欢迎登录材料期刊网

材料期刊网

高级检索

Low temperature fuel cells are an attractive technology for transportation and residential applica‐tions due to their quick start up and shut down capabilities. This review analyzed the current status of nanocatalysts for proton exchange membrane fuel cells and alkaline membrane fuel cells. The preparation process influences the performance of the nanocatalyst. Several synthesis methods are covered for noble and non‐noble metal catalysts on various catalyst supports including carbon nanotubes, carbon nanofibers, nanowires, and graphenes. Ex situ and in situ characterization methods like scanning electron microscopy, transmission electron microscopy, X‐ray photoelectron spectroscopy and fuel cell testing of the nanocatalysts on various supports for both proton exchange and alkaline membrane fuel cells are discussed. The accelerated durability estimate of the nanocat‐alysts, predicted by measuring changes in the electrochemically active surface area using a voltage cycling method, is considered one of the most reliable and valuable method for establishing durabil‐ity.

参考文献

[1] Schell A;Peng H;Tran D;Stamos E Lin C Kim M .[J].Annual Rev Con-trol,2005,29(01):159.
[2] EG&G Technical Services Inc.Fuel Cell Handbook. 7th Ed[M].West Virginia,USA:US Department of Energy,2004
[3] Singhal S C .[J].Electrochem Soc Interface,2007,16(04):41.
[4] Slade S;Campbell S A;Ralph T R;Walsh F C .[J].Journal of the Electrochemical Society,2002,149:A1556.
[5] Steele B C H;Heinzel A .[J].NATURE,2001,414:345.
[6] Rajesh B;Piotr Z .[J].NATURE,2006,443:63.
[7] Technical Plan-Fuel Cells-2012[OL].http://www1.eere.energy.gov/hydrogenandfuelcells/mypp/pdfs/fuel_cells.pdf
[8] Debe M K .[J].NATURE,2012,486:43.
[9] Antolini E .[J].Applied Catalysis B:Environmental,2009,88:1.
[10] Wang X;Li W Z;Chen Z W;Waje M Yan Y S .[J].Journal of Power Sources,2006,158:154.
[11] Wu J F;Yuan X Z;Martin J J;Wang H J Zhang J J Shen J Wu S H Merida W .[J].Journal of Power Sources,2008,184:104.
[12] Iijima S .[J].NATURE,1991,354:56.
[13] Li J;Papadopoulos C;Xu J M;Moskovits M .[J].Applied Physics Letters,1999,75:367.
[14] Zhang DH;Ryu K;Liu XL;Polikarpov E;Ly J;Tompson ME;Zhou CW .Transparent, conductive, and flexible carbon nanotube films and their application in organic light-emitting diodes[J].Nano letters,2006(9):1880-1886.
[15] Baughman R H;Zakhidov A A;de Heer W A .[J].SCIENCE,2002,297:787.
[16] Meyyappan M.Carbon Nanotubes-Science and Applications. 1st Ed[M].Boston:CRC Press,2005
[17] Vashist SK;Zheng D;Al-Rubeaan K;Luong JH;Sheu FS .Advances in carbon nanotube based electrochemical sensors for bioanalytical applications. [Review][J].Biotechnology Advances: An International Review Journal,2011(2):169-188.
[18] Shang N G;Tan Y Y;Stolojan V;Papakonstantinou P Silva S R P .[J].NANOTECHNOLOGY,2010,21:505604/1.
[19] Kamavaram V;Veedu V;Kannan A M .[J].Journal of Power Sources,2009,188:51.
[20] Lin J F;Kamavaram V;Kannan A M .[J].Journal of Power Sources,2010,195:466.
[21] Bessel C A;Laubernds K;Rodriguez N M;Baker R T K .[J].Journal of Physical Chemistry B,2001,105:1115.
[22] Debe M K;Schmoeckel A K;Vernstrorn G D;Atanasoski R .[J].Journal of Power Sources,2006,161:1002.
[23] Toebes M L;van der Lee M;Tang L M;in 't Veld M H H Bitter J H van Dillen A J de Jong K P .[J].Journal of Physical Chemistry B,2004,108:11611.
[24] Tang H;Chen J H;Nie L H;Liu D Y Deng W Kuang Y F Yao S Z .[J].Journal of Colloid and Interface Science,2004,269:26.
[25] Sarac M F;Wilson R M;Johnston-Peck A C;Wang J W Pearce R Klein K L Melechko A V Tracy J B .[J].ACS Appl Mater Interfaces,2011,3:936.
[26] Eastcott J I;Easton E B .[J].Electrochimica Acta,2009,54:3460.
[27] Anderson M L;Stroud R M;Rolison D R .[J].Nano Letters,2002,2:235.
[28] Zhang L;Kim J;Dy E;Ban S Tsay K C Kawai H Shi Z Zhang J J .[J].Electrochimica Acta,2013,108:480.
[29] Sharma S;Pollet B G .[J].Journal of Power Sources,2012,208:96.
[30] Song S Q;Liang Y R;Li Z H;Wang Y Fu R W Wu D C Tsiakaras P .[J].Applied Catalysis B:Environmental,2010,98:132.
[31] Schniepp H C;Li J L;McAllister M J;Sai H Herrera-Alonso M Ad-amson D H Prud'homme R K Car R Saville D A Aksay I A .[J].Journal of Physical Chemistry B,2006,110:8535.
[32] McAllister M J;Li J L;Adamson D H;Schniepp H C Abdala A A Liu J Herrera-Alonso M Milius D L Car R Prud'homme R K Aksay I A .[J].CHEMISTRY OF MATERIALS,2007,19:4396.
[33] Marinkas A;Arena F;Mitzel J;Prinz G M Heinzel A Peinecke V Natter H .[J].CARBON,2013,58:139.
[34] Cui C H;Gan L;Heggen M;Rudi S Strasser P .[J].NATURE MATERIALS,2013,12:765.
[35] Gasteiger HA;Kocha SS;Sompalli B;Wagner FT .Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2005(1/2):9-35.
[36] Mukerjee S;Srinivasan S .[J].Journal of Electroanalytical Chemistry,1993,357:201.
[37] Esmaeilifar A;Rowshanzamir S;Eikani M H;Ghazanfari E .[J].ENERGY,2010,35:3941.
[38] Li W Z;Chen Z W;Xu L B;Yan Y S .[J].Journal of Power Sources,2010,195:2534.
[39] Calvillo L;Gangeri M;Perathoner S;Centi G Moliner R Lazaro M J .[J].International Journal of Hydrogen Energy,2011,36:9805.
[40] Zhu H;Li X W;Wang F H .[J].International Journal of Hydrogen Energy,2011,36:9151.
[41] Xu Z;Zhang H M;Liu S S;Zhang B S Zhong H X Su D S .[J].Int J Hydro-gen Energy,2012,37:17978.
[42] Moreira J;del Angel P;Ocampo A L;Sebastian P J Montoya J A Castellanos R H .[J].International Journal of Hydrogen Energy,2004,29:915.
[43] Li B;Qiao J L;Zheng J S;Yang D J Ma J X .[J].International Journal of Hydrogen Energy,2009,34:5144.
[44] Zhang H J;Yuan X;X Sun L L;Yang J H Ma Z F Shao Z P .[J].Electro-chim Acta,2012,77:324.
[45] Henry C R .[J].Progress in Surface Science,2005,80:92.
[46] Wilson G J;Matijasevich A S;Mitchell D R G;Schulz J C Will G D .[J].LANGMUIR,2006,22:2016.
[47] Reetz M T;Schulenburg H;Lopez M;Spliethoff B Tesche B .[J].CHIMIA,2004,58:896.
[48] Shen J F;Huang W S;Wu L P;Hu Y Z Ye M X .[J].COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING,2007,38:1331.
[49] Sheng W .[D].Boston:MIT,2010.
[50] Bonnemann H;Nagabhushana K .[J].J New Mater Electrochem Sys-tems,2004,7(02):93.
[51] Hashim A A.The Delivery of Nanoparticles. Chapter 19[M].Croatia,2012:406.
[52] Grolleau C;Coutanceau C;Pierre F;Leger J M .[J].Electrochimica Acta,2008,53:7157.
[53] Lin J F;Adame A;Kannan A M .[J].Journal of the Electrochemical Society,2010,157:B846.
[54] Bronstein L M .[J].Topics in Current Chemistry,2003,226:55.
[55] Liu B;Creager S .[J].Journal of Power Sources,2010,195:1812.
[56] Zhang Y;Erkey C .[J].Journal of Supercritical Fluids,2006,38:252.
[57] Lin J F;Mason C W;Adame A;Liu X Peng X H Kannan A M .[J].Elec-trochim Acta,2010,55:6496.
[58] Harish S;Baranton S;Coutanceau C;Joseph J .[J].Journal of Power Sources,2012,214:33.
[59] Fievet F;Lagier J P;Blin B;Beaudoin B Figlarz M .[J].Solid State Ionicis,1989,32-33:198.
[60] Liu Z L;Gan L M;Hong L;Chen W X Lee J Y .[J].Journal of Power Sources,2005,139:73.
[61] Lebegue E;Baranton S;Coutanceau C .[J].Journal of Power Sources,2011,196:920.
[62] White R J;Luque R;Budarin V L;Clark J H Macquarrie D J .[J].CHEMICAL SOCIETY REVIEWS,2009,38:481.
[63] Saminathan K;Kamavaram V;Veedu V;Kannan A M .[J].Int J Hydro-gen Energy,2009,34:3838.
[64] Mehta V;Cooper J S .[J].Journal of Power Sources,2003,114:32.
[65] Jung D S;Park S B;Kang Y C .[J].Korean Journal of Chemical Engineering,2010,27:1621.
[66] Morse J D;Jankowski A F;Graff R T;Hayes J P .[J].J Vacuum Sci Technol A,2000,18:2003.
[67] Girishkumar G;Rettker M;Underhile R;Binz D;Vinodgopal K;McGinn P;Kamat P .Single-wall carbon nanotube-based proton exchange membrane assembly for hydrogen fuel cells[J].Langmuir: The ACS Journal of Surfaces and Colloids,2005(18):8487-8494.
[68] Wee J H;Lee K Y;Kim S H .[J].Journal of Power Sources,2007,165:667.
[69] Basu D;Basu S .[J].Electrochimica Acta,2011,56:7758.
[70] Tamasauskaite-Tamasiunaite L;Balciunaite A;Vaiciukeviciene A;Selskis A Pakstas V .[J].Journal of Power Sources,2012,208:242.
[71] Ramesh K V;Shukla A K .[J].Journal of Power Sources,1987,19:279.
[72] Zhiani M;Gasteiger H A;Piana M;Catanorchi S .[J].International Journal of Hydrogen Energy,2011,36:5110.
[73] Lai C L;Kolla P;Zhao Y;Fong H Smirnova A L .[J].Electrochimica Acta,2014,130:431.
[74] Jasinski R J .[J].NATURE,1964,201:1212.
[75] Zagal J H .[J].Coordination Chemistry Review,1992,119:89.
[76] Vasudevan P;Santosh;Mann N;Tyagi S .[J].Transition Metal Chem,1990,15:81.
[77] Schilling T;Okunola A;Masa J;Schuhmann W Bron M .[J].Electrochimica Acta,2010,55:7597.
[78] Tarasevich M R;Zhutaeva G V;Radina M V;Karichev Z R Teishev E A Miners J H Goueres P Sanchez-Corteron E .[J].Russian Journal of Electrochemistry,2003,39:1094.
[79] Baker R;Wilkinson D P;Zhang J J .[J].Electrochimica Acta,2008,53:6906.
[80] Zagal J;Paez M;Tanaka A A;Dos Santos Junior J R Linkous C A .[J].Journal of Electroanalytical Chemistry,1992,339:13.
[81] Ramirez G.;Trollund E.;Isaacs M.;Armijo F.;Zagal J.;Costamagna J. Aguirre MJ. .Electroreduction of molecular oxygen on poly-iron-tetraaminophthalocyanine modified electrodes[J].Electroanalysis,2002(7/8):540-545.
[82] Tse Y H;Janda P;Lam H;Zhang J J Pietro W J Lever A B P .[J].J Por-phyrins Phthalocyanines,1997,1(01):3.
[83] Collman J P;Elliott C M;Halbert T R;Tovrog B S .[J].Proceedings of the National Academy of Sciences(USA),1977,74:18.
[84] Durand R R;Bencosme C S;Collman J P;Anson F C .[J].Journal of the American Chemical Society,1983,105:2710.
[85] Tanaka A A;Fierro C;Scherson D A;Yeager E .[J].Materials Chemistry and Physics,1989,22:431.
[86] Ding L;Dai X F;Lin R;Wang H J Qiao J L .[J].Journal of the Electrochemical Society,2012,159:F577.
[87] Kruusenberg, I.;Mondal, J.;Matisen, L.;Sammelselg, V.;Tammeveski, K..Oxygen reduction on graphene-supported MN_4 macrocycles in alkaline media[J].Electrochemistry communications,2013:18-22.
[88] Zagal J H;Griveau S;Ozoemena K I;Nyokong T Bedioui F .[J].J Na-nosci Nanotechnol,2009,9:2201.
[89] Morozan A;Campidelli S;Filoramo A;Jousselme B Palacin S .[J].CARBON,2011,49:4839.
[90] Kruusenberg I;Matisen L;Tammeveski K .[J].JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,2013,13:621.
[91] Okunola A;Kowalewska B;Bron M;Kulesza P J Schuhmann W .[J].Electrochimica Acta,2009,54:1954.
[92] Yamazaki S;Yamada Y;Ioroi T;Fujiwara N;Siroma Z;Yasuda K;Miyazaki Y .Estimation of specific interaction between several Co porphyrins and carbon black: its influence on the electrocatalytic O-2 reduction by the porphyrins[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,2005(2):253-259.
[93] Mamuru, S.A.;Ozoemena, K.I. .Heterogeneous electron transfer and oxygen reduction reaction at nanostructured iron(II) phthalocyanine and its MWCNTS nanocomposites[J].Electroanalysis,2010(9):985-994.
[94] Lalande G;Cote R;Guay D;Dodelet J P Weng L T Bertrand P .[J].Electrochimica Acta,1997,42:1379.
[95] Jahnke H;Schonborn M;Zimmermann G .[J].Topics in Current Chemistry,1976,61:133.
[96] Ramavathu, L.N.;Maniam, K.K.;Gopalram, K.;Chetty, R. .Effect of pyrolysis temperature on cobalt phthalocyanine supported on carbon nanotubes for oxygen reduction reaction[J].Journal of Applied Electrochemistry,2012(11):945-951.
[97] Kruusenberg I;Matisen L;Tammeveski K .[J].International Journal of Electrochemical Science,2013,8(01):1057.
[98] Kruusenberg I;Matisen L;Shah Q;Kannan A M Tammeveski K .[J].International Journal of Hydrogen Energy,2012,37:4406.
[99] Steigerwalt E S;Deluga G A;Cliffel D E;Lukehart C M .[J].Journal of Physical Chemistry B,2001,105:8097.
[100] Ohgai T;Peng X H.Nanowires-Recent Advances[M].Shang-hai,China,2012:101.
[101] Brunauer S;Emmett P H;Teller E .[J].Journal of the American Chemical Society,1938,60:309.
[102] Pozio A;Francesco M D;Cemmi A;Cardellini F Giorgi L .[J].Journal of Power Sources,2002,105:13.
[103] Gao H L;Liao S J;Zeng J H;Xie Y C Dang D .[J].Electrochimica Acta,2011,56:2024.
[104] Ohyagi S;Matsuda T;Iseki Y;Sasaki T Kaito C .[J].Journal of Power Sources,2011,196:3743.
[105] Mench M;Kumbur E C;Veziroglu T N.Polymer Electrolyte Fuel Cell Degradation[M].Oxford:Elsevier,2011:472.
[106] Bellows R J;MarucchiSoos E P;Buckley D T .[J].Industrial and Engineering Chemistry Research,1996,35:1235.
[107] Ohyagi S;Sasaki T .[J].Electrochimica Acta,2013,102:336.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%