欢迎登录材料期刊网

材料期刊网

高级检索

Sr1.995–1.5xGdxSiO4:0.005Eu2+ phosphor series withx=0–0.08 molfor near-ultraviolet white light-emitting diodes (NUV w-LEDs) were synthesized via solid-state reaction method. XRD profile pattern and refinement results demonstrated that doping Gd3+ ions resulted in the phase transformation (β-Sr2SiO4→α’-Sr2SiO4). The photoluminescence spectrum of the sample withx=0 mol dis-played two emission peaks centered at 470 and 525 nm. The two-peak spectra became one-peak spectra with the Gd3+ concentration increasing. Actually, the fitting results demonstrated that the one-peak spectra were still composed of two single emission spectra. The photoluminescence intensity was improved and the CIE chromaticity coordinates were adjusted via doping Gd3+.

参考文献

[1] Nakamura S .Present performance of InGaN based blue/green/yellow LEDs[J].Proc SPIE,1997,3002:26.
[2] Hsu C H;Jagannathan R;Lu C H .Luminescent enhance-ment with tunable emission in Sr2SiO4:Eu2+ phosphors for white LEDs[J].MATERIALS SCIENCE & ENGINEERING B,2010,167:137.
[3] Bandi V R;Nien Y T;Chen I G .Enhancement of white light emission from novel Ca3Y2Si3O12:Dy3+ phosphors with Ce3+ ion codoping[J].Journal of Applied Physics,2010,108:23111.
[4] Zhang, XM;Choi, N;Park, K;Kim, J .Orange emissive Sr3Al2O5Cl2:Eu2+ phosphor for warm-white light-emitting diodes[J].Solid State Communications,2009(25/26):1017-1020.
[5] Zhang X M;Wang J;Wu H;Zhang J H Su Q .One-step synthesis and double emission(Ca1+x-yEuy)Ga2S4+x phos-phor for white LEDs[J].Materials Letters,2009,63:340.
[6] Wu, ZC;Liu, J;Gong, ML .Thermally stable luminescence of SrMg2(PO4)(2): Eu2+ phosphor for white light NUV light-emitting diodes[J].Chemical Physics Letters,2008(1/3):88-90.
[7] Song W S;Kim Y S;Yang H .Yellow-emitting phosphor of Sr3B2O6:Eu2+ for application to white light-emitting di-odes[J].Materials Chemistry and Physics,2009,117:500.
[8] Kim, D.-H.;Ryu, J.H.;Cho, S.-Y. .Light emitting properties of SiAlON:Eu~(2+) green phosphor[J].Applied physics, A. Materials science & processing,2011(1):79-83.
[9] Xie R J;Hirosaki N;Mitomo M;Yamamoto Y, Suehiro T, Sakuma K .Optical properties of Eu2+ inα-SiAlON[J].J Phys Chem , B,2004,108:12027.
[10] 柏朝晖,卢菲菲,于晶晶,张舒婷,张云鹏,张希艳.Sr2Si5N8:Eu2+荧光粉的制备与发光性能[J].无机化学学报,2010(06):1003-1007.
[11] Li H;Yang H K;Moon B K;Choi B C Jeong J H Jang K Lee H S Yi S S .Color-conversion and photoluminescence properties of Ba2MgW(Mo)O6:Eu phosphor[J].Journal of Alloys and Compounds,2011,509:8788.
[12] Gu Y X;Zhang Q H;Li Y G;Wang H Z .Simultaneous tuning for excitation and emission of N doped Sr2SiO4:Eu for white light LEDs[J].Journal of Alloys and Compounds,2011,509:L109.
[13] WANG Xiaochun,ZHANG Xiyan,WANG Chen,QIN Weida,SUN Jiaxun.Influences of phase composition on Sr3SiO5∶Eu2+ luminous performance[J].稀土学报(英文版),2013(05):456-460.
[14] Zhao C;Zhu D C;Gao W;Tu M J Luo L Han T Jing X L .A near-ultraviolet(NUV)converting green-yellow Ca2AlMg0.5Si1 5O7:Eu2+ phosphor for white light-emit-ting-diodes(w-LEDs)[J].Chem Eng J,2014,254:486.
[15] Ma X L;Zhang W D;Guo H J;Liu R H Liu Y H He H Q Peng P Chen L .Synthesis and luminescence properties of Sr3-z(AlxSi1-x)O5-xFx:zCe3+ phosphors[J].Journal of Rare Earths,2013,31(7):665.
[16] Ye, S.;Xiao, F.;Pan, Y.X.;Ma, Y.Y.;Zhang, Q.Y. .Phosphors in phosphor-converted white light-emitting diodes: Recent advances in materials, techniques and properties[J].Materials Science & Engineering, R. Reports: A Review Journal,2010(1):1-34.
[17] Zeuner M;Pagano S;Schnick W .Nitridosilicates and oxonitridosilicates:from ceramic materials to structural and functional diversity[J].ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2011,50:7754.
[18] Li Y Q;Hirosaki N;Xie R J;Takeda T Mitomo M .Yel-low-orange-emitting CaAlSiN:Ce3+ phosphor:structure,photoluminescence,and application in white LEDs[J].CHEMISTRY OF MATERIALS,2008,20:6704.
[19] Liu, H.;Hao, Y.;Wang, H.;Zhao, J.;Huang, P.;Xu, B. .Luminescent properties of ~R doped Sr_2SiO _4:Eu~3(R=Li, Na and K) red-emitting phosphors for white LEDs[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2011(11):2422-2426.
[20] Gupta, S.K.;Mohapatra, M.;Kaity, S.;Natarajan, V.;Godbole, S.V. .Structure and site selective luminescence of solgel derived Eu:Sr _2SiO _4[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2012(6):1329-1338.
[21] Hsu W H;Sheng M H;Tsai M S .Preparation of Eu-acti-vated strontium orthosilicate(Sr1.95SiO4:Eu0 05)phosphor by a sol-gel method and its luminescent properties[J].J Al-loys Compd,2009,467:491.
[22] Kalaji A;Mikami M;Cheetham A K .Ce3+-activatedγ-Ca2SiO4 and other olivine-type ABXO4 phosphors for solid-state lighting[J].CHEMISTRY OF MATERIALS,2014,26:3966.
[23] Li Y;Wang Y;Gong Y;Xu X Zhang F .Photoionization behavior of Eu2+-doped BaMgSiO4 long-persisting phos-phor upon UV irradiation[J].ACTA MATERIALIA,2011,59:3174.
[24] Denault KA;Brgoch J;Gaultois M W;Mikhailovsky A Petry R Winkler H DenBaars S P Seshadri R .Conse-quences of optimal bond valence on structural rigidity and improved luminescence properties in Sr[J].CHEMISTRY OF MATERIALS,2014,26:2275.
[25] Yang, R.-Y.;Chen, H.-Y.;Chang, S.-J.;Yang, Y.-K. .Effect of Eu ~(3+) concentration on microstructure and photoluminescence of Sr _2SiO _4:Eu ~(3+) phosphors prepared by microwave assisted sintering[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2012(3):780-783.
[26] Park S H;Yoon H S;Boo H M;Jang H G Lee K H Im W B .Efficiency and thermal stability enhancements of Sr2SiO4:Eu2+ phosphor via Bi3+ Co-doping for solid-state white lighting[J].Japanese Journal of Applied Physics,2012,51:22602.
[27] Wang Qi,Qiu Jian-Bei,Song Zhi-Guo,Zhou Da-Cheng,Xu Xu-Hui.Green long-after-glow luminescence of Tb3+ in Sr2SiO4[J].中国物理B(英文版),2014(06):266-270.
[28] 周小军,熊兆贤,薛昊,林一森,宋春晓.Hydrothermal synthesis and photoluminescent properties of Li2Sr0.996SiO4:Pr3+0.004 phosphors for white-LED lightings[J].稀土学报(英文版),2015(03):244-248.
[29] Miao S H;Xia Z G;Zhang J;Liu Q L .Increased Eu2+ content and codoping Mn2+ induced tunable full-color emitting phosphor Ba1.55Ca0 45SiO4:Eu2+,Mn2+[J].Inorganic Chemistry,2014,53:10386.
[30] Gupta S K;Bhide M K;Kadam R M;Natarajan V God-bole S V .Nanorods of white light emitting Sr2SiO4:Eu2+:microemulsion-based synthesis,EPR,photoluminescence,and thermoluminescence studies[J].J Exp Nanosci,2013,10:610.
[31] Gu Y X;Zhang Q H;Li Y G;Wang H Z .Simultaneous tuning for excitation and emission of N doped Sr2SiO4:Eu for white light LEDs[J].Journal of Alloys and Compounds,2011,509:L109.
[32] YU Hong,GAO Guimei,KONG Li,LI Guanghuan,GAN Shucai,HONG Guangyan.Synthesis and luminescence properties of a novel red-emitting phosphor SrCaSiO4:Eu3+ for ultraviolet white light-emitting diodes[J].稀土学报(英文版),2011(05):431-435.
[33] Nishioka H;Watari T;Eguchi T;Yada M .Synthesis and luminescent properties of Sr2SiO4 phosphors.Symposium 7[J].Optical Ceramics,2011,18:102008.
[34] Kim JS;Jeon PE;Choi JC;Park HL .Emission color variation of M2SiO4 : Eu2+ (M=Ba, Sr, Ca) phosphors for light-emitting diode[J].Solid State Communications,2005(3):187-190.
[35] Jang H S;Yang H;Kim S W;Han J Y Lee S Jeon D Y .White light-emitting diodes with excellent color rendering based on organically capped CdSe quantum dots and Sr[J].Advanced Materials,2008,20:2696.
[36] Zhang T P .The calculation and application of electronega-tivity of ions[J].Journal of High Correspondence Education(Nature Science),2003,16(5):31.
[37] Rack PD.;Holloway PH. .The structure, device physics, and material properties of thin film electroluminescent displays [Review][J].Materials Science & Engineering, R. Reports: A Review Journal,1998(4):171-219.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%