在1100~1200℃温度范围内，于炭纤维布上原位合成多壁碳纳米管。采用扫描电镜、透射电镜、拉曼光谱等手段对样品进行表征。结果表明，所制碳纳米管为多壁管，管端可见小球，生成物呈列线生长，生长方向基本垂直于基底，管壁少有杂质和缺陷，结晶度较高。反应温度、反应时间对产物的结构与形态均有一定影响。原位生成碳纳米管的数量和形态与基底的大小、形状有关，可通过调节反应温度和反应时间加以控制。
Multi-wall carbon nanotubes ( MWCNTs) were synthesized on carbon fiber cloth by chemical vapor deposition using natural gas as the carbon source and FeSO4·7H2 O powder as the catalyst precursor. Scanning and transmission electron microscopy and Raman spectroscopy were used to characterize the product. Small catalyst particles were observed on the top of the tubes. The MWCNTs were dispersed uniformly and aligned perpendicular to the cloth. They had a high crystallinity, and few impurities and de-fects. The density and structure of the MWCNTs on the cloth can be controlled by deposition temperature and time.
参考文献
| [1] | Lau K T;Hui D .The revolutionary creation of new advanced materials carbon nanotube composites[J].Composite Part B,2002,33(04):263-277. |
| [2] | Song Q;Li K Z;Li H J et al.Increasing the tensile pcroperty of unidirectional carbon/carbon composites by grafting carbon nanotubes onto carbon fibers by electrophoretic deposition[J].Journal of Materials Science &Technology,2013,29(08):711-714. |
| [3] | Valdirene Gonzaga de Resende;Erica Freire Antunes;Anderson de Oliveira Lobo .Growth of carbon nanotube forests on carbon fibers with an amorphous silicon interface[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(12):3655-3658. |
| [4] | Yun Zhao;Jingli Shi;Huiqi Wang.A sandwich structure graphite block with excellent thermal and mechanical properties reinforced by in-situ grown carbon nanotubes[J].Carbon: An International Journal Sponsored by the American Carbon Society,2013:427-430. |
| [5] | Kim JA;Seong DG;Kang TJ;Youn JR .Effects of surface modification on rheological and mechanical properties of CNT/epoxy composites[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(10):1898-1905. |
| [6] | 陈永,李成,涂进春,安立南.高分子自组装制备多壁纳米炭管[J].新型炭材料,2012(06):416-420. |
| [7] | Sun L;Warren GL;O'Reilly JY;Everett WN;Lee SM;Davis D;Lagoudas D;Sue HJ .Mechanical properties of surface-functionalized SWCNT/epoxy composites[J].Carbon: An International Journal Sponsored by the American Carbon Society,2008(2):320-328. |
| [8] | Wagner HD.;Feldman Y.;Tenne R.;Lourie O. .Stress-induced fragmentation of multiwall carbon nanotubes in a polymer matrix[J].Applied physics letters,1998(2):188-190. |
| [9] | Hisashi Kajiura;Anil Nandyala;Alexey Bezryadin .Quasi-ballistic electron transport In as-produced and annealed multiwall carbon nanotubes[J].Carbon: An International Journal Sponsored by the American Carbon Society,2005(6):1317-1319. |
| [10] | Zhang T;Amiridis M D .Hydrogen production via the direct cracking of methane over silica-supported nickel catalysts[J].Applied Catalysis A:General,1998,167(02):161-172. |
| [11] | Nishuang Liu;Guojia Fang;Wei Zeng .Enhanced field emission from three-dimensional patterned carbon nanotube arrays grown on flexible carbon cloth[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2012(8):3478-3484. |
| [12] | Namiko Yamamoto;A.John Hart;Enrique J.Garcia .High-yield growth and morphology control of aligned carbon nanotubes on ceramic fibers for multifunctional enhancement of structural composites[J].Carbon: An International Journal Sponsored by the American Carbon Society,2009(3):551-560. |
| [13] | Hui Qian;Alexander Bismarck;Emile S. Greenhalgh .Synthesis and characterisation of carbon nanotubes grown on silica fibres by injection CVD[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(1):277-286. |
| [14] | Zhang Q;Qian WZ;Xiang R;Yang Z;Luo GH;Wang Y;Wei F .In situ growth of carbon nanotubes on inorganic fibers with different surface properties[J].Materials Chemistry and Physics,2008(2/3):317-321. |
| [15] | Qiao-Juan Gong;He-Jun Li;Xiang Wang .In situ catalytic growth of carbon nanotubes on the surface of carbon cloth[J].Composites science and technology,2007(14):2986-2989. |
| [16] | 李克智,宋强,武立言,李贺军,弓巧娟.碳纳米管含量对炭炭复合材料组织及力学性能的影响[J].无机化学学报,2011(05):1001-1007. |
| [17] | Jose Maria Calderon Moreno;Masahiro Yoshimura .Hydrothermal Processing of High-Quality Multiwall Nanotubes from Amorphous Carbon[J].Journal of the American Chemical Society,2001(4):741-742. |
| [18] | Zhenhui Kang;Enbo Wang;Lei Gao;Suoyuan Lian;Min Jiang;Changwen Hu;Lin Xu .One-Step Water-Assisted Synthesis of High-Quality Carbon Nanotubes Directly from Graphite[J].Journal of the American Chemical Society,2003(45):13652-13653. |
| [19] | Monthioux M;Allouche H;Jacobsen R L .Chemical vapour deposition of pyrolytic carbon on carbon canotubes part 3:growth mechanisms[J].CARBON,2006,44(15):3183-3194. |
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