欢迎登录材料期刊网

材料期刊网

高级检索

A new aluminosilicate long-lasting phosphor with composition of NaAlSiO4:Eu2+,Ho3+ was synthesized and investigated. Under UV light excitation, the phosphor emitted yellow light corresponding to the characteristic emission of Eu2+ due to 5d-4f transi-tion.Bright yellow phosphorescence sustaining for more than 30 min was observedafter ceasing the excitation. The phosphorescence intensity decay obeyed a t-1 decay law, indicating a tunneling electron-hole recombination process in the phosphor. Four peaks ap-peared in the thermoluminescence curve and the ones at 322 and 370 K were thought to account for the long lasting phosphorescence at room temperature. The Ho3+ ion incorporated into the phosphor did not give any light but dramatically increased the intensities of both photoluminescence and phosphorescence via promoting defect levels in the phosphor.

参考文献

[1] Matsuzawa T.;Takeuchi N.;Murayama Y.;Aoki Y. .NEW LONG PHOSPHORESCENT PHOSPHOR WITH HIGH BRIGHTNESS, SRAL2O4-EU2+,DY3+[J].Journal of the Electrochemical Society,1996(8):2670-2673.
[2] Tianzhi Zhang;Qiang Su .Rare-earth materials for use in the dark[J].Journal of the Society for Information Display,2000(1):27-30.
[3] Lin Y L;Tang Z L;Zhang Z T .Preparation of long-af-terglow Sr4Al14O25-based luminescent material and its op-tical properties[J].Materials Letters,2001,51:14.
[4] Setlur AA;Srivastava AM;Pham HL;Hannah ME;Happek U .Charge creation, trapping, and long phosphorescence in Sr2MgSi2O7 : Eu2+, RE3+[J].Journal of Applied Physics,2008(5):053513-1-053513-6-0.
[5] Jiang L;Chang C K;Mao D L;Feng C L .Luminescent properties of Ca2MgSi2O7 phosphor activated by Eu2+,Dy3+ and Nd3+[J].Optics Letters,2004,27:51.
[6] Kuang JY;Liu YL;Zhang JX;Huang LH;Rong JH;Yuan DS .Blue-emitting long-lasting phosphor, Sr3Al10SiO20 : Eu2+,Ho3+[J].Solid State Communications,2005(1):6-10.
[7] Liu L Y;Li C Y;Wang S B;Su Q .Redshift phenome-non of the excitation light of long life emission phos-phor[J].Applied Physics Letters,2006,88:241107.
[8] Pang R;Li C Y;Zhang S;Su Q .Luminescent properties of a new blue long-lasting phosphor Ca2P2O7:Eu2+,Y3+[J].Materials Chemistry and Physics,2009,113:215.
[9] Guo Y Z;Yu X B;Liu J;Yang X Y .Photoluminescence of Eu2+-activated Na1-xAl1-xSi1+xO4 upon UV excitation[J].Journal of Rare Earths,2010,28:34.
[10] Jihae Kim;Hideki Kato;Masato Kakihana .Control of NaAlSiO_4:Eu~(2+) photoluminescence properties by charge-compensated aliovalent element substitutions[J].Journal of information display,2012(3):97-100.
[11] Han J Y;Im W B;Kim D;Cheong S H Lee G Jeon D Y .New full-color-emitting phosphor,Eu2+-doped Na2-xAl2-xSixO4 obtained using phase transitions for solid-state white lighting[J].Journal of Materials Chemistry,2012,22:5374.
[12] Jo D S;Luo Y Y;Senthil K;Toda K Kim B S Masaki T Yoon D H .Synthesis and photoluminescence properties of new NaAlSiO4:Eu2+ phosphors for near-UV white LED applications[J].Optical Materials,2012,34:696.
[13] Tait K T;Sokolova E;Hawthorne F C .The crystal chemis-try of nepheline[J].Canadian mineralogist,2003,41:61.
[14] Shannon R D .Revised effective ionic radii and systematic studies of interatomic distances in halides and chalco-genides[J].Acta Cryst,1976,A32:751.
[15] 钟丹,胡小野,李振华,李永绣.镨和镱掺杂Ba2 SiO4:Eu2+荧光材料的合成与发光性能[J].中国稀土学报,2009(01):36-39.
[16] Kodama N;Sasaki N;Yamaga M;Masui Y .Long-lasting phosphorescence of Eu2+ in melilite[J].Journal of Luminescence,2001,94-95:19.
[17] Lin G;Dong G P;TanD Z;Liu X F Zhang Q Chen D P Qiu J R Zhao Q Z Xu Z Z .Long lasting phosphorescence in oxygen-deficient zinc-boron-germanosilicate glass-ce-ramics[J].Journal of Alloys and Compounds,2010,504:177.
[18] Li CY.;Yu YN.;Wang SB.;Su Q. .Photo-stimulated long-lasting phosphorescence in Mn2+-doped zinc borosilicate glasses[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2003(3):191-196.
[19] McKeever S W S;Prokic M;Townsend P D.Thermolu-minescence Dosimetery Materals[A].Ashford,UK:Nuclear Technology Press,1995:182.
[20] Chen R .On the calculation of activation energies and fre-quency factors from glow curves[J].Journal of Applied Physics,1969,40:570.
[21] 李成宇,苏锵,邱建荣.稀土元素掺杂长余辉发光材料研究的最新进展[J].发光学报,2003(01):19-27.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%