An Au-Cu bimetal catalyst was prepared by deposition-precipitation (urea) of gold and copper species on mesoporous TiO2 and activation with H2. The sample was characterized by N2 adsorption/desorption, X-ray diffraction, ultraviolet-visible spectroscopy, and high-resolution transmission electron microscopy. The results showed that the Au and Cu species formed an Au-Cu alloy and were well dis-persed on the mesoporous TiO2. According to CO oxidation test results, it was found that the catalytic activity of gold was enhanced by cop-per. The Au-Cu bimetal catalyst supported on mesoporous TiO2 showed better catalytic stability in CO oxidation than the Au catalyst sup-ported on mesoporous TiO2 and the nonporous TiO2-supported catalysts. This may be related to the effects of both Au-Cu alloying and the mesostructure of TiO2.
参考文献
[1] | Haruta M;Yamada N;Kobayashi T;Iijima S .[J].Journal of Catalysis,1989,115:301. |
[2] | Haruta M;Daté M .[J].Applied Catalysis A:General,2001,222:427. |
[3] | Haruta M .[J].Cattech,2002,6:102. |
[4] | Hashmi A S K;Hutchings G J .[J].Angewandte Chemie International Edition,2006,45:7896. |
[5] | Campbell C T;Parker S C;Starr D E .[J].Science,2002,298:811. |
[6] | Lai X;St Clair T P;Goodman D W .[J].Faraday Discussions,1999,114:279. |
[7] | Min B K;Wallace W T;Goodman D W .[J].Journal of Physical Chemistry B,2004,108:14609. |
[8] | He J;Kunitake T .[J].Chemistry of Materials,2004,16:2656. |
[9] | Bore M T;Pham H N;Switzer E E;Ward T L Fukuoka A Datye A K .[J].Journal of Physical Chemistry B,2005,109:2873. |
[10] | Yan W;Mahurin S M;Pan Z;Overbury S H Dai S .[J].Journal of the American Chemical Society,2007,127:10480. |
[11] | Ma Z;Brown S;Howe J Y;Overbury S H Dai S .[J].Journal of Physical Chemistry C,2008,112:9448. |
[12] | Zhu H;Ma Z;Overbury S H;Dai S .[J].Catalysis Letters,2007,116:128. |
[13] | Liu XY;Wang AQ;Wang XD;Mou CY;Zhang T .Au-Cu Alloy nanoparticles confined in SBA-15 as a highly efficient catalyst for CO oxidation[J].Chemical communications,2008(27):3187-3189. |
[14] | Bracey C L;Ellis P R;Hutchings G J .[J].Chemical Society Reviews,2009,38:2231. |
[15] | Sangeetha P;Zhao B;Chen Y W .[J].Industrial and Engineering Chemistry Research,2010,49:2096. |
[16] | He M;Lu XH;Feng X;Yu L;Yang ZH .A simple approach to mesoporous fibrous titania from potassium dititanate[J].Chemical communications,2004(19):2202-2203. |
[17] | Zhu Y H;Li W;Zhou Y X;Lu X H Feng X Yang Z H .[J].Catalysis Letters,2009,127:406. |
[18] | 马璇璇,朱银华,李力成,王昌松,陆小华,杨祝红.介孔 TiO2晶须担载 Au 的热稳定性[J].催化学报,2012(09):1480-1485. |
[19] | 朱银华,陈闪山,陆小华,杨祝红,冯新,汪怀远.新型晶须状氧化钛担载Au的CO催化氧化性能[J].催化学报,2009(05):421-425. |
[20] | Pal, S;De, G .Oriented Au-Cu nanoalloy particle incorporated SiO2 films using a new layer by layer deposition technique[J].Journal of Materials Chemistry,2007(5):493-498. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%