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Eu2+-doped K2MgSi3O8 phosphors were synthesized by conventional solid-state reaction method. The phase formation of as-prepared samples was characterized by X-ray powder diffraction. The luminescence properties were investigated by the photolu-minescence excitation and emission spectra, decay curve and CIE coordinates. The phosphor showed bluish-green emission centered at 460 nm under the excitation of UV and near UV light with the wavelength range of 250–430 nm. Two Eu2+ emission centers ex-isted in the K2MgSi3O8:Eu2+ phosphor according to the luminescence spectra and the decay curves. The critical quenching concentra-tion of Eu2+ doping was determined to be 3.0 mol.% and the concentration quenching mechanism was dipole-dipole interactions be-tween Eu2+ ions. These results suggested that K2MgSi3O8:Eu2+ was a potential bluish-green phosphor candidate for white UV-LED.

参考文献

[1] 王育华;朱革;辛双宇;王倩;李艳艳;吴泉生;王闯;王希成;丁鑫;耿婉莹.Recent development in rare earth doped phosphors for white light emitting diodes[J].稀土学报(英文版),2015(1):1-12.
[2] Zhang, XG;Zhang, JL;Huang, JQ;Tang, XP;Gong, ML.Synthesis and luminescence of Eu2+-doped alkaline-earth apatites for application in white LED[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,20104(4):554-559.
[3] Ju Seong Kim;Hee Jo Song;Hee-Suk Roh;Dong Kyun Yim;Jun Hong Noh;Kug Sun Hong.Luminescent characteristics of green emitting Li-2Ca_2Si_2O_7:Eu~(2+) phosphor[J].Materials Letters,2012:112-115.
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