银催化羧化偶联反应及钌催化交叉复分解反应串联合成官能团炔酸酯

催化学报 , 2013, 34(6): 1179-1186. doi: 10.1016/S1872-2067(12)60527-0

银催化羧化偶联反应及钌催化交叉复分解反应串联合成官能团炔酸酯

张琳琳 ^1, , 张文珍 ^2, , 石凌龙 ^3, , 任祥 ^4, , 吕小兵 ^5,

1.大连理工大学精细化工国家重点实验室,辽宁大连116024

2.大连理工大学精细化工国家重点实验室,辽宁大连116024

3.大连理工大学精细化工国家重点实验室,辽宁大连116024

4.大连理工大学精细化工国家重点实验室,辽宁大连116024

5.大连理工大学精细化工国家重点实验室,辽宁大连116024

基金项目: 辽宁省教育厅科研项目(L2012024).This work was supported by the National Natural Science Foundation of China(20802007,21111120073) 国家自然科学基金(20802007,21111120073) 中央高校基本科研业务费专项资金(DUT12LK47) the Fundamental Research Funds for the Central Universities(DUT12LK47) the Scientific Research Fund of Liaoning Provincial Education Department(L2012024)

关键词：二氧化碳 , 羧化偶联反应 , 银催化剂 , 交叉复分解反应 , Grubbs-Hoveyda催化剂 , 均相催化

Sequential Ag-catalyzed carboxylative coupling/Ru-catalyzed cross-metathesis reactions for the synthesis of functionalized 2-alkynoates

ZHANG Linlin ^1, , ZHANG Wenzhen ^2, , SHI Linglong ^3, , REN Xiang ^4, , Lü Xiaobing ^5,

1.大连理工大学精细化工国家重点实验室,辽宁大连116024

2.大连理工大学精细化工国家重点实验室,辽宁大连116024

3.大连理工大学精细化工国家重点实验室,辽宁大连116024

4.大连理工大学精细化工国家重点实验室,辽宁大连116024

5.大连理工大学精细化工国家重点实验室,辽宁大连116024

Keywords： Carbon dioxide , Carboxylative coupling , Silver catalyst , Cross-metathesis , Grubbs-Hoveyda catalyst , Homogeneous catalysis

通过将Ag催化的羧化偶联反应与Ru催化的交叉复分解反应串联,用端炔、二氧化碳、端烯基取代的溴代物和甲基丙烯酸甲酯高效高产率地合成了一系列官能团化的炔酸酯.

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