苯磺酰胺参与下二价钌催化环丙乙炔扩环反应

催化学报 , 2013, 34(10): 1816-1819. doi: 10.1016/S1872-2067(12)60680-9

苯磺酰胺参与下二价钌催化环丙乙炔扩环反应

1.南京理工大学环境与生物工程学院,江苏南京210014;中国科学院大连化学物理研究所,辽宁大连116023

2.南京理工大学环境与生物工程学院,江苏南京210014

3.中国科学院大连化学物理研究所,辽宁大连116023

4.南京理工大学环境与生物工程学院,江苏南京210014

基金项目: 江苏省青蓝工程中央高校基本科研业务费专项资金(30920130121013).This work was supported by the National Natural Science Foundation of China(31070312,31170131) the Jiangsu Qinglan Project,and the Fundamental Research Funds for the Central Universities(30920130121013) 国家自然科学基金(31070312,31170131)

关键词：过渡金属 , 钌催化 , 扩环反应 , 苯磺酰胺

Ru(Ⅱ)-catalyzed ring expansion of alkynylcyclopropanes in the presence of sulfonamides

Yuye Chen ^1, , Junsong Wang ^2, , Xingwei Li ^3, , Aiqun Jia ^4,

1.南京理工大学环境与生物工程学院,江苏南京210014;中国科学院大连化学物理研究所,辽宁大连116023

2.南京理工大学环境与生物工程学院,江苏南京210014

3.中国科学院大连化学物理研究所,辽宁大连116023

4.南京理工大学环境与生物工程学院,江苏南京210014

Keywords： Transition metal , Ruthenium , Catalysis , Ring expansion

将二价钌配合物用于催化环丙乙炔扩环生成四元环结构的反应,扩展了一系列环丙乙炔底物和磺酰胺底物,并得到了较高的产率.

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