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LaFeO3 was used to improve the hydrogen storage properties of MgH2. The MgH2+20 wt.%LaFeO3 composite was pre-pared by ball milling method. The composite could absorb 3.417 wt.% of hydrogen within 21 min at 423 K while MgH2 only uptaked 0.977 wt.% hydrogen under the same conditions. The composite also released 3.894 wt.% of hydrogen at 623 K, which was almost twice more than MgH2. The TPD measurement showed that the onset dissociation temperature of the composite was 570 K, 80 K lower than the MgH2. Based on the Kissinger plot analysis of the composite, the activation energyEdes was estimated to be 86.69 kJ/mol, which was 36 kJ/mol lower than MgH2. The XRD and SEM results demonstrated that highly dispersed LaFeO3 could be pre-sented in MgH2, benefiting the reduction of particle size and also acting as an inhibitor to keep the particles from clustering during the ball-milled process.

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