Magnesium bicarbonate, prepared by the carbonation of magnesium hydroxide slurry, was used as a novel saponifier to eliminate the ammonia nitrogen pollution in the rare earth extraction separation process. The effect of impurity ions introduced by system on the carbonation reaction of magnesium hydroxide was studied in the work. The results showed that the presence of Ca2+could lead to side reactions so as to reduce the conversion rate of magnesium hydroxide, and a small number of rare earth ions would have great influence on the carbonation reaction. What’s more, there was no influence on carbonation reaction with the low concen-tration of Na+or Mg2+, the conversion rate of magnesium hydroxide could reach above 96%. This paper showed a practical theory which could provide scientific guidance for the preparation of novel saponifier in rare earth extraction separation process.
参考文献
[1] | Xu G X.Rare Earths (Second Edition)[M].Beijing:Metal-lurgy Industry Press,2002 |
[2] | 黄小卫,庄卫东,李红卫,余成洲,薛向欣,张国成.稀土功能材料研究开发现状和发展趋势[J].稀有金属,2004(04):711-715. |
[3] | CHEN Zhanheng.Global rare earth resources and scenarios of future rare earth industry[J].稀土学报(英文版),2011(01):1-6. |
[4] | 黄小卫,李红卫,薛向欣,张国成.我国稀土湿法冶金发展状况及研究进展[J].中国稀土学报,2006(02):129-133. |
[5] | Xu G X;Yuan C Y.Solvent Extraction of Rare Earth[M].Bei-jing:Science Press,1987 |
[6] | Taichi Sato .Liquid-liquid extraction of rare-earth elements from aqueous acid solutions by acid organ phosphorus compounds[J].Hydrometallurgy,1989,22:121. |
[7] | Huang X W;Li H W;Long Z Q;Peng X L, Cui D L,Yang G L,Luo X H,Zhao N,Zhang Y Q .A process for pre-treating organic extractant and its product and application[P].Australian patent,AU2008217450,2008. |
[8] | Liu H J;Feng Z Y;Huang X W;Long Z Q, Cui D L .The behavior and influence of the Fe impurities in the process of preparing high-purity Mg(HCO3)2 with magnesium chloride wastewater[J].J Chin Soc Rare Earths (in Chin ),2012,30(03):273. |
[9] | Huang X W;Long Z Q;Peng X L;Li H W, Yang G L,Cui D L,Wang C M,Zhao N,Wang L S,Yu Y .Use of Mg(HCO3)2 and/or Ca(HCO3)2 aqueous solution in metal extractive separation and purification[P].China Patent,CN201080000551.8,2010. |
[10] | Huang X W;Long Z Q;Peng X L;Li H W, Yang G L,Han Y B,Cui D L,Luo X H,Zhao N,Wang L S .A proc-ess for extraction and separation of rare earth element[P].China Patent:CN200910118985.7,2009. |
[11] | FENG Zongyu,HUANG Xiaowei,LIU Hongji,WANG Meng,LONG Zhiqi,YU Ying,WANG Chunmei.Study on preparation and application of novel saponification agent for organic phase of rare earths extraction[J].稀土学报(英文版),2012(09):903-908. |
[12] | LIU Hongji,FENG Zongyu,HUANG Xiaowei,LONG Zhiqi,WANG Meng,XIAO Yanfei,HOU Yongke.Study on purification and application of novel precipitant for ceria-based polishing powder[J].稀土学报(英文版),2013(02):174-179. |
[13] | 冯小平,张正文,谢峻林.轻烧白云石的煅烧工艺对活性度的影响[J].矿产综合利用,2007(01):13-15,25. |
[14] | LIANG ZHAO;LIQIN SANG;JUN CHEN .Aqueous Carbonation of Natural Brucite: Relevance to CO2 Sequestration[J].Environmental Science & Technology: ES&T,2010(1):406-411. |
[15] | 张焕军,朱国才.机械力强化作用下轻烧氧化镁碳化过程的传质与反应动力学研究[J].中国化学工程学报(英文版),2004(02):196-201. |
[16] | 刘宝树,乔满辉,胡庆福,翟学良.白云石灰浆碳化反应动力学研究[J].河北科技大学学报,2005(02):118-123. |
[17] | Chen J Y.Handbook of Hydrometallurgy[M].Beijing:Metal-lurgical Industry Press,2005 |
[18] | Wang G;Wang H;Bai J T;Ren Z Y, Bai J B .PVP-as-sisted assembly of lanthanum carbonate hydroxide with hierarchical architectures and their luminescence proper-ties[J].Chemical Engineering Journal,2013,214:386. |
[19] | Han D G;Gao Z D;Gao P L.Physical Chemistry[M].北京:高等教育出版社,2003 |
[20] | Martin Back;Markus Bauer;Helge Stanjek;Stefan Peiffer .Sequestration of CO2 after reaction with alkaline earth metal oxides CaO and MgO[J].Applied Geochemistry,2011,26:1097. |
[21] | Zhang L L.Research of Product Lightweight Magnesium Carbonate by Twice Carbonation with Powder of Light-burned Dolomite[M].北京:北京化工大学,2008 |
[22] | Wang Q.Study on Optimum Condition of Carbonation of Calcium and Magnesium System[M].Hefei:Hefei University of Technology,2002 |
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