欢迎登录材料期刊网

材料期刊网

高级检索

研究了活性炭负载的Cu-K-O复合氧化物催化剂上碳还原NO的反应.结果表明,K的加入可有效地提高CuO催化剂的活性和稳定性,当Cu/K的质量比为2时催化性能最佳.X射线衍射、X射线光电子能谱和程序升温脱附-质谱等结果表明,K与Cu间的协同作用可促进表面碳活化中心与表面氧物种生成CO2的反应,保持表面Cu2+活性中心的数量,从而有利于Cu2+/Cu+反应循环的进行.

参考文献

[1] Epling W S;Campbell L E;Yezerets A;Currier N W Parks J E .[J].Catalysis Review:Science and Engineering,2004,46:163.
[2] Roy S;Hegde M S;Madras G .[J].Applied Energy,2009,86:2283.
[3] Wojtowicz M A;Miknis F P;Grimes R W;Smith W W Serio M A .[J].Journal of Hazardous Materials B:Environmental Technologies,2000,74:81.
[4] Garcia-Garcia A;Man-Gomez M J;Linares-Solano A;Salinas-Martinez de Lecea C .[J].Fuel Processing Technology,1999,61:289.
[5] Man-Gomez M J;Raymundo-Pinero E;Garcia-Garcia A;Linares-Solano A Salinas-Martinez de Lecea C .[J].Applied Catalysis B:Environmental,1999,20:267.
[6] Xue Y Y;Lu G Z;Guo Y;Guo Y L Wang Y Q Zhang Z G .[J].Applied Catalysis B:Environmental,2008,79:262.
[7] Xue Y Y;Guo Y;Zhang Z G;Guo Y L Wang Y Q Lu G Z .[J].Applied Surface Science,2008,255:2591.
[8] Man-Gomez M J;Brandan S;Linares-Solano A;Salinas-Martinez de Lecea C .[J].Applied Catalysis B:Environmental,2000,25:11.
[9] Nejar N;Illan-Gomez MJ .Potassium-copper and potassium-cobalt catalysts supported on alumina for simultaneous NOx and soot removal from simulated diesel engine exhaust[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2007(26):261-268.
[10] Reichert D;Bockhorn H;Kureti S .[J].Applied Catalysis B:Environmental,2008,80:248.
[11] Zhu ZH.;Lu GQ.;Radovic LR. .Effects of acid treatments of carbon on N2O and NO reduction by carbon-supported copper catalysts[J].Carbon: An International Journal Sponsored by the American Carbon Society,2000(3):451-464.
[12] Lee Y W;Park J W;Jun S J;Choi D K Yie J E .[J].CARBO,2004,42:59.
[13] Mangun C L;Benak K R;Economy J;Foster K L .[J].CARBO,2001,39:1809.
[14] Mear F O;Essi M;Sistat P;Guimon M F Gonbcau D Pradel A .[J].Applied Surface Science,2009,255:6607.
[15] Batista J;Pintar A;Mandrino D;Jenko M Martin V .[J].Applied Catalysis A:General,2001,206:113.
[16] Wagner C D;Riggs W M;Moulder L E;Muilenberg G E.Handbook of X-Ray Photoelectron Spectroscopy[M].Eden Prairie,MN:Perkin-Elmer Corporation Physical Electronics Division,1979
[17] Barrabes N;Just J;Dafinov A;Medina F Fierro J L G Sueiras J E Salagre P Cesteros Y .[J].Applied Catalysis B:Environmental,2006,62:77.
[18] Nickolov R;Tsoncheva T;Mehandjiev D .[J].Fuel,2002,81:203.
[19] Chen S G;Yang R T .[J].Energy & Fuels,1997,11:421.
[20] Zhu ZH.;Lu GQ.;Yang RT. .New insights into alkali-catalyzed gasification reactions of carbon: Comparison of N2O reduction with carbon over Na and K catalysts[J].Journal of Catalysis,2000(1):77-87.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%