丝网印刷法制备高催化活性对电极

催化学报 , 2014, 35(2): 219-226. doi: 10.1016/S1872-2067(12)60737-2

丝网印刷法制备高催化活性对电极

1.大连理工大学化学学院精细化工国家重点实验室,辽宁大连116024

2.大连理工大学化学学院精细化工国家重点实验室,辽宁大连116024

3.营口奥匹维特新能源科技有限公司,辽宁营口115003

4.大连理工大学化学学院精细化工国家重点实验室,辽宁大连116024;营口奥匹维特新能源科技有限公司,辽宁营口115003

基金项目: 国家高新技术研究发展计划(863计划,2009AA03Z220) the National Natural Science Foundation of China(51273032) the National High Technology Research and Development Program of China(2009AA03Z220) 国家自然科学基金(51273032) the Fundamental Research Funds for the Central Universities (DUT12RC(3)57) 中央高校基本科研业务费专项资金资助(DUT12RC(3)57)

关键词：对电极 , 附着力 , 均匀性 , 简易可控 , 染料敏化太阳能电池

Screen-printed Pt counter electrodes exhibiting high catalytic activity

Chunyu Zhao ^1, , Yantao Shi ^2, , Zhiyong Zhong ^3, , Tingli Ma ^4,

1.大连理工大学化学学院精细化工国家重点实验室,辽宁大连116024

2.大连理工大学化学学院精细化工国家重点实验室,辽宁大连116024

3.营口奥匹维特新能源科技有限公司,辽宁营口115003

4.大连理工大学化学学院精细化工国家重点实验室,辽宁大连116024;营口奥匹维特新能源科技有限公司,辽宁营口115003

Keywords： Counter electrode , Adhesion uniformity , Controllable , Dye-sensitized solar cell ,

对电极在染料敏化太阳能电池(DSCs)中主要起催化氧化还原反应及收集电荷的作用,铂对电极常用的制备方法为磁控溅射法,但其成本较高,制备条件苛刻.本文通过引入低成本的表面活性剂Span-85,所制得的铂对电极的附着力、透光率和均匀性显著改善,实现了面积可控,与两步浸泡法和旋涂热解法制备的对电极在DSCs中的光电转换效率分别为7.30％,6.96％和7.03％.紫外-可见吸收光谱、扫描电镜和附着力测试等结果表明,(1)添加表面活性剂有利于增加附着力及改善透光率和均匀性;(2)使用该法制备的Pt/FTO对电极的透光率与两步浸泡法制作的相同,且铂粒子分布更加均匀.电化学阻抗图谱、塔菲尔极化曲线和循环伏安曲线结果表明,丝网印刷方法制备的Pt/FTO对电极具有更加优异的催化性能,且该法更有利于降低其生产成本和大规模生产.

参考文献

[1]	O'Regan B;Gratzel,M .[J].Nature,1991,353:737.
[2]	Gratzel M .[J].Nature,2001,414:338.
[3]	Hagfeldt, A.;Boschloo, G.;Sun, L.;Kloo, L.;Pettersson, H. .Dye-sensitized solar cells[J].Chemical Reviews,2010(11):6595-6663.
[4]	林红,李鑫,刘忆翥,李建保.太阳能电池发展的新概念和新方向[J].稀有金属材料与工程,2009(z2):722-725.
[5]	王彦明,李新军,郑少健.铂分布形式对TiO2薄膜光电化学行为的影响[J].无机材料学报,2007(04):729-732.
[6]	Wu M X;Lin X;Wang L;Guo W,Wang Y D,Xiao J Q,Hagfeldt A,Ma T L .[J].Journal of Physical Chemistry C,2011,115:22598.
[7]	Wu M X;Lin X;Hagfeldt A;Ma T L .[J].Angewandte Chemie International Edition,2011,50:3520.
[8]	Lin, X.;Wu, M.;Wang, Y.;Hagfeldt, A.;Ma, T. .Novel counter electrode catalysts of niobium oxides supersede Pt for dye-sensitized solar cells[J].Chemical communications,2011(41):11489-11491.
[9]	Wu M X;Zhang Q Y;Xiao J Q;Ma T L .[J].Journal of Materials Chemistry,2011,21:10761.
[10]	Wu M X;Lin X;Wang Y D;Wang L,Guo W,Qi D D,Peng X J,Hagfeldt A,Gratzel,M,Ma T L .[J].Journal of the American Chemical Society,2012,134:3419.
[11]	Wang M K;Anghel A M;Marsan B;Ha N-L C,Pootrakulchote N,Zakeeruddin S M,Grtzel M .[J].Journal of the American Chemical Society,2009,131:15976.
[12]	冯小明,黄先威,谭卓,赵斌,谭松庭.聚吡咯/石墨复合对电极在染料敏化太阳能电池中的应用研究[J].化学学报,2011(06):653-658.
[13]	Wu M X;Lin X;Wang T H;Qiu J S,Ma T L .[J].Energy & Environmental Science,2011,4:2308.
[14]	徐顺建,罗玉峰,李水根,钟炜,黄明道.低温制备介孔碳对电极构建的染料敏化太阳电池优化研究[J].无机材料学报,2012(01):83-88.
[15]	孟凡宁,王春雷,武明星,林逍,王同华,马廷丽.染料敏化太阳能电池无FTO煤基炭对电极的研究[J].无机材料学报,2013(03):273-277.
[16]	Choi J Y;Hong J T;Seo H;Kim M,Son M K,Lee K J,Lee D Y,Kim H J .[J].Thin Solid Films,2008,517:963.
[17]	Ikegami M;Miyoshi K;Miyasaka T;Teshima K,Wei T C,Wan C,Wang Y Y .[J].Applied Physics Letters,2007,90:153122.
[18]	Khelashvili G;Behrens S;Weidenthaler C;Vetter C;Hinsch A;Kern R;Skupien K;Dinjus E;Bonnemann H .Catalytic platinum layers for dye solar cells: A comparative study[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2006(0):342-348.
[19]	Kim S-S;Nah Y-C;Noh Y Y;Kim D-Y .[J].Electrochimica Acta,2006,51:3814.
[20]	Tsekouras G;Mozer A J;Wallace G G .[J].Journal of The Electrochemical Society,2008,155:K124.
[21]	Lan J-L;Wang Y-Y;Wan C-C;Wei T-C,Feng H-P,Peng C,Cheng H-P,Chang Y-H,Hsu W-C .[J].Current Applied Physics,2010,10:S168.
[22]	Wei T-C;Wan C-C;Wang Y-Y;Chen C-M,Shiu H-S .[J].Journal of Physical Chemistry C,2007,111:4847.
[23]	Chen C-M;Chen C-H;Cherng S-J;Wei T-C .[J].Materials Chemistry and Physics,2010,124:173.
[24]	Wang G Q;Lin R F;Lin Y;Li X P,Xiao X R .[J].Electrochimica Acta,2005,50:5546.
[25]	Fang XM;Ma TL;Guan GQ;Akiyama M;Kida T;Abe E .Effect of the thickness of the Pt film coated on a counter electrode on the performance of a dye-sensitized solar cell[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,2004(2):257-263.
[26]	Li P J;Wu J H;Lin J M;Guan G Q,Huang Y F,Li Q H .[J].Solar Energy,2009,83:845.
[27]	Wang Q;Moser J-E;Graitzel M .[J].Journal of Physical Chemistry B,2005,109:14945.
[28]	Hauch A;Georg A .[J].Electrochimica Acta,2001,46:3457.
[29]	Wang Y D;Wu M X;Lin X;Shi Z C,Ma T L .[J].Journal of Materials Chemistry,2012,22:4009.
[30]	Wang Y D;Zhao C Y;Qin D;Wu M X,Liu W,Ma T L .[J].Journal of Materials Chemistry,2012,22:22155.
[31]	Hu L B;Choi J W;Yang Y;Jeong S,Cui L F,Cui Y .[J].Proceedings of the National Academy of Sciences of the United States of America,2009,106:21490.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网