A method based on the semi-empirical Miedema model and a geometrical model was used to study the glass forming abili-ties (GFA) and the amorphous forming ranges of Al-Fe-Nd-Zr system and its constituent ternary systems. The amorphous forming composition ranges were analyzed based on different criteria such asΔGam-ss and PHSS (PHSS=ΔHchem (ΔSC/R)(ΔSσ/R)) for Al-Fe-Nd system. The predicted amorphous forming range was in good agreement with the experimental results. The results showed that the criterion ofΔGam-ss was more accurate, and agreed well with the experiment results. The Gibbs free energy differenceΔGam-ss and pa-rameter PHSS were then used to predict the amorphous forming composition range for the rest of the constitutive ternary systems of Al-Fe-Nd-Zr. In addition, the amorphous forming composition ranges of the (Al-Fe-Zr)100-xNdx (x=50, 60, 70) systems were predicted byΔGam-ss and the modified parameter PHSS. The Gibbs free energy of Al10(Fe1-xZrx)30Nd60 were also calculated. The GFA parameter PHSS indicated that the composition with the highest GFA was Al33.5Fe13.5Zr3Nd50 for the (Al-Fe-Zr)50Nd50 system, Al28.8Fe10Zr1.2Nd60 for the (Al-Fe-Zr)40Nd60 system and Al22.8Fe6.9Zr0.3Nd70 for the (Al-Fe-Zr)30Nd70 system, and the results suggested that those alloys with high content of Al had higher GFA. The appropriate content of neodymium and zirconium resulted in the lower value of PHSS and increased the GFA obviously.
参考文献
| [1] | Akihisa Inoue;Nobuyuki Nishiyama .New Bulk Metallic Glasses for Applications as Magnetic-Sensing, Chemical, and Structural Materials[J].MRS bulletin,2007(8):651-658. |
| [2] | A.Inoue .Stabilization of metallic supercooled liquid and bulk amorphous alloys[J].Acta materialia,2000(1):279-306. |
| [3] | Wang X.;Yoshii I. .Bulk Amorphous Co-Ni-Based Alloys with a Large Supercooled Liquid Region[J].Materials transactions,2000(4):539-542. |
| [4] | W. L. Johnson .Bulk Amorphous Metal--An Emerging Engineering Material[J].JOM,2002(3):40-43. |
| [5] | Inoue A;Takeuchi A .Recent progress in bulk glassy, nanoquasicrystalline and nanocrystalline alloys[J].Mater Sci Eng A,2004,375:16. |
| [6] | Inoue A.Bulk Amorphous Alloys:Preparation and Fun-damental Characteristics, Materials Science Foundations 4[M].Netherlands:Trans Tech Publications,1998:1. |
| [7] | Jorg F. Loffler .Bulk metallic glasses[J].Intermetallics,2003(6):529-540. |
| [8] | Turnbull D .Under what conditions can a glass be formed Contemp[J].Phys,1969,10(05):473. |
| [9] | Inoue A;Zhang T;Masumoto T .Al-La-Ni amorphous al-loys with a wide supercooled liquid region[J].Materials Transactions JIM,1989,30(12):965. |
| [10] | Lu Z P;Liu C T .A new glass-forming ability criterion for bulk metallic glasses[J].ACTA MATERIALIA,2002,50(13):3501. |
| [11] | Mondal K;Murty BS .On the parameters to assess the glass forming ability of liquids[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2005(16/17):1366-1371. |
| [12] | Chen QJ;Shen J;Zhang DL;Fan HB;Sun J;McCartney DG .A new criterion for evaluating the glass-forming ability of bulk metallic glasses[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2006(1-2):155-160. |
| [13] | Rao B R;Srinivas M;Shah A K;Gandhi A S Murty B S .A new thermodynamic parameter to predict glass forming ability in iron based multi-component systems containing zirconium[J].INTERMETALLICS,2013,35:73. |
| [14] | Das N;Mittra J;Murty B S;Pabi S K Kulkarni U D Dey G K .Miedema model based methodology to predict amor-phous-forming-composition range in binary and ternary systems[J].Journal of Alloys and Compounds,2012,550:483. |
| [15] | Somoza JA.;Rey C.;Rozenberg S.;Arcondo B.;Sirkin H. Detendler RH.;Kovacs JA.;Alonso JA.;Gallego LJ. .AN EXPERIMENTAL AND THEORETICAL STUDY OF THE GLASS-FORMING REGION OF THE MG-CU-SN SYSTEM[J].Journal of Materials Science,1995(1):40-46. |
| [16] | Akira Takeuchi;Akihisa Inoue .Calculations of Mixing Enthalpy and Mismatch Entropy for Ternary Amorphous Alloys[J].Materials transactions,2000(11):1372-1378. |
| [17] | Basu J;Murty B S;Ranganathan S .Glass forming ability:Miedema approach to(Zr,Ti,Hf)-(Cu,Ni)binary and ter-nary alloys[J].Journal of Alloys and Compounds,2008,465(01):163. |
| [18] | Sun, SP;Yi, DQ;Liu, HQ;Zang, B;Jiang, Y .Calculation of glass forming ranges in Al-Ni-RE (Ce, La, Y) ternary alloys and their sub-binaries based on Miedema's model[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2010(1):377-387. |
| [19] | Li, H.;Lu, X.;Liu, Y.;Wu, R.;Yin, H.;Han, M.;Chen, G..Thermodynamic calculation of glass formation for Co-ETM alloys based on Miedema'smodel[J].Physica, B. Condensed Matter,2013:24-30. |
| [20] | Miedema A R;de Chatel P F;de Boer F R .Cohesion in alloys-fundamentals of a semi-empirical model[J].Physica B+C,1980,100(01):1. |
| [21] | de Boer F R;Boom R;Mattens W C M;Miedema A R Niessen A R.Cohesion in Metals:Transition Metal Alloys[M].Amsterdam:North Holland,1988 |
| [22] | Meschel S V;Nash P;Chen X Q .The standard enthalpies of formation of binary intermetallic compounds of some late 4d and 5d transition metals by high temperature direct synthesis calorimetry[J].Journal of Alloys and Compounds,2010,492(01):105. |
| [23] | J.F. Fernandez;J.R. Ares;F. Cuevas .A thermodynamic study of the hydrogenation of the pseudo-binary Mg_6Pd_(0.5)Ni_(0.5) intermetallic compound[J].Intermetallics,2010(2):233-241. |
| [24] | HongWei Yang;DongPing Tao;XiaoMei Yang .Prediction of the formation enthalpies of Bi-Cd-Ga-In-Pb-Sn-Zn liquid alloys by binary infinitely dilute enthalpies[J].Journal of Alloys and Compounds,2009(2):625-628. |
| [25] | Long Z H;Liu H S;Jin Z P .Thermodynamic description of Ru-Ge-Si ternary system[J].Journal of Alloys and Compounds,2009,479(01):262. |
| [26] | Djaballah Y;Pasturel A;Belgacem-Bouzida A .Thermo-dynamic assessment of the calcium-germanium system[J].Journal of Alloys and Compounds,2010,497(01):74. |
| [27] | Gonzalez G;Sagarzazu A;Bonyuet D;D'Angelo L Villalba R .Solid state amorphisation in binary systems prepared by mechanical alloying[J].Journal of Alloys and Compounds,2009,483(01):289. |
| [28] | S.Sheibani;S.Heshmati-Manesh;A.Ataie .Structural investigation on nano-crystalline Cu-Cr supersaturated solid solution prepared by mechanical alloying[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2010(1):59-62. |
| [29] | Gallego L J;Somoza J A;Alonso J A .Glass formation in ternary transition metal alloys[J].Journal of Physics:Condensed Matter,1990,2(29):6245. |
| [30] | Zhang BW.;Jesser WA. .Formation energy of ternary alloy systems calculated by an extended Miedema model[J].Physica, B. Condensed Matter,2002(1/3):123-132. |
| [31] | Toop G W .Predicting ternary activities using binary data[J].Trans TMS-AIME,1965,233:850. |
| [32] | Ouyang Y F;Zhong X P;Du Y;Jin Z P He Y H Yuan Z H .Formation enthalpies of Fe-Al-RE ternary alloys calcu-lated with a geometric model and Miedema's theory[J].Journal of Alloys and Compounds,2006,416(01):148. |
| [33] | Ouyang Y F;Zhong X P;Du Y;Feng Y P He Y H .En-thalpies of formation for the Al-Cu-Ni-Zr quaternary al-loys calculated via a combined approach of geometric model and Miedema theory[J].Journal of Alloys and Compounds,2006,420(01):175. |
| [34] | ?niadecki Z;Narojczyk J W;Idzikowski B .Calculation of glass forming ranges in the ternary Y-Cu-Al system and its sub-binaries based on geometric and Miedema's models[J].INTERMETALLICS,2012,26:72. |
| [35] | A.I. SALIMON;A. M. KORSUNSKY;E. V. SHELEKHOV .CRYSTALLOCHEMICAL ASPECTS OF SOLID STATE REACTIONS IN MECHANICALLY ALLOYED Al-Cu-Fe QUASICRYSTALLINE POWDERS[J].Acta materialia,2001(10):1821-1833. |
| [36] | Tcherdyntsev VV.;Kaloshkin SD.;Salimon AI.;Tomilin IA.;Korsunsky AM. .Quasicrystalline phase formation by heating a mechanically alloyed Al65Cu23Fe12 powder mixture[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2002(0):522-526. |
| [37] | Baker I;George E P.Aluminides:Processing properties and the mechanical properties of FeAl[A].Warrendale,The Metallurgical Society,1997:145. |
| [38] | Tortorelli P F;DeVan J H .Behavior of iron aluminides in oxidizing and oxidizing/sulfidizing environments[J].Mater Sci Eng A,1992,153:573. |
| [39] | Haraguchi T;Yoshimi K;Yoo MH;Kato H;Hanada S;Inoue A .Vacancy clustering and relaxation behavior in rapidly solidified B2FeAl ribbons[J].Acta materialia,2005(13):3751-3764. |
| [40] | He Y;Poon S J;Shiflet G J .Synthesis and properties of metallic glasses that contain aluminum[J].SCIENCE,1988,241(4873):1640. |
| [41] | Louzguine DV.;Inoue A.;Takeuchi A. .New amorphous alloys in Al-Si-Fe-TM (TM = Cr, Mn, V) systems and their crystallization behavior[J].Journal of Materials Science Letters,1998(17):1439-1442. |
| [42] | Liu BX.;Zhang Q.;Lai WS. .Irradiation induced amorphization in metallic multilayers and calculation of glass-forming ability from atomistic potential in the binary metal systems [Review][J].Materials Science & Engineering, R. Reports: A Review Journal,2000(1/2):1-48. |
| [43] | Ouyang Y F;Zhang J;Chen H M;Liao S Z Zhong X P .Crystallization study of amorphous Al82Fe5Ni5Ce8 alloy[J].Journal of Alloys and Compounds,2008,454(01):359. |
| [44] | Tavoosi M;Karimzadeh F;Enayati M H .Formation and characterization of amorphous-nanocrystalline Al80Fe10M10 [M=Fe,Nb,Ti,Ni,(Ni0 5Ti0 5)] alloys[J].J Alloys Compd,2013,551:584. |
| [45] | Chrobaka A;Nosenkob V;Haneczokc G;Boichyshynd L Koturd B Bajoreka A Zivotskye O Hendrych A .Effect of rare earth additions on magnetic properties of Fe82Nb2B14RE2(RE=Y,Gd,Tb and Dy)amorphous alloys[J].Materials Chemistry and Physics,2011,130(1-2):603. |
| [46] | Shirakawa K;Aoki K;Masumoto T .Thermal stability,magnetic and electrical properties in amorphous RE-Al alloys[J].JOURNAL OF NON-CRYSTALLINE SOLIDS,1984,61-62:1371. |
| [47] | N.S. Uporova,S.A. Uporov,V.E. Sidorov.Magnetic susceptibility of Al2RE compounds in crystal and liquid states[J].稀土学报（英文版）,2011(08):768-771. |
| [48] | SONG Jie,YUE Ming,ZUO Jianhua,ZHANG Zirui,LIU Weiqiang,ZHANG Dongtao,ZHANG Jiuxing.Structure and magnetic properties of bulk nanocrystalline Nd-Fe-B permanent magnets prepared by hot pressing and hot deformation[J].稀土学报（英文版）,2013(07):674-678. |
| [49] | WANG Yupu,YOU Caiyin,WANG Junwei,TIAN Na,LU Zhengxin,GE Liling.Coercivity enhancement of Nd2Fe14B/α-Fe nanocomposite magnets through neodymium diffusion under annealing[J].稀土学报（英文版）,2012(08):757-760. |
| [50] | Akihisa Inoue;Tao Zhang;Wei Zhang;Akira Takeuchi .Bulk Nd-Fe-Al Amorphous Alloys with Hard Magnetic Properties[J].Materials Transactions, JIM,1996(2):99-108. |
| [51] | Bai Q;Xu H;Tan X H .Magnetic properties of Fe63-xNd37 Alx(x=5,8,10,12)alloys made by suction casting[J].J Yunnan Univ (in Chin ),2005,27(3A):267. |
| [52] | Cardoso KR.;Lieblich M.;Botta WJ.;Escorial AG. .Amorphous and nanostructured AI-Fe-Nd powders obtained by gas atomization[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2001(1/2):89-97. |
| [53] | Inoue A;Zhang T .Thermal stability and glass-forming ability of amorphous Nd-Al-TM(TM=Fe, Co, Ni or Cu)alloys[J].Mater Sci Eng A,1997,226:393. |
| [54] | Fan GJ.;Roth S.;Eckert J.;Schultz L.;Loser W. .Glass-forming ability and magnetic properties of Nd70-xFe20Al10Cox alloys[J].Journal of Materials Research,2000(7):1556-1563. |
| [55] | Eshelby J D .Distortion of a crystal by point imperfections[J].Journal of Applied Physics,1954,25(02):255. |
| [56] | Eshelby J D .The continuum theory of lattice defects[J].Solid State Physics,1956,3:79. |
| [57] | Mansoori G A;Carnahan N F;Starling K E;Leland T W .Equilibrium thermodynamic properties of the mixture of hard spheres[J].Journal of Chemical Physics,1971,54:1523. |
| [58] | Smith C J.Metal Reference Book[M].London:But-terworth,1976:100. |
| [59] | Bhatt J;Jiang W;Junhai X;Qing W Dong C Murty B S .Optimization of bulk metallic glass forming compositions in Zr-Cu-Al system by thermodynamic modeling[J].Inter-metallics,2007,15(05):716. |
| [60] | Oleszak D;Shingu P H .Amorphous Fe-Al alloys obtained by mechanical alloying[J].Materials Science Forum,1996,235:91. |
| [61] | Cheng X Y;Ouyang Y F;Shi H W;Zhong X P Du Y Tao X M .Nano-amorphous(FeAl)1-xZrx alloys prepared by mechanical alloying[J].Journal of Alloys and Compounds,2006,421(01):314. |
| [62] | Ouyang Y;Chen HM;Zhong XP;Du Y .(FeAl3)(1-x)Zr-x amorphous alloys prepared by mechanical alloying[J].Physica, B. Condensed Matter,2007(2):380-384. |
| [63] | Hongmei Chen;YifangOuyang;DeboGuo;ShuzhiLiao;XiapingZhong;YongDu;YongLiu .The formationandcrystallizationforamorphousAlFeZr4 preparedby mechanicalalloying[J].Physica, B. Condensed Matter,2010(8):2005-2008. |
| [64] | Kimura H;Wang L;Inoue A .Formation,thermal stability and mechanical properties of new amorphous Al89Fe10Zr1 alloy[J].Materials Transactions JIM,1998,39(08):866. |
| [65] | Ohnuma S;Shirakawa K;Nose M;Kanehira J, Masumoto T.Aging effect on the curie temperature of Fe-Zr base amorphouse alloys[A].Sendai,Japan,1982:1203. |
| [66] | Kim M C;McNallan M J .Oxidation and crystallization studies of Fe22.5Al10Zr rapidly solidified metallic glass ribbons[J].Mater Sci Eng A,1991,134:1078. |
| [67] | Zhang T;Inoue A .New glassy Zr-Al-Fe and Zr-Al-Co al-loys with a large supercooled liquid region[J].Materials Transactions JIM,2002,43:267. |
| [68] | Wang L M;Ma L Q;Kimura H;Inoue A .Amorphous forming ability and mechanical properties of rapidly so-lidified Al-Zr-LTM(LTM=Fe,Co,Ni and Cu)alloys[J].Materials Letters,2002,52(01):47. |
| [69] | Vigier G;Ortiz-Mendez U;Merle P;Thollet G Fouquet F .Microstructural stability of rapidly quenched Al-Fe alloys:influence of zirconium[J].Material Science and Engineering,1988,98:191. |
| [70] | Tsai A P;Inoue A;Masumoto T .Formation of metal-metal type aluminum-based amorphous alloys[J].Metallurgical and Materials Transactions A:Physical Metallurgy and Materials Science,1988,19(05):1369. |
| [71] | Hongmei Chen,Yixin Liu,Changyou Fan,Yifang Ouyang,Xiaping Zhong,Yong Du,Zhanpeng Jin.The composition range of amorphous forming for Al-Fe-Zr[C].第十四届全国相图会议暨国际相图与材料设计研讨会论文集,2008:13-18. |
| [72] | Zhou F;Lück R;Scheffer M;Lang D Lu K .The crystal-lization process of amorphous Al80Fe20 alloy powders prepared by ball milling[J].JOURNAL OF NON-CRYSTALLINE SOLIDS,1999,250:704. |
| [73] | Akihisa Inoue .Amorphous, nanoquasicrystalline and nanocrystalline alloys in Al-based systems[J].Progress in materials science,1998(5):365-520. |
| [74] | Massalski T B;Murray J L;Bennett L H;Baker H.Binary Alloy Phase Diagrams[M].Metals Park,Ohio:ASM,1986 |
| [75] | Li, J.H.;Dai, Y.;Cui, Y.Y.;Liu, B.X. .Atomistic theory for predicting the binary metallic glass formation[J].Materials Science & Engineering, R. Reports: A Review Journal,2011(1/2):1-28. |
| [76] | Gudzenko V N;Polesya A F .Structure of splat cooled from liquid-state zirconium-aluminium alloys[J].Fizika Metallov I Metallovedenie,1975,39:1313. |
| [77] | Ma E;Atzmon M .Enthalpies of formation and crystalliza-tion of amorphous Zr1-xAlx and Zr1-xNix alloys:calcula-tions compared with measurements[J].Journal of Alloys and Compounds,1993,194(02):235. |
| [78] | Ma E;Atzmon M .Calorimetric evidence for polymor-phous constraints on metastable Zr-Al phase formation by mechanical alloying[J].Physical Review Letters,1991,67(09):1126. |
| [79] | Fecht H J;Han G;Fu Z;Johnson W L .Metastable phase formation in the Zr-Al binary system induced by me-chanical alloying[J].Journal of Applied Physics,1990,67(04):1744. |
| [80] | Yamada M;Terashima Y;Tanaka K .X-ray diffraction study of local atomic structures in amorphous Nd-Fe-B al-loys[J].Materials Transactions JIM,1993,34(10):895. |
| [81] | Siratori K;Nagayama K;Ino H;Saito N Nakagawa Y .Appearance of high-coercivity in Fe-Nd amorphous alloys[J].IEEE Transactions on Magnetics,1987,23(05):2302. |
| [82] | Tanaka K;Yamada M;Okamoto T;Narita Y, Takaki H .Photoemission study of electronic structures of Nd-Fe and Nd-Fe-B alloy glasses[J].Mater Sci Eng A,1994,181:932. |
| [83] | Croat J J .Crystallization and magnetic properties of melt-spun neodymium-iron alloys[J].Journal of Magnetism and Magnetic Materials,1981,24(02):125. |
| [84] | Buschow K H J .Short-range order and thermal stability in amorphous alloys[J].Journal of Physics F:Metal Physics,1984,14(03):593. |
| [85] | Altounian Z;Volkert C A;Strom-Olsen J O .Crystalliza-tion characteristics of Fe-Zr metallic glasses from Fe43Zr57 to Fe20Zr80[J].Journal of Applied Physics,1985,57(06):1777. |
| [86] | Hellman F;van Dover R B;Gyorgy E M .Direction of the easy axis in amorphous Tb-Fe[J].Journal of Applied Physics,1987,61(08):3249. |
| [87] | Eckert J;Schultz L;Urban K .Glass-forming ranges in transition metal-Zr alloys prepared by mechanical alloying[J].JOURNAL OF THE LESS-COMMON METALS,1988,145:283. |
| [88] | Krauss W;Politis C;Weimar P .Preparation and compac-tion of mechanically alloyed amorphous materials[J].Metal Powder Report,1988,43:231. |
| [89] | Hellstern E;Schultz L .Amorphization of transition metal Zr alloys by mechanical alloying[J].Applied Physics Letters,1986,48(02):124. |
| [90] | Hellstern E;Schultz L .Glass forming ability in mechani-cally alloyed Fe-Zr[J].Applied Physics Letters,1986,49(18):1163. |
| [91] | Hellstern E;Schultz L .Formation and properties of me-chanically alloyed amorphous Fe-Zr[J].Material Science and Engineering,1988,97:39. |
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