采用半池考察了Pt/C催化剂在含不同浓度甲醇的0.5 mol/L硫酸中的氧还原活性(ORR).研究发现,当甲醇浓度为0.1 mol/L时,Pt/C催化剂的ORR活性最高,在催化层上热压商品Nafion NRE-212膜后也出现同样趋势.线性扫描伏安曲线显示,压膜前后的Pt/C催化剂的ORR活性在含0.1 mol/L甲醇的0.5 mol/L硫酸中几乎没有变化.电化学阻抗谱结果表明,在该溶液中,Nafion膜的电阻比在其它电解液中低,这可能是导致Pt/C催化剂ORR活性提高的主要原因.有必要关注Nafion膜的这一异常性质并通过特殊设计后用于电池堆,以提高燃料电池性能.
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