为了明确热HCP马氏体对CoAl和CoNi合金形状记忆效应的作用,研究CoAl和CoNi合金形状记忆效应(SME)与应力诱发马氏体和热HCP马氏体之间的关系.采用原位金相观察合金深冷前后热诱发马氏体的变化,并研究其对应力诱发马氏体和形状记忆效应的影响.结果表明,CoAl和CoNi合金的形状记忆效应都来源于应力诱发HCP马氏体,热马氏体对两者形状记忆效应的贡献都是强化基体.CoAl合金形状记忆效应高于CoNi合金的原因是Al原子对基体更强的固溶强化作用导致CoAl合金基体强度高于CoNi合金强度.
To address the role of the HCP martensite in CoAl and CoNi shape memory alloys, the relationship between the shape memory effect (SME) and the content of the thermal and stress-induced HCP martensite was investigated in the solution-treated CoAl and CoNi alloys. In-situ optical observations were employed to investigate the contents of thermal HCP martensite before and after deep cooling and its influence on the stress-induced HCP martensite transformation and SME. The results show that the SME in both the CoAl and the CoNi alloys results from the stress-induced HCP martensite. The role of the thermal HCP martensite in both of them is the strengthening of the matrix. The much higher yield strength in the solution-treated CoAl alloy due to solution strengthening of Al is responsible for its better SME compared with the CoNi alloy.
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