研究了二价铜酞菁(CuPc)催化咪唑与芳基碘或溴的N-芳基化反应。结果表明, CuPc表现出高的催化活性,并且能够重复使用3次活性无明显降低。采用傅里叶变换红外光谱、X射线光电子能谱和紫外-可见光谱对催化剂样品进行了表征。
Copper (II) phthalocyanine (CuPc) was used as a catalyst for the N-arylation of imidazoles with aryl iodides or bromides. The catalyst showed high activity and could be reused 3 times without any significant loss in activity. The catalyst was characterized by Fourier transform infrared spectros-copy, X-ray photoelectron spectroscopy, and ultraviolet-visible spectroscopy.
参考文献
[1] | Rezaeifard A;Jafarpour M;Naeimi A;Mohammadi K .[J].Journal of Molecular Catalysis A:Chemical,2012,357:141. |
[2] | Grootboom N;Nyokong T .[J].Journal of Molecular Catalysis A:Chemical,2002,179:113. |
[3] | Shinu V S;Pramitha P;Bahulayan D .[J].Tetrahedron Letters,2011,52:3110. |
[4] | Sadek S A;Solyman S M;Abdel-Samad H S;Hassan S A .[J].Int J Polymer Mater,2010,59:353. |
[5] | Sorokin A B;Kudrik E V .[J].Catalysis Today,2011,159:37. |
[6] | Kison C;Opatz T .[J].Chemistry-A European Journal,2009,15:843. |
[7] | Kantam M L;Yadav J;Laha S;Sreedhar B Jha S .[J].Advanced Synthesis and Catalysis,2007,349:1938. |
[8] | Chen C X;Shang G N;Zhou J J;Yu Y H Li B Peng J S .[J].Organic Letters,2014,16:1872. |
[9] | Yang Q C;Wang Y F;Zhang B J;Zhang M J .[J].Chinese Journal of Chemistry,2012,30:2389. |
[10] | Zhang, Q.;Luo, J.;Wei, Y. .Efficient and reusable catalytic system of Cul-PEG for n-arylation of imidazoles[J].Synthetic Communications,2012(1/3):114-121. |
[11] | Boswell M G;Yeung F G;Wolf C .[J].SYNLETT,2012,23:1240. |
[12] | 金明,赵丹,何国珍,童耀,韩世清.水相中底物促进的铜催化氨基醇N-芳基化反应[J].催化学报,2013(09):1651-1655. |
[13] | Sreedhar B;Arundhathi R;Reddy P L;Reddy M A,Kantam M L.[J].Synthesis,2009:2517. |
[14] | Mondal P;Sinha A;Salam N;Roy A S Jana N R Islam S M .[J].RSC Adv,2013,3:5615. |
[15] | Altman RA;Buchwald SL .4,7-Dimethoxy-1,10-phenanthroline: An excellent ligand for the Cu-catalyzed N-arylation of imidazoles[J].Organic letters,2006(13):2779-2782. |
[16] | Sehlotho N;Nyokon T .[J].Journal of Molecular Catalysis A:Chemical,2004,209:51. |
[17] | Ghorbani-Vaghei R;Hemmati S;Veisi H .[J].Tetrahedron Letters,2013,54:7095. |
[18] | Shaabani A. .Synthesis of metallophthalocyanines under solvent-free conditions using microwave irradiation[J].Journal of Chemical Research. Synopses,1998(10):672-673. |
[19] | Guo Z C;Chen B;Mu J B;Zhang M Y Zhang P Zhang Z Y Wang J F Zhang X Sun Y Y Shao C L Liu Y C .[J].Journal of Hazardous Materials,2012,219-220:156. |
[20] | Peisert H;Knupfer M;Schwieger T;Auerhammer J M Golden M S Fink J .[J].Journal of Applied Physics,2002,91:4872. |
[21] | Krzywiecki M;Grz?dziel L;Ottaviano L;Parisse P Santucci S Szuber J .[J].MATERIALS SCIENCE-POLAND,2008,26:287. |
[22] | Ottaviano L.;Rispoli F.;Santucci S.;Lozzi L. .Hexadecafluoro-copper-phthalocyanine UHV deposited onto Si(111)7x7 substrate: an XPS study[J].Surface Science: A Journal Devoted to the Physics and Chemistry of Interfaces,1998(1/3):518-522. |
[23] | Koifman O I;Hanack M;Syrbu S A;Lyubimtsev A V .[J].Russian Chemical Bulletin,2013,62:896. |
[24] | Zhang L;Wang L .[J].Poly Plast Technol Eng,2012,51:6. |
[25] | Huang Y Z;Miao H;Zhang Q H;Chen C Xu J .[J].Catalysis Letters,2008,122:344. |
[26] | Liu Y;Zhang Q;Ma X W;Liu P Xie J W Dai B Liu Z Y .[J].Int J Org Chem,2013,3:185. |
[27] | 綦晓龙,周丽梅,蒋晓慧,范红伟,付海燕,陈华.蒙脱土负载 Cu催化含氮杂环化合物的 N-芳基化反应[J].催化学报,2012(12):1877-1882. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%