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The Ce-TiO2/KL (diatomite) ball photocatalyst was prepared and characterized based on the pretreated diatomite. The re-sults showed that comparing with the crude diatomite, proper pretreatment could significantly improve its SiO2 purity and specific surface area. The surface of diatomite was clear with uniform pore structure and big pore size. With diatomite ball as carrier, the sup-ported Ce-TiO2/KL ball photocatalyst was prepared by sol-gel method. The photocatalytic performances of the supported Ce-TiO2/ KL ball and Ce-TiO2/KL powder photocatalysts under various preparation conditions were studied in view of photocatalytic degrada-tion rate of Rhodamine B (Rh B) solution. The degradation rate of the ball photocatalysts for Rh B reached 94.6% and could be re-used for many times, which showed much better photocatalytic performance and stability than powder photocatalysts.

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