A series ofphosphorylation and blank CeSn0.8W0.6Ox/TiAl0.2Si0.1Oycatalystsprepared byextrusion molding were tested for NH3-SCR ofNO, and were characterized by techniques ofX-ray diffraction (XRD),Brumauer-Emmett-Teller(N2-BET),envi-ronmental scanning electron microscope(ESEM),temperature programmed reduction(H2-TPR)andtemperature programmed desorp-tion(NH3-TPD). Effects ofphosphorylation on catalytic activity and sulfur-resisting performance of the CeSn0.8W0.6Ox/TiAl0.2Si0.1Oy for NH3-SCR of NO were mainly studied. Results showed that the phosphorylation improved the catalytic activity and sulfur-resisting performance in anactive temperature window of300–440°C, and thephosphorylationcatalyst with 0.4wt.% H3PO4exhibited the best catalytic performance and the strongestsulfur-resisting performance. Analysis showed that the phosphorylation increased specif-ic surface area, enhanced the surface acidity and improved redox properties.
参考文献
[1] | Lijuan Xie;Fudong Liu;Kuo Liu.Inhibitory effect of NO2 on the selective catalytic reduction of NO_x with NH3 over one-pot-synthesized Cu-SSZ-13 catalyst[J].Catalysis science & technology,20144(4):1104-1110. |
[2] | Xiaoyan Shi;Fudong Liu;Lijuan Xie.NH3-SCR Performance of Fresh and Hydrothermally Aged Fe-ZSM-5 in Standard and Fast Selective Catalytic Reduction Reactions[J].Environmental Science & Technology: ES&T,20137(7):3293-3298. |
[3] | LIANG CHEN;JUNHUA LI;MAOFA GE.DRIFT Study on Cerium-Tungsten/ Titiania Catalyst for Selective Catalytic Reduction of NO_x with NH3[J].Environmental Science & Technology: ES&T,201024(24):9590-9596. |
[4] | Junhua Li;Huazhen Chang;Lei Ma.Low-temperature selective catalytic reduction of NO_x with NH3 over metal oxide and zeolite catalysts-A review[J].Catalysis Today,20111(1):147-156. |
[5] | Li, LL;Xu, J;Yuan, Q;Li, ZX;Song, WG;Yan, CH.Facile Synthesis of Macrocellular Mesoporous Foamlike Ce-Sn Mixed Oxides with a Nanocrystalline Framework by Using Triblock Copolymer as the Single Template[J].Small,200923(23):2730-2737. |
[6] | Fudong Liu;Hong He.Structure—Activity Relationship of Iron Titanate Catalysts in the Selective Catalytic Reduction of NO_x with NH3[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201040(40):16929-16936. |
[7] | Li, Y;Cheng, H;Li, DY;Qin, YS;Xie, YM;Wang, SD.WO3/CeO2-ZrO2, a promising catalyst for selective catalytic reduction (SCR) of NOx with NH3 in diesel exhaust[J].Chemical Communications,200812(12):1470-1472. |
[8] | Katariina Rahkamaa-Tolonen;Teuvo Maunula;Mari Lomma;Mika Huuhtanen;Riitta L.Keiski.The effect of NO_2 on the activity of fresh and aged zeolite catalysts in the NH_3-SCR reaction[J].Catalysis Today,20053/4(3/4):217-222. |
[9] | Liu ZM;Woo SI.Recent advances in catalytic DeNO(X) science and technology[J].Catalysis Reviews. Science and Engineering,20061(1):43-89. |
[10] | Surface science studies of selective catalytic reduction of NO: Progress in the last ten years[J].Surface Science: A Journal Devoted to the Physics and Chemistry of Interfaces,200910/12(10/12):1740-1750. |
[11] | Joshi, A;Rammohan, A;Jiang, Y;Ogunwumi, S.Density functional theory (DFT) study of the interaction of ammonia with pure and tungsten-doped ceria[J].Journal of Molecular Structure. Theochem: Applications of Theoretical Chemistry to Organic, Inorganic and Biological Problems,20091/3(1/3):73-81. |
[12] | Castegnaro, M.V.;Kilian, A.S.;Baibich, I.M.;Alves, M.C.M.;Morais, J..On the reactivity of carbon supported pd nanoparticles during NO reduction: Unraveling a metal-support redox interaction[J].Langmuir: The ACS Journal of Surfaces and Colloids,201323(23):7125-7133. |
[13] | Zhichun Si;Duan Weng;Xiaodong Wu.Lattice oxygen mobility and acidity improvements of NiO-CeO2-ZrO2 catalyst by sulfation for NO_x reduction by ammonia[J].Catalysis Today,20131(1):122-130. |
[14] | Tingting Gu;Yue Liu;Xiaole Weng.The enhanced performance of ceria with surface sulfation for selective catalytic reduction of NO by NH3[J].Catalysis Communications,20104(4):310-313. |
[15] | 纵宇浩;沈岳松;王玉云;韩冰;祝社民;眭国荣.Ce-Sn-W-Ox催化剂的配伍优化及脱硝影响因素[J].环境工程学报,2015(3):1329-1336. |
[16] | Wenqing Xu;Yunbo Yu;Changbin Zhang.Selective catalytic reduction of NO by NH3 over a Ce/TiO2 catalyst[J].Catalysis Communications,20086(6):1453-1457. |
[17] | Caixia Liu;Liang Chen;Junhua Li.Enhancement of Activity and Sulfur Resistance of CeO2 Supported on TiO2-SiO2 for the Selective Catalytic Reduction of NO by NH3[J].Environmental Science & Technology: ES&T,201211(11):6182-6189. |
[18] | Yuesong Shen;Yifan Ma;Shemin Zhu.Promotional effect of zirconium additives on Ti_(0.8)Ce_(0.2)O2 for selective catalytic reduction of NO[J].Catalysis science & technology,20123(3):589-599. |
[19] | Zhiwang Yang;Lengyuan Niu;Zhenhong Ma.Fabrication of highly active Sn/W mixed transition-metal oxides as solid acid catalysts[J].Transition Metal Chemistry,20113(3):269-274. |
[20] | Kim JR;Myeong WJ;Ihm SK.Characteristics in oxygen storage capacity of ceria-zirconia mixed oxides prepared by continuous hydrothermal synthesis in supercritical water[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,20071/2(1/2):57-63. |
[21] | Byoung-Whan Soh;In-Sik Nam.Effect of Support Morphology on the Sulfur Tolerance of V_2O_5/Al_2O_3 Catalyst for the Reduction of NO by NH_3[J].Industrial & Engineering Chemistry Research,200313(13):2975-2986. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%