以简单金属前躯体为原料通过快速热解法制备炭包覆纳米金属磁性颗粒,通过透射电镜、X-射线衍射、热重-示差扫描同步热分析及振动样品磁强计等对产物形貌、结构、成分与磁性能进行表征.结果表明:采用该方法制备的炭包覆纳米金属磁性颗粒形状为近球形颗粒,粒径均一,其中炭包覆镍纳米磁性颗粒的粒径集中在10nm～30nm范围,炭包覆铁纳米磁性颗粒粒径则在50nm～60nm范围;所制炭包覆纳米金属磁性颗粒在室温下具有顺磁性,其磁性能随金属颗粒含量的变化而改变.该方法有望发展成一种工艺简单,可进行连续工业化生产炭包覆纳米金属磁性颗粒的方法.
Carbon-encapsulated iron and nickel magnetic nanoparticles (CEMNPs) were synthesized from their salt precursors using an instant pyrolysis method. The morphologies, structural features and magnetic properties of the particles were investigated by transmission electron microscopy, X-ray diffraction, simultaneous thermogravimetry-differential scanning calorimetry and vibrating sample magnetometry. It was found that almost all of the CEMNPs were spherical, and their size changed from 10 to 30nm, whereas the size of the carbon-encapsulated iron nanoparticles changed from 50 to 60nm. The magnetic properties of the products indicated that the carbon-encapsulated iron nanoparticles were paramagnetic and their properties were tunable with the iron content. The present approach is promising for large-scale production of CEMNPs.
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