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  4. Preyssler heteropolyacid supported on silica coated NiFe2O4 nanoparticles for the catalytic synthesis of bis(dihydropyrimidinone)benzene and 3,4-dihydropyrimidin-2(1H)-ones

催化学报 , 2015, (3): 299-307. doi: 10.1016/S1872-2067(14)60265-5

Hossein Eshghi 1, , Ali Javid 2, , Amir Khojastehnezhad 3, , Farid Moeinpour 4, , Fatemeh F. Bamoharram 5, , Mehdi Bakavoli 6, , Masoud Mirzaei 7,

1.Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad, Iran

2.Department of Chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran

3.Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad, Iran

4.Department of Chemistry, Bandar Abbas Branch, Islamic Azad University, Bandar Abbas, 7915893144, Iran

5.Department of Chemistry, College of Science, Mashhad Branch, Islamic Azad University, Mashhad, Iran

6.Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad, Iran

7.Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad, Iran

Preyssler heteropolyacid supported on silica coated NiFe2O4 nanoparticles for the catalytic synthesis of bis(dihydropyrimidinone)benzene and 3,4-dihydropyrimidin-2(1H)-ones

Keywords： Preyssler

A novel magnetic acidic catalyst comprising Preyssler (H14[NaP5W30O110]) heteropoly acid support‐ed on silica coated nickel ferrite nanoparticles (NiFe2O4@SiO2) was prepared. The catalyst was characterized by Fourier transform infrared, scanning electron microscopy, transmission electron microscopy, X‐ray diffraction, energy dispersive spectrum, VSM and particle size neasurement. Its catalytic activity was investigated for the synthesis of bis(dihydropyrimidinone)benzene and 3,4‐dihydropyrimidin‐2(1H)‐ones derivatives by the Biginelli reaction. With the catalyst, the reac‐tions occurred in less than 1 h with good to excellent yields. More importantly, the catalyst was easily separated from the reaction mixture by an external magnet and reused at least five times without degradation in the activity.

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