Monophthalocyanine complexes of samarium and terbium with axial ligands:synthesis, structure and optoelectronic properties

稀土学报(英文版), 2014, (12): 1101-1108. doi: 10.1016/S1002-0721(14)60189-7

Alexander A Maleev ^1, , Anatoly P Pushkarev ^2, , Vasily A Ilichev ^3, , Mikhail A Lopatin ^4, , Maxim A Samsonov ^5, , Georgy K Fukin ^6, , Georgy L Pakhomov ^7, , Vladislav V Travkin ^8, , Ivan D Grishin ^9, , Mikhail N Bochkarev ^10,

1.G. A. Razuvaev Institute of 0rganometal ic Chemistry, Russian Academy of Sciences, Tropinina str. 49, 603950 Nizhny Novgorod, Russia

2.G. A. Razuvaev Institute of 0rganometal ic Chemistry, Russian Academy of Sciences, Tropinina str. 49, 603950 Nizhny Novgorod, Russia

3.G. A. Razuvaev Institute of 0rganometal ic Chemistry, Russian Academy of Sciences, Tropinina str. 49, 603950 Nizhny Novgorod, Russia

4.G. A. Razuvaev Institute of 0rganometal ic Chemistry, Russian Academy of Sciences, Tropinina str. 49, 603950 Nizhny Novgorod, Russia

5.G. A. Razuvaev Institute of 0rganometal ic Chemistry, Russian Academy of Sciences, Tropinina str. 49, 603950 Nizhny Novgorod, Russia

6.G. A. Razuvaev Institute of 0rganometal ic Chemistry, Russian Academy of Sciences, Tropinina str. 49, 603950 Nizhny Novgorod, Russia

7.Institute for Physics of Microstructures, Rus-sian Academy of Sciences, 7 ul. Akademicheskaya, 603950 Nizhny Novgorod, Russia

8.Institute for Physics of Microstructures, Rus-sian Academy of Sciences, 7 ul. Akademicheskaya, 603950 Nizhny Novgorod, Russia

9.Department of 0rganic Chemistry, Nizhny Novgorod State University, 23 Gagarin Avenue, 603950 Nizhny Novgorod, Russia

10.G. A. Razuvaev Institute of 0rganometal ic Chemistry, Russian Academy of Sciences, Tropinina str. 49, 603950 Nizhny Novgorod, Russia

基金项目: the Russian Foundation of Basic Research(13-0397046,13-02-97044) grant(the agreement of August 27,2013№02.В.49.21.0003 between The Ministry of Education and Science of the Russian Federation and Lobachevsky State Uni-versity of Nizhni gorod)

Monophthalocyanine complexes of samarium and terbium with axial ligands:synthesis, structure and optoelectronic properties

Keywords： phthalocyanine

The monophthalocyanine complexes of samarium and terbium containing axial 2-mercaptobenzothiazole (PcSm(MBT) (1)), 2-(2-benzoxazol-2-yl) phenolate (PcTb(OON) (2)) or 2-(2-benzothiazol-2-yl)phenolate (PcTb(SON) (3)) ligands were synthe-sized and identified by elemental, LDI-TOF and X-ray (for 1) analysis. Photoluminescence (PL) and electroluminescence (EL) spec-tra of the compounds contained only emission bands of phthalocyanine and axial ligands but did not contain the bands of f-f transi-tions. It was found that among the complexes 1, 2, 3 the latter had highest photoconductivity (~10–7 S/cm) and photovoltaic properties. An organic photovoltaic device (OPV) of configuration of ITO/3/C60/Alq3/Al revealed open-circuit voltage (VOC) of 0.24 V and short current density (ISC) of 0.3μA/cm2 under illumination by a xenon lamp at 17 mW/cm2.

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Monophthalocyanine complexes of samarium and terbium with axial ligands:synthesis, structure and optoelectronic properties

参考文献