Pure nanocrystalline La2O3 powders were successfully prepared by the combustion method.The effect of ethanolamine-to-nitrate ratio on phase composition and crystallite size of the combustion products was systematically investigated.Pure hexagonal La2O3 powders were almost formed in stoichiometric reaction (Ψ=1.15),while metallic La phase was obtained in fuel-rich conditions (Ψ≥3.0).The as-synthesized hexagonal La2O3 was found to be chemically unstable in ambient air since a complete transformation to hexagonal La(OH)3was detected after 24 h exposure to air.The resulting hexagonal La(OH)3 showed an excellent ability to remove water pollutant and could nearly remove 100% of the Congo red at room temperature with a removal capacity of 143.5 mg Congo red/g.The phosphate adsorption data on hexagonal La(OH)3 agreed well with the Langmuir model with the estimated maximum adsorption capacity of 57.8 mg/g.
参考文献
[1] | Tao L;Sun C G;Fan M L;Liu Q Huang C J Zhai H S Wu H L Chao Z S .Synthesis and characterization of lanthanum oxide nanotubes using dendritic surfactant[J].Studies in Surface Science and Catalysis,2007,165:339. |
[2] | ZHANG Houan,GU Siyong,XIE Nengping.Effect of La2O3 on the wear behavior of MoSi2 at high temperature[J].稀土学报(英文版),2011(04):370-373. |
[3] | Wang X G;Wang M L;Song H;Ding B J .A simple sol-gel technique for preparing lanthanum oxide nanopowders[J].Materials Letters,2006,60(17-18):2261. |
[4] | Ana C. Ferreira;A.M. Ferraria;A.M. Botelho do Rego .Partial oxidation of methane over bimetallic nickel-lanthanide oxides[J].Journal of Alloys and Compounds,2010(1):316-323. |
[5] | Fleys M;Shan W J;Simon Y;Marquaire P M .Detailed kinetic study of the partial oxidation of methane over La2O3 catalyst Part 1:Experimental[J].Results Industrial Engineering Chemistry Research,2007,46(04):1063. |
[6] | Fleys M;Simon Y;Marquaire PM .Detailed kinetic study of the partial oxidation of methane over La2O3 catalyst. Part 2: Mechanism[J].Industrial & Engineering Chemistry Research,2007(4):1069-1078. |
[7] | Pisecny P;Husekova K;Frohlich K;Harmatha L;Soltys J;Machajdik D;Espinos JP;Jergel M;Jakabovic J .Growth of lanthanum oxide films for application as a gate dielectric in CMOS technology[J].Materials science in semiconductor processing,2004(4/6):231-236. |
[8] | Sang-Woo Kang;Shi-Woo Rhee .Deposition of La_2O_3 Films by Direct Liquid Injection Metallorganic Chemical Vapor Deposition[J].Journal of the Electrochemical Society,2002(6):C345-C348. |
[9] | Yang JC.;Nie ZR.;Wang YM. .Microstructure and emission ability of rare earth oxides doped molybdenum cathodes[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2003(1/4):87-95. |
[10] | Guo Z;Jiang Z W;Chen X;Sun B Li M Q Liu J H Huang X J .Novel cocoon-like Au/La2O3 nanomaterials:synthesis and their ultra-enhanced cataluminescence performance to volatile organic compounds[J].Journal of Materials Chemistry,2011,21:1874. |
[11] | Tang L;Li YM;Xu KL;Hou XD;Lv Y .Sensitive and selective acetone sensor based on its cataluminescence from nano-La2O3 surface[J].Sensors and Actuators, B. Chemical,2008(1):243-249. |
[12] | J. Cao;H. Ji;J. Liu .Controllable syntheses of hexagonal and lamellar mesostructured lanthanum oxide[J].Materials Letters,2005(4):408-411. |
[13] | Wang SY.;Qian YT.;Wang W. .Preparation of La2O3 thin films by pulse ultrasonic spray pyrolysis method[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2000(1/2):50-53. |
[14] | Imanaka N;Masui T;Kato Y .Preparation of the cubic-type La2O3 phase by thermal decomposition of LaI3[J].International Journal of Quantum Chemistry,2005(1):395-398. |
[15] | Sheng J;Zhang S;Lv S;Sun W .Surfactant-assisted synthesis and characterization of lanthanum oxide nanostructures[J].Journal of Materials Science,2007(23):9565-9571. |
[16] | Q.Z. Wu;Y. Shen;J.F. Liao .Synthesis and characterization of three-dimensionally ordered macroporous rare earth oxides[J].Materials Letters,2004(21):2688-2691. |
[17] | Hu C G;Liu H;Dong W T;Zhang Y Y Bao G Lao C S Wang Z L .La(OH)3 and La2O3 nanobelts-synthesis and physical properties[J].Advanced Materials,2007,19(17):470. |
[18] | Bazzi R.;Flores-Gonzalez MA.;Louis C.;Lebbou K.;Dujardin C.;Brenier A.;Zhang W.;Tillement O.;Bernstein E.;Perriat P. .Synthesis and luminescent properties of sub-5-nm lanthanide oxides nanoparticles[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2003(0):445-450. |
[19] | A. Vadivel Murugan;S.C. Navale;V. Ravi .Synthesis of nanocrystalline La_2O_3 powder at 100℃[J].Materials Letters,2006(6):848-849. |
[20] | Jain S R;Adiga K C;Pai Vemeker V R .A new approach to thermochemical calculations of condensed fuel-oxidizer mixtures[J].Combustion and Flame,1981,40:71. |
[21] | Weifan Chen;Fengsheng Li;Jiyi Yu .Combustion synthesis and characterization of nanocrystalline CeO_2-based powders via ethylene glycol-nitrate process[J].Materials Letters,2006(1):57-62. |
[22] | Nieminen M.;Niinisto L.;Putkonen M. .Formation and stability of lanthanum oxide thin films deposited from beta-diketonate precursor[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2001(2):155-165. |
[23] | Peter Fleming;Richard A. Farrell;Justin D. Holmes .The Rapid Formation of La(OH)_3 from La_2O_3 Powders on Exposure to Water Vapor[J].Journal of the American Ceramic Society,2010(4):1187-1194. |
[24] | L.-S. Zhong;J.-S. Hu;H.-P. Liang;A.-M. Cao;W.-G. Song;L.-J. Wan .Self-Assembled 3D Flowerlike Iron Oxide Nanostructures and Their Application in Water Treatment[J].Advanced Materials,2006(18):2426-2431. |
[25] | Wang, PP;Bai, B;Hu, S;Zhuang, J;Wang, X .Family of Multifunctional Layered-Lanthanum Crystalline Nanowires with Hierarchical Pores: Hydrothermal Synthesis and Applications[J].Journal of the American Chemical Society,2009(46):16953-16960. |
[26] | WILAIWAN CHOUYYOK;ROBERT J. WIACEK;KANDA PATTAMAKOMSAN .Phosphate Removal by Anion Binding on Functionalized Nanoporous Sorbents[J].Environmental Science & Technology: ES&T,2010(8):3073-3078. |
[27] | Chitrakar R;Tezuka S;Sonoda A;Sakane K;Ooi K;Hirotsu T .Phosphate adsorption on synthetic goethite and akaganeite[J].Journal of Colloid and Interface Science,2006(2):602-608. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%