采用合金样与扩散偶相结合的方法,利用电子探针射线显微分析(EPMA)对 Al?Ti?Zr 三元系的1073 K 等温截面的相关系进行实验测定。结果表明:截面中存在一个 Al 含量(摩尔分数)达到16.3%的β(Ti,Zr)固溶体。Ti和 Zr 可以在大多数 Al?Zr 和 Ti?Al 二元中间化合物中相互取代。其中,Zr 在 Ti3Al 和 TiAl 中的最大固溶度分别达到17.9%和4.0%。该等温截面共包含16个单相区,27个两相区和14个三相平衡,没有检测到三元化合物。
Through alloy sampling combined with diffusion triple technique, phase equilibria in Al?Ti?Zr ternary system at 1073 K were experimentally determined with electron probe microanalysis (EPMA). Experimental results show that there is a solid solutionβ(Ti,Zr) which dissolves Al up to 16.3% (mole fraction). Ti and Zr can substitute each other in most Ti?Al and Al?Zr binary intermediate phases to a certain degree while the maximum solubility of Zr in Ti3Al and TiAl reaches up to 17.9% and 4.0% (mole fraction), respectively. The isothermal section consists of 16 single-phased regions, 27 two-phased regions and 14 three-phased regions. No ternary phase was detected.
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