenberg E;Brown R N .Fluorescence of europium(Ⅲ) in fluoride glass containing zirconium[J].Chemical Physics Letters,1983,95(02):91.
[27]	Tian Y;Qi X H;Wu X W;Hua R N Chen B J .Luminescent properties of Y2(MoO4)3:Eu3+ red phosphors with flowerlike shape prepared via coprecipitation method[J].Journal of Physical Chemistry C,2009,113:10767.

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Luminescent properties of Eu3+ doped Gd2WO6 and Gd2(WO4)3 nanophosphors prepared via co-precipitation method

参考文献