采用浇铝法制备铜铝复合铸锭,研究液体铝与固体铜复合过程中过渡层的凝固过程与组织变化规律,结果表明,铜铝复合铸锭中过渡层由α(Al)+α(Al)?CuAl2共晶、α(Al)?CuAl2共晶、CuAl2+α(Al)?CuAl2共晶和Cu9Al4四种组织组成,浇注温度、铜板外表面强制冷却方式以及浇注后到开始强制冷却时间不影响过渡层内组织种类,但过渡层内各种组织占过渡层厚度的比例随工艺参数而变化。过渡层顶部的纯铝最先开始凝固,而后α相以枝晶的方式、CuAl2相以平面晶或胞晶方式分别从过渡层的两侧向过渡层内生长。铜板外表面冷却强度越强,α枝晶越发达,CuAl2相越容易长成平面晶。
The Cu?Al composite casts were prepared by the method of pouring molten aluminum. The solidification process and the microstructure of the transition layer were investigated during the recombination process of the liquid Al and the solid Cu. The results reveal that the microstructure of the transition layer in the Cu?Al composite cast consists of α(Al)+α(Al)?CuAl2 eutectic,α(Al)?CuAl2 eutectic, CuAl2+α(Al)?CuAl2 eutectic and Cu9Al4. Additionally, the pouring temperature, cooling mode of the Cu plate surface and start time of the forced cooling after pouring have no effect on the microstructure species. But the proportion of the various microstructures in the transition layer changes with the process parameters. The pure Al at the top of the transition layer starts to solidify first and then theα(Al) phase grows in a dendritic way, while the CuAl2 phase exhibits plane or cellular crystal growth from the two sides of the transition layer towards its interior. The stronger the cooling intensity of the Cu plate outer surface, the more developed the dendrite, and the easier it is for the CuAl2 phase to grow into a plane crystal.
参考文献
[1] | Alan Gibson.Emerging applications for copper-clad steel and aluminum wire[J].Wire Journal International,20082(2):142-148. |
[2] | D. C. Ko;S. K. Lee;B. M. Kim;H. H. Jo;H. Jo.Evaluation of copper coating ratio in steel/copper clad wire drwaing[J].Journal of Materials Processing Technology,20071/3(1/3):22-26. |
[3] | Hug, E.;Bellido, N..Brittleness study of intermetallic (Cu, Al) layers in copper-clad aluminium thin wires[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,201122(22):7103-7106. |
[4] | Mohammad Sadegh Mohebbi;Abbas Akbarzadeh.Fabrication of copper/aluminum composite tubes by spin-bonding process: experiments and modeling[J].The International Journal of Advanced Manufacturing Technology,20119/12(9/12):1043-1055. |
[5] | HENRYK PAUL;LIDIA LITYNSKA-DOBRZYNSKA;MARIUSZ PRAZMOWSKI.Microstructure and Phase Constitution Near the Interface of Explosively Welded Aluminum/Copper Plates[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,20138(8):3836-3851. |
[6] | 李小兵;祖国胤;王平.Al/Cu多层复合板的组织演化及其对力学性能的影响[J].中国有色金属学报(英文版),2015(1):36-45. |
[7] | Meguro, K.;O, M.;Kajihara, M..Growth behavior of compounds due to solid-state reactive diffusion between Cu and Al[J].Journal of Materials Science,201212(12):4955-4964. |
[8] | In-Kyu Kim;Sun Ig Hong.Effect of heat treatment on the bending behavior of tri-layered Cu/Al/Cu composite plates[J].Materials & design,2013May(May):590-598. |
[9] | Robert Uscinowicz.Experimental identification of yield surface of Al-Cu bimetallic sheet[J].Composites, Part B. Engineering,2013Dec.(Dec.):96-108. |
[10] | Vahid Yousefi Mehr;Mohammad Reza Toroghinejad;Ahmad Rezaeian.The effects of oxide film and annealing treatment on the bond strength of Al-Cu strips in cold roll bonding process[J].Materials & design,2014Jan.(Jan.):174-181. |
[11] | YA-JUN SU;XIN-HUA LIU;HAI-YOU HUANG.Interfacial Microstructure and Bonding Strength of Copper Cladding Aluminum Rods Fabricated by Horizontal Core-Filling Continuous Casting[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,201113(13):4088-4099. |
[12] | LY. Sheng;F. Yang;T.F. Xi;C. Lai;H.Q, Ye.Influence of heat treatment on interface of Cu/Al bimetal composite fabricated by cold rolling[J].Composites, Part B. Engineering,20116(6):1468-1473. |
[13] | T.G.Huang;Z.C.Lin.Hot rolling of an aluminum-copper sandwich flat strip with the three-dimensional finite element method[J].Journal of Materials Processing Technology,2000s1-3(s1-3):154-168. |
[14] | He LIANG;Zhiyong XUE;Chunjing WU;Qing LIU;Yuan WU.Research on continuous core-filling casting forming process of copper-clad aluminum bimetal composite material[J].金属学报(英文版),2010(03):206-214. |
[15] | LUO Jun-ting;ZHAO Shuang-jing;ZHANG Chun-xiang.Microstructure of aluminum/copper clad composite fabricated by casting-cold extrusion forming[J].中南大学学报(英文版),2011(04):1013-1017. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%