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  4. 从工业催化角度看分子筛催化剂未来发展的若干思考

催化学报 , 2012, 33(1): 22-38. doi: 10.1016/S1872-2067(10)60299-9

从工业催化角度看分子筛催化剂未来发展的若干思考

刘志成 1, , 王仰东 2, , 谢在库 3,

1.中国石油化工股份有限公司上海石油化工研究院,上海201208

2.中国石油化工股份有限公司上海石油化工研究院,上海201208

3.中国石油化工股份有限公司,北京100027

基金项目:   国家重点基础研究发展计划(973计划)(2009CB623504;2009CB623506)  

关键词： 沸石分子筛 , 工业催化剂 , 石油化工 , 未来发展 , 高效催化 , 经济合成 , 绿色环保

Thoughts on the Future Development of Zeolitic Catalysts from an Industrial Point of View

从工业催化的角度思考和探讨了分子筛催化剂合成、催化及应用方面存在的一些问题与挑战,并从沸石分子筛的高效催化、新结构分子筛合成与催化应用、沸石分子筛的经济合成、分子筛在绿色环保领域的新应用等几个方面,综述了国内外相关的最新研究进展,探讨了分子筛催化剂未来的发展方向.旨在引发人们对分子筛催化未来向经济、可控、高效催化、绿色环保和新应用等方面发展的思考与探索.

参考文献

[1] Plank C J.Heterogeneous Catalysis,Selected American Histories[A].Washington,DC:American Chemical Society,1983:253.
[2] Vermeiren W;Gilson J P .[J].Topics in Catalysis,2009,52:1131.
[3] 谢在库.新结构高性能多孔催化材料[M].北京:中国石化出版社,2010:4.
[4] 王亚军,唐颐,王星东.纳米沸石的合成、性质、组装及应用[J].石油化工,2002(03):217-223.
[5] Schoeman B J;Sterte J;Otterstedt J E .[J].Zeolites,1994,14:110.
[6] Tsapatsis M;Lovallo M;Okubo T;Davis M E Sadakata M .[J].Chemistry of Materials,1995,7:1734.
[7] Persson A E;Schoeman B J;Sterte J;Otterstedt J E .[J].Zeolites,1995,15:611.
[8] Camblor M A;Corma A;Mifsud A;Perez-Pariente J Valencia S .[J].Studies in Surface Science and Catalysis,1997,105:341.
[9] 柳云骐;刘春英;刘晨光 .[J].化学进展,2005,17:666.
[10] Yang H Q;Liu Zh Ch;Gao H X;Xie Z K .[J].Journal of Materials Chemistry,2010,20:3227.
[11] Choi M;Na K;Kim J;Sakamoto Y Terasaki O Ryoo R .[J].Nature,2009,461:246.
[12] Christensen C H;Johannsen K;Schmidt I;Christensen C H .[J].Journal of the American Chemical Society,2003,125:13370.
[13] Schmidt I;Boisen A;Gustavsson E;Stahl K Pehrson S Dahl S Carlsson A Jacobsen C J H .[J].Chemistry of Materials,2001,13:4416.
[14] 刘志成,孔德金,王仰东,谢在库.淀粉模板法合成介孔ZSM-5分子筛[J].石油学报（石油加工）,2008(z1):124-126,135.
[15] Zhu H B;Liu Zh Ch;Wang Y D;Kong D J Yuan X H Xie Z K .[J].Chemistry of Materials,2008,20:1134.
[16] Xiao F Sh;Wang L F;Yin C Y;Lin K F,Di Y,Li J X,Xu R R,Su D S,Schl(o)gl R,Yokoi T,Tatsumi T .[J].Angewandte Chemie International Edition,2006,45:3090.
[17] Zhu HB;Liu ZC;Kong DJ;Wang YD;Yuan XH;Me ZK .Synthesis of ZSM-5 with intracrystal or intercrystal mesopores by polyvinyl butyral templating method[J].Journal of Colloid and Interface Science,2009(2):432-438.
[18] Choi M;Cho H S;Srivastava R;Venkatesan C Choi D H Ryoo R .[J].Nature Materials,2006,5:718.
[19] Fan W;Snyder M A;Kumar S;Lee P S Yoo W C McCormick A V Lee Penn R Stein A Tsapatsis M .[J].Nature Materials,2008,7:984.
[20] 刘志成;王仰东;孔德金;谢在库.现代化工、冶金与材料技术前沿[A].北京:化学工业出版社,2009:557.
[21] Zhu H B;Liu Zh Ch;Kong D J;Wang Y D Xie Z K .[J].Journal of Physical Chemistry C,2008,112:17257.
[22] Yang H Q;Liu Zh Ch;Gao H X;Xie Z K .[J].Applied Catalysis A:General,2010,379:166.
[23] Thomas J;Ramdas S;Millward B .[J].New Scientist,1982,96:435.
[24] Xie S J;Liu Sh L;Liu Y;Li X J Zhang W P Xu L Y .[J].Microporous and Mesoporous Materials,2009,121:166.
[25] Niu X L;Song Y Q;Xie S J;Liu Sh L Wang Q X Xu L Y .[J].Catalysis Letters,2005,103:211.
[26] 谢素娟,刘盛林,张玲,徐龙伢.MCM-49与ZSM-35的共结晶及混合物的芳构化性能比较[J].石油学报（石油加工）,2009(z2):37-40.
[27] 祁晓岚,李斌,李士杰,刘希尧,林炳雄.BEA/MOR两相共生分子筛的酸性及其催化性能[J].催化学报,2006(03):228-232.
[28] Kaeding W W;Chu C;Young L B;Weinstein B Butter S A .[J].Journal of Catalysis,1981,67:159.
[29] Zhao G L;Teng J W;Xie Z K;Jin W Q Yang W M Chen Q L Tang Y .[J].Journal of Catalysis,2007,248:29.
[30] Xue N H;Chen X K;Nie L;Guo X F Ding W P Chen Y Gu M Xie Z K .[J].Journal of Catalysis,2007,248:20.
[31] Davis M E;Saldarriaga C;Montes C;Garces J Crowder C .[J].Nature,1988,331:698.
[32] Dessau R M;Schlenker J L;Higgins J B .[J].Zeolites,1990,10:522.
[33] Vogt E T C;Richardson J W Jr .[J].Journal of Solid State Chemistry,1990,87:469.
[34] Estermann M;McCusker L B;Baerlocher C;Merrouche A Kessler H .[J].Nature,1991,352:320.
[35] Huo Q S;Xu R R;Li S G;Ma Z G,Thomas J M,Jones R H,Chippindale A M.[J].Journal of the Chemical Society,Chemical Communications,1992:875.
[36] Loiseau T;Ferey G .[J].Journal of Solid State Chemistry,1994,111:403.
[37] Maeda K;Akimoto J;Kiyozumi Y;Mizukami F .[J].Angewandte Chemie International Edition,1995,34:1199.
[38] Khan M I;Meyer L M;Haushalter R C;Schweitzer A L Zubieta J Dye J L .[J].Chemistry of Materials,1996,8:43.
[39] Loiseau T;Ferey G .[J].Mater Res Soc Confer Proc,1996,431:27.
[40] Freyhardt C C;Tsapatsis M;Lobo R F;Balkus K J Jr Davis M E .[J].Nature,1996,381:295.
[41] Cavellec M;Greneche J M;Riou D;Ferey G .[J].Microporous Materials,1997,8:103.
[42] Wagner P;Yoshikawa M;Tsuji K;Davis M E,Lovallo M,Taspatsis M.[J].Chemical Communications,1997:2179.
[43] Li H L;Laine A;O'Keeffe M;Yaghi O M .[J].Science,1999,283:1145.
[44] Guillou N;Gao Q M;Nogues M;Morris R E,Hervieu M,Ferey G,Cheetham A K .[J].C R Acad Sci Ser IIc,1999,2:387.
[45] Yang G Y;Sevov S C .[J].Journal of the American Chemical Society,1999,121:8389.
[46] Guillou N;Gao Q M;Forster P M;Chang J-S,Nogues M,Park S-E,Ferey G,Cheetham A K .[J].Angewandte Chemie International Edition,2001,40:2831.
[47] Zhou Y M;Zhu H G;Chen Z X;Chen M Q,Xu Y,Zhang H Y,Zhao D Y .[J].Angewandte Chemie International Edition,2001,40:2166.
[48] Lin CH.;Lii KH.;Wang SL. .[Ga-2(DETA)(PO4)(2)]center dot 2H(2)O (DETA = diethylenetriamine): A novel porous gallium phosphate containing 24-ring channels[J].Journal of the American Chemical Society,2001(19):4649-4650.
[49] Cheetham A K;Fjellvg H;Gier T E;Kongshaug K O Lillerud K P Stucky G D .[J].Studies in Surface Science and Catalysis,2001,135:158.
[50] Corma A;Diaz Cabanas MJ;Martinez Triguero J;Rey F;Rius J .A large-cavity zeolite with wide pore windows and potential as an oil refining catalyst.[J].Nature,2002(6897):514-517.
[51] Castaneda R;Corma A;Fornes V;Rey F Rius J .[J].Journal of the American Chemical Society,2003,125:7820.
[52] Burton A;Elomari S;Chen C-Y;Medrud R C Chan I Y Bull L M Kibby C Harris T V Zones S I Vittoratos E S .[J].Chemistry-A European Journal,2003,9:5737.
[53] Strohmaier K G;Vaughan D E W .[J].Journal of the American Chemical Society,2003,125:16035.
[54] Paillaud J-L;Harbuzaru B;Patarin J;Bats N .[J].Science,2004,304:990.
[55] Corma A;Diaz Cabanas MJ;Jorda JL;Martinez C;Moliner M .High-throughput synthesis and catalytic properties of a molecular sieve with 18- and 10-member rings.[J].Nature,2006(7113):842-845.
[56] Sun J L;Bonneau C;Cantin A;Corma A Diaz-Cabanas M J Moliner M Zhang D L Li M R Zou X D .[J].Nature,2009,458:1154.
[57] Simancas R;Dari D;Velamazán N;Navarro M T Cantín A Jordá J L Sastre G Corma A Rey F .[J].Science,2010,330:1219.
[58] Jiang J X;Jorda J L;Diaz-Cabanas M J;Yu J H,Corma A .[J].Angewandte Chemie International Edition,2010,49:4986.
[59] Jiang J X;Jorda J L;Yu J H;Baumes L A Mugnaioli E Diaz-Cabanas M J Kolb U Corma A .[J].Science,2011,333:1131.
[60] Davis M E;Lobo R F .[J].Chemistry of Materials,1992,4:756.
[61] Harrison W T A;Gier T E;Stucky G D;Broach R W Bedard R A .[J].Chemistry of Materials,1996,8:145.
[62] Feng P Y;Bu X H;Tolbert S H;Stucky G D .[J].Journal of the American Chemical Society,1997,119:2497.
[63] Gier T;Bu X H;Feng P Y;Stucky G D .[J].Nature,1998,395:154.
[64] Tang LQ;Shi L;Bonneau C;Sun JL;Yue HJ;Ojuva A;Lee BL;Kritikos M;Bell RG;Bacsik Z .A zeolite family with chiral and achiral structures built from the same building layer[J].Nature materials,2008(5):381-385.
[65] Roth W J;Dorset D L .[J].Microporous and Mesoporous Materials,2011,142:32.
[66] Corma A;Corell C;Llopis F;Martínez A Pérez-Pariente J .[J].Applied Catalysis A:General,1994,115:121.
[67] Guarino R F;Li C H .[J].Hydrocarbon Engineering,1999,4:39.
[68] Maerz B;Chen S S;Venkat C R;Mazzone D N.[J].Hydrocabon Tech Intern,1996:21.
[69] Rouleau L;Lacombe S;Alario F;Merlen E,Kolenda F,Magne-Drisch J .[P].US 6 337 063,2002.
[70] Martens J A;Souverijns W;Verrelst W;Parton R,Groment G F,Jacobs P A .[J].Angewandte Chemie International Edition,1995,34:2528.
[71] Souverijns W.;Froment GF.;Jacobs PA.;Martens JA. .Hydrocracking of isoheptadecanes on Pt/H-ZSM-22: An example of pore mouth catalysis[J].Journal of Catalysis,1998(2):177-184.
[72] Zones SI.;Hwang SJ. .Synthesis of high silica zeolites using a mixed quaternary ammonium cation, amine approach: Discovery of zeolite SSZ-47[J].Chemistry of Materials,2002(1):313-320.
[73] Zones S I .[P].US 20 080 075 656,2008.
[74] Bull I;Muller U .[P].WO 2 011 064 186,2011.
[75] Lee G S;Nakagawa Y;Zones S I .[P].US 6 156 290,2000.
[76] Zones S I;Zhang G;Krishna K R;Biscardi J A,Marcantonio P,Vittoratos E .[P].US 20 050 092 651,2005.
[77] Blackwell C S;Broach R W;Gatter M G;Holmgren J S,Jan D-Y,Lewis G J,Mezza B J,Mezza T M,Miller M A,Moscoso J G,Patton R L,Rohde L M,Schoonover M W,Sinkler W,Wilson B A,Wilson S T .[J].Angewandte Chemie International Edition,2003,42:1737.
[78] Knight L M;Lewis G J .[J].Studies in Surface Science and Catalysis,2005,154A:171.
[79] Moscoso J G;Lewis G J;Gisselquist J L;Miller M A,Knight L M .[P].US 6 713 041,2004.
[80] 奈特 L M;刘易斯 G J;米勒 M A;莫斯科索 J G,吉塞尔奎斯特 J L,巴顿 R L,威尔逊 S T,詹登阳,柯斯特 S C .[P].CN 1 997 593,2007.
[81] Wang J Y;Song J W;Yin C Y;Ji Y Y Zou Y C Xiao F Sh .[J].Microporous and Mesoporous Materials,2009,117:561.
[82] 周朋燕,李晓峰,王裕鑫,武行洁,窦涛.导向剂法合成EU-1分子筛[J].石油学报（石油加工）,2008(z1):226-229.
[83] McWilliams J P;Rubin M K .[P].US 4 894 212,1990.
[84] Moini A;Valyocsik E W .[P].US 5 192 521,1993.
[85] Zones S I;Holtermann D;Innes R A .[P].US 5 200 377,1993.
[86] Nakagawa Y;Zones S I .[P].US 5 707 600,1998.
[87] Nakagawa Y .[P].US 5 316 753,1994.
[88] 李赫咺;项寿鹤;吴德明;刘月亭 张晓森 刘述铨 .[J].高等学校化学学报,1981,2:517.
[89] 王福生;程文才;张式 .[J].催化学报,1981,2:282.
[90] Shiralkar V P;Clearfield A .[J].Zeolites,1989,9:363.
[91] 孟祥举,谢彬,肖丰收.无有机模板剂条件下合成沸石催化材料[J].催化学报,2009(09):965-971.
[92] Song J W;Dai L;Ji Y Y;Xiao F Sh .[J].Chemistry of Materials,2006,18:2775.
[93] Wu Z F;Song J W;Ji Y Y;Ren L M Xiao F Sh .[J].Chemistry of Materials,2008,20:357.
[94] Xie B;Song J W;Ren L M;Ji Y Y Li J X Xiao F Sh .[J].Chemistry of Materials,2008,20:4533.
[95] Kamimura Y;Chaikittisilp W;Itabashi K;Shimojima A Okubo T .[J].Chem Asian J,2010,5:2182.
[96] Kamimura Y;Tanahashi S;Itabashi K;Sugawara A Wakihara T Shimojima A Okubo T .[J].Journal of Physical Chemistry C,2011,115:744.
[97] 汪靖,程晓维,杨晓蔚,龙英才.含有乙醚的无胺无氟反应物体系中高硅丝光沸石的合成[J].化学学报,2008(07):769-774.
[98] Warrender S J;Wright P A;Zhou W Z;Lightfoot P Camblor M A Shin C H Kim D J Hong S B .[J].Chemistry of Materials,2005,17:1272.
[99] Zhang H Y;Guo Q;Ren L M;Yang C G Zhu L F Meng X J Li C Xiao F Sh .[J].Journal of Materials Chemistry,2011,21:9494.
[100] Yokoi T;Yoshioka M;Imai H;Tatsumi T .[J].Angewandte Chemie International Edition,2009,48:9884.
[101] Xie, B.;Zhang, H.;Yang, C.;Liu, S.;Ren, L.;Zhang, L.;Meng, X.;Yilmaz, B.;Müller, U.;Xiao, F.-S. .Seed-directed synthesis of zeolites with enhanced performance in the absence of organic templates[J].Chemical communications,2011(13):3945-3947.
[102] Kuznicki S M .[P].US 4 453 202,1989.
[103] Kuznicki SM;Bell VA;Nair S;Hillhouse HW;Jacubinas RM;Braunbarth .A titanosilicate molecular sieve with adjustable pores for size-selectiveadsorption of molecules[J].Nature,2001(6848):720-724.
[104] Taramasso M;Perego G;Notarir B .[P].US 4 410 501,1983.
[105] Reddy J S;Kumar R;Ratnasamy P .[J].Applied Catalysis,1990,58:L1.
[106] Camblor M A;Corma A;Martinez A;Perez-Pariente J.[J].Journal of the Chemical Society,Chemical Communications,1992:589.
[107] van der Waal J C;Kooyman P J;Jansen J C;van Bekkum H .[J].Microporous and Mesoporous Materials,1998,25:43.
[108] Tatsumi T;Jappar N .[J].Journal of Physical Chemistry,1998,102:7126.
[109] Tuel A .[J].Zeolites,1995,15:236.
[110] Serrano D P;Li H X;Davis M E.[J].Journal of the Chemical Society,Chemical Communications,1992:745.
[111] Wu P;Komatsu T;Yashima T .[J].Journal of Physical Chemistry,1996,100:10316.
[112] Dartt C B;Davis M E .[J].Applied Catalysis A:General,1996,143:53.
[113] Diaz-Cabanas M J;Villaescusa L A;Camblor M A.[J].Chemical Communications,2000:761.
[114] Wu P;Tatsumi T;Komatsu T;Yashima T .[J].Journal of Physical Chemistry B,2001,105:2897.
[115] Wu P;Tatsumi T.[J].Chemical Communications,2002:1026.
[116] Wu P;Miyaji T;Liu Y M;He M Y Tatsumi T .[J].Catalysis Today,2005,99:233.
[117] Kubota Y;Koyama Y;Yamada T;Inagaki S;Tatsumi T .Synthesis and catalytic performance of Ti-MCM-68 for effective oxidation reactions[J].Chemical communications,2008(46):6224-6226.
[118] Fan WB;Duan RG;Yokoi T;Wu P;Kubota Y;Tatsumi T .Synthesis, crystallization mechanism, and catalytic properties of titanium-rich TS-1 free of extraframework titanium species[J].Journal of the American Chemical Society,2008(31):10150-10164.
[119] 林民;朱斌;舒兴田;汪燮卿 .[J].石油学报(石油加工),2005,34(z1):377.
[120] 谢伟,刘月明,汪玲玲,吴鹏.具有MWW结构钛硅分子筛的研究进展[J].催化学报,2010(05):502-513.
[121] Bull I;Xue W M;Burk P;Boorse R S,Jaglowski W M,Koermer G S,Moini A,Patchett J A,Dettling J C,Caudle M T .[P].US 7 601 662,2009.
[122] Andersen P J;Bailie J E;Casci J L;Chen H Y,Fedeyko J M,Foo R K S,Rajaram R R .[P].WO 2 008 132 452,2008.
[123] Houel V;James D;Millington P;Pollington S Poulston S Rajaram R Torbati R .[J].Journal of Catalysis,2005,230:150.
[124] Grossale A;Nova I;Tronconi E;Chatterjee D Weibel M .[J].Topics in Catalysis,2009,52:1837.
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