采用二次法快速合成了Sn-β沸石。该方法包含杂原子脱除和与SnCl4的同晶取代两个步骤,合成时间从水热法的约40 d缩短为少于1 d,且Sn含量更高。将该沸石用于水相催化葡萄糖异构化制果糖反应,详细考察了反应温度、时间、催化剂用量、溶剂以及卤盐添加物对反应性能的影响。在优化的反应条件下,果糖收率最高可达约43%。催化剂可以通过焙烧再生。
Sn-βzeolites were facilely synthesized by a post-synthesis method consisting of two steps, i.e., het-eroatom removal and isomorphous substitution by reaction with SnCl4. This significantly shortened the Sn-βzeolite preparation time from the previously reported 40 d to less than 1 d. It was shown that Sn-βsamples prepared using the post-synthesis method had higher Sn contents than that pre-pared using a hydrothermal method. The as-synthesized Sn-βzeolites were tested in the isomeriza-tion of glucose to fructose in aqueous media. The effects of reaction temperature, reaction time, catalyst amount, solvent, and halide additive on the isomerization reaction over Sn-Al-β zeolites were studied in detail. Under the optimized conditions, the yield of fructose reached a maximum of~43%. The catalysts can be reused without loss of activity after regeneration by calcination.
参考文献
| [1] | Nigam P S;Singh A .[J].Progress in Energy and Combustion Science,2011,37:52. |
| [2] | Chheda J N;Huber G W;Dumesic J A .[J].ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2007,46:7164. |
| [3] | Climent M J;Corma A;Iborra S .[J].Green Chemistry,2011,13:520. |
| [4] | Kunkes E L;Simonetti D A;West R M;Serrano-Ruiz J C Gartner C A Dumesic J A .[J].SCIENCE,2008,322:417. |
| [5] | Caes B R;Raines R T .[J].ChemSusChem,2011,4:353. |
| [6] | Zhao H;Holladay JE;Brown H;Zhang ZC .Metal chlorides in ionic liquid solvents convert sugars to 5-hydroxymethylfurfural.[J].Science,2007(5831):1597-1600. |
| [7] | Bicker M;Hirth J;Vogel H .[J].Green Chemistry,2003,5:280. |
| [8] | Corma A;Iborra S;Velty A .[J].CHEMICAL REVIEWS,2007,107:2411. |
| [9] | Takagaki A;Ohara M;Nishimura S;Ebitani K.[J].Chemistry Communications,2009:6276. |
| [10] | Nikolla E;Roman-Leshkov Y;Moliner M;Davis M E .[J].ACS Catal,2011,1:408. |
| [11] | Yang BY.;Montgomery R. .ALKALINE DEGRADATION OF GLUCOSE - EFFECT OF INITIAL CONCENTRATION OF REACTANTS[J].Carbohydrate research,1996(1):27-45. |
| [12] | De Wit G;Kieboom A P G;van Bekkum H .[J].Carbohydrate Research,1979,74:157. |
| [13] | Li P;Liu G Q;Wu H H;Liu Y M Jiang J G Wu P .[J].J Phys Chem C,2011,115:3663. |
| [14] | Corma A;Renz M.[J].Chemistry Communications,2004:550. |
| [15] | Corma A.;Domine ME.;Valencia S. .Water-resistant solid Lewis acid catalysts: Meerwein-Ponndorf-Verley and Oppenauer reactions catalyzed by tin-beta zeolite[J].Journal of Catalysis,2003(2):294-304. |
| [16] | Moliner M;Roman-Leshkov Y;Davis M E .[J].Proceedings of the National Academy of Sciences(USA),2010,107:6164. |
| [17] | Chang C C;Wang Z;Dornath P;Cho H J Fan W .[J].RSC Adv,2012,2:10475. |
| [18] | Choudhary V;Pinar A B;Sandler S I;Vlachos D G Lobo R F .[J].ACS Catal,2011,1:1724. |
| [19] | Lew C M;Rajabbeigi N;Tsapatsis M .[J].Industrial and Engineering Chemistry Research,2012,51:5364. |
| [20] | 刘民,郭新闻,王祥生.以B-ZSM-5为母体合成Ti-ZSM-5高效苯酚羟基化催化剂[J].催化学报,2004(03):169-170. |
| [21] | Corma A;Nemeth L T;Renz M;Valencia S .[J].NATURE,2001,412:423. |
| [22] | Valencia S;Corma A .[P].US Patent 5968473,1999. |
| [23] | Osmundsen, C.M.;Spangsberg Holm, M.;Dahl, S.;Taarning, E. .Tin-containing silicates: Structure-activity relations[J].Proceedings of the Royal Society. Mathematical, physical and engineering sciences,2012(2143):2000-2016. |
| [24] | Higgins J B;Lapierre R B;Schlenker J L;Rohrman A C Wood J D Kerr G T Rohrbaugh W J .[J].ZEOLITES,1988,8:446. |
| [25] | van Grieken R;Martos C;Sanchez-Sanchez M;Serrano D P Melero J A Iglesias J Cubero A G .[J].Microporous and Mesoporous Materials,2009,119:176. |
| [26] | Gu F.;Wang SF.;Song CF.;Lu MK.;Qi YX.;Zhou GJ.;Xu D.;Yuan DR. .Synthesis and luminescence properties of SnO2 nanoparticles[J].Chemical Physics Letters,2003(3-4):451-454. |
| [27] | Mal N K;Ramaswamy A V .[J].Journal of Molecular Catalysis A:Chemical,1996,105:149. |
| [28] | Bermejo-Deval R;Gounder R;Davis M E .[J].ACS Catal,2012,2:2705. |
| [29] | Blasco T;Camblor M A;Corma A;Esteve P Guil J M Martinez A Perdigon-Melon J A Valencia S .[J].Journal of Physical Chemistry B,1998,102:75. |
| [30] | Boronat M;Concepcion P;Corma A;Renz M;Valencia S .Determination of the catalytically active oxidation Lewis acid sites in Sn-beta zeolites, and their optimisation by the combination of theoretical and experimental studies[J].Journal of Catalysis,2005(1):111-118. |
| [31] | Sohn J R;Decanio S J;Lunsford J H;Odonnell D J .[J].ZEOLITES,1986,6:225. |
| [32] | Qi X H;Watanabe M;Aida T M;Smith R L .[J].CATALYSIS COMMUNICATIONS,2009,10:1771. |
| [33] | Roman-Leshkov Y;Moliner M;Labinger J A;Davis M E .[J].ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2010,49:8954. |
| [34] | Corma A;Garcia H .[J].CHEMICAL REVIEWS,2002,102:3837. |
| [35] | Dong W;Zhao Y;Zhuo K;Chen Y .[J].Industrial and Engineering Chemistry Research,2010,49:9430. |
| [36] | 董伟燕,张心宽,卓克垒,王键吉.298.15 K下卤化钠在葡萄糖水溶液中单个离子活度系数研究[J].河南师范大学学报（自然科学版）,2009(02):188-188. |
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