对聚对苯二甲酸乙二醇酯(PET)织物进行碱性水解预处理.通过浸渍法以十二烷基硫酸钠作为分散剂在原始的和经预处理的PET中加入纳米炭黑(CB1515和CB156),纳米二氧化钛(NTO)-NCBs(CB1515或CB156)混合物.以柠檬酸(CA)和次磷酸钠(SHP)分别为交联剂和催化剂,分别在预处理前后的PETs中加入NTO+CB1515和NTO+CB156作对比研究.结果表明,CB156比CB1515更能有效地降低样品的电阻率.加入NTO后,由原始PET所制样品比预处理PET所制样品具有更低的电阻率.然而,这与不加NTO所制样品结果相反.通过增加添加量和改善NCBs和NTO在织物中的分散均匀性,采用CA和SHP可明显降低样品的电阻率.发现NCBs与NTO的协同效应可提高预处理织物的紫外吸收.由原始PET中加入NCB和NTO所制样品比预处理的PET对亚甲基蓝降解具有更高活性.通过添加NTO或CA-SHP可提高活性,前者比后者更有效.
参考文献
| [1] | Parkin IP;Palgrave RG .Self-cleaning coatings[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2005(17):1689-1695. |
| [2] | Ramaratnam K;Tsyalkovsky V;Kelp V.Ultra hydrophobic textile surface via decorating fibers with monolyer of reactive nanoparticles and Non-florinated polymer[J].Chem Coumun,2007:4510-4512. |
| [3] | Shim BS;Chen W;Doty C;Xu CL;Kotov NA .Smart Electronic Yarns and Wearable Fabrics for Human Biomonitoring made by Carbon Nanotube Coating with Polyelectrolytes[J].Nano letters,2008(12):4151-4157. |
| [4] | Wilusz E.Military textile[M].United Kingdom:Wood head Ltd,2008:284. |
| [5] | Yongsong Luo;Jinping Liu;Xiaohong Xia .Fabrication and characterization of TiO_2/short MWNTs with enhanced photocatalytic activity[J].Materials Letters,2007(11/12):2467-2472. |
| [6] | Hemming L H.Electromagnetic anechoic chambers[M].Wiley-IEEE Press,2002:32. |
| [7] | Dana Pantea;Hans Darmstadt;Serge Kaliaguine;Lydia Summchen;Christian Roy .Electrical conductivity of thermal carbon blacks Influence of surface chemistry[J].Carbon: An International Journal Sponsored by the American Carbon Society,2001(8):1147-1158. |
| [8] | Dapeng Li;Gang Sun .Coloration of textiles with self-dispersible carbon black nanoparticles[J].Dyes and Pigments,2007(26):144-149. |
| [9] | Zhang F J;Chen M L;Oh W C .Characterization of CNT/TiO2 electrode prepared through impregnation with TNB and their photo electro catalytic properties[J].Environ Eng Res,2009,14(01):32-40. |
| [10] | Wu, Deyong;Long, Mingce;Zhou, Jiangya;Cai, Weimin;Zhu, Xiehao;Chen, Chao;Wu, Yahui .Synthesis and characterization of self-cleaning cotton fabrics modified by TiO2 through a facile approach[J].Surface & Coatings Technology,2009(24):3728-3733. |
| [11] | Akira Fujishima;Xintong Zhang;Donald A. Tryk .TiO_2 photocatalysis and related surface phenomena[J].Surface Science Reports,2008(12):515-582. |
| [12] | Hu, LB;Pasta, M;La Mantia, F;Cui, LF;Jeong, S;Deshazer, HD;Choi, JW;Han, SM;Cui, Y .Stretchable, Porous, and Conductive Energy Textiles[J].Nano letters,2010(2):708-714. |
| [13] | 陈明亮,张峰君,吴沅春.CNT/TiO2复合材料的合成、表征及其光催化性能分析[J].新型炭材料,2009(02):159-166. |
| [14] | Tryba B .Increase of the Photocatalytic activity of TiO2 by carbon and iron modifications[J].International Journal of Photoenergy,2008,2008:1-15. |
| [15] | Kolosnjaj J;Szwarc H;Moussa F.Toxicity studies of carbon nanotubes.[J].Advances in Experimental Medicine and Biology,2008:181-204. |
| [16] | Alexandra E. Porter;Mhairi Gass;Karin Muller;Jeremy N. Skepper;Paul A. Midgley;Mark Welland .Direct imaging of single-walled carbon nanotubes in cells[J].Nature nanotechnology,2007(11):713-717. |
| [17] | Zumwalde R;Laura H .Approaches to safe nanotechnology:Managing the health and safety concerns associated with engineered nano materials.National institute for occupational safety and health[J].NIOSH (DHHS) Publication,2009,125:14-16. |
| [18] | Lam CW;James JT;McCluskey R;Arepalli S;Hunter RL .A review of carbon nanotube toxicity and assessment of potential occupational and environmental health risks[J].Critical reviews in toxicology,2006(3):189-217. |
| [19] | Pasta, M.;la Mantia, F.;Hu, L.;Deshazer, H.D.;Cui, Y. .Aqueous supercapacitors on conductive cotton[J].Nano Research,2010(6):452-458. |
| [20] | Mejia M I;Matin J M;Restrepo G et al.Preparation testing and performance of a TiO2/PET photo catalyst for the degradation of gaseous methanol[J].Applied Catalysis B:Environmental,2009,94:166-172. |
| [21] | Montazer M;Jolaei M M .β-Cyclodextrin stabilized on three-dimensional polyester fabric with different crosslinking agents[J].Journal of Applied Polymer Science,2010,116:210-217. |
| [22] | Montazer, M.;Ghayem Asghari, M.S.;Pakdel, E. .Electrical conductivity of single walled and multiwalled carbon nanotube containing wool fibers[J].Journal of Applied Polymer Science,2011(6):3353-3358. |
| [23] | Tatsuma T;Tachibana S;Miwa T et al.Remote bleaching of methylene blue UV-irradiated TiO2 in the gas phase[J].Journal of Physical Chemistry B,103:8033-8035. |
| [24] | Zeng J;Li R;Liu S et al.Fiber-like TiO2 nano materials with different crystallinity phases fabricated via green path way[J].Appl Mater Interfaces,2011,3(09):2074-2079. |
| [25] | Qi KH;Daoud WA;Xin JH;Mak CL;Tang WZ;Cheung WP .Self-cleaning cotton[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2006(47):4567-4574. |
| [26] | Donelli, I.;Freddi, G.;Nierstrasz, V.A.;Taddei, P. .Surface structure and properties of poly-(ethylene terephthalate) hydrolyzed by alkali and cutinase[J].Polymer Degradation and Stability,2010(9):1542-1550. |
| [27] | Hashemizad, S.;Montazer, M.;Rashidi, A. .Influence of the surface hydrolysis on the functionality of poly(ethylene terephthalate) fabric treated with nanotitanium dioxide[J].Journal of Applied Polymer Science,2012(2):1176-1184. |
| [28] | Wan-Kuen Jo;Sung-Hoon Yang;Seung-Ho Shin;Sung-Bong Yang .Degradation of Volatile Hydrocarbons Using Continuous-Flow Photocatalytic Systems with Enhanced Catalytic Surface Areas[J].Environmental engineering research,2011(2):91-96. |
| [29] | Chung DDL. .Review graphite [Review][J].Journal of Materials Science,2002(8):1475-1489. |
| [30] | Martel B;Weltrowski M .Polycarboxylic acids as crosslinking agents for grafting cyclodextrins onto cotton and wool fabrics:Study of the process parameters[J].Journal of Applied Polymer Science,2002,83(07):1449-1456. |
| [31] | Nazari A;Montazer M;Rashidi A et al.Nano TiO2 photo catalyst and sodium hypo phosphate for cross-linking cotton with poly carboxylic acids under UV and high temperature[J].Applied Catalysis A:General,2009,371:10-16. |
| [32] | Montazer, M.;Pakdel, E. .Functionality of nano titanium dioxide on textiles with future aspects: Focus on wool[J].Journal of photochemistry and photobiology, C. Photochemistry reviews,2011(4):293-303. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%