研究了降解温度、反应时间和添加剂对超临界正丙醇中炭纤维增强环氧树脂基复合材料回收的影响.利用扫描电镜、热重、X射线光电子能谱、接触角和单丝拉伸对回收炭纤维进行表征.结果表明,随温度的升高,复合材料降解速率加快,但回收炭纤维力学性能略微降低.随反应时间的延长,复合材料降解速率降低,回收炭纤维力学性能降低.1%质量含量的KOH能明显提高复合材料的回收效率.伴随KOH含量增加,复合材料降解速率没有明显提高,而使回收炭纤维力学性能变差.合适的反应条件对回收具有清洁表面、良好热稳定性和力学性能完好保留的炭纤维至关重要.回收炭纤维表面化学的微弱变化使回收炭纤维同环氧树脂的接触角略增加.超临界正丙醇是一种回收炭纤维复合材料的有效方法.
参考文献
[1] | 杨云华;潘月秀;冯志海;石松.宇航级炭纤维评价表征[J].新型炭材料,2014(3):161-168. |
[2] | 刘影;邓天昇;吕春祥;蔡榕;侯相林.氯化锌乙醇溶液回收炭纤维/环氧树脂复合材料[J].新型炭材料,2014(5):363-368. |
[3] | 刘秀影;宋英;李存梅;王福平.炭纤维表面接枝碳纳米管对复合材料界面性能的影响[J].新型炭材料,2012(6):455-461. |
[4] | Edward Lester;Sam Kingman;Kok Hoong Wong;Chris Rudd;Stephen Pickering;Nidal Hilal.Microwave heating as a means for carbon fibre recovery from polymer composites:a technical feasibility study[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,200410(10):1549-1556. |
[5] | Liu YY;Meng LH;Huang YD;Du JJ.Recycling of carbon/epoxy composites[J].Journal of Applied Polymer Science,20045(5):1912-1916. |
[6] | SJ. Pickering.Recycling technologies for thermoset composite materials-current status[J].Composites, Part A. Applied science and manufacturing,20068(8):1206-1215. |
[7] | Soraia Pimenta;Silvestre T. Pinho.Recycling carbon fibre reinforced polymers for structural applications: Technology review and market outlook[J].Waste Management,20112(2):378-392. |
[8] | J. Palmer;O.R. Ghita;L. Savage.Successful closed-loop recycling of thermoset composites[J].Composites, Part A. Applied science and manufacturing,20094(4):490-498. |
[9] | Mohamad Anas Nahil;Paul T. Williams.Recycling of carbon fibre reinforced polymeric waste for the production of activated carbon fibres[J].Journal of analytical & applied pyrolysis,20111(1):67-75. |
[10] | K.H.Wong;S.J.Pickering, CD. Rudd.Recycled carbon fibre reinforced polymer composite for electromagnetic interference shielding[J].Composites, Part A. Applied science and manufacturing,20106(6):693-702. |
[11] | Raul Pinero-Hernanz;Juan Garda-Serna;Christopher Dodds.Chemical recycling of carbon fibre composites using alcohols under subcritical and supercritical conditions[J].The Journal of Supercritical Fluids,20081(1):83-92. |
[12] | Liu Yuyan;Shan Guohua;Meng Linghui.Recycling of carbon fibre reinforced composites using water insubcritical conditions[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20091/2(1/2):179-183. |
[13] | J. Palmer;L. Savage;O.R. Ghita;K.E. Evans.Sheet moulding compound (SMC) from carbon fibre recyclate[J].Composites, Part A. Applied science and manufacturing,20109(9):1232-1237. |
[14] | T.A. Turner;S.J. Pickering;N.A. Warrior.Development of recycled carbon fibre moulding compounds - Preparation of waste composites[J].Composites, Part B. Engineering,20113(3):517-525. |
[15] | Adrian M. Cunliffe;Nicola Jones;Paul T. Williams.Recycling of fibre-reinforced polymeric waste by pyrolysis: thermo-gravimetric and bench-scale investigations[J].Journal of analytical & applied pyrolysis,20032(2):315-338. |
[16] | Jiang G;Pickering SJ;Walker GS;Bowering N;Wong KH;Rudd CD.Soft ionisation analysis of evolved gas for oxidative decomposition of an epoxy resin/carbon fibre composite[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,20072(2):109-115. |
[17] | Jiang, G;Pickering, SJ;Walker, GS;Wong, KH;Rudd, CD.Surface characterisation of carbon fibre recycled using fluidised bed[J].Applied Surface Science,20089(9):2588-2593. |
[18] | H. L. H. Yip;S. J. Pickering;C. D. Rudd.Characterisation of carbon fibres recycled from scrap composites using fluidised bed process[J].Plastics, Rubber and Composites,20026(6):278-282. |
[19] | Jason R. Hyde;Edward Lester;Sam Kingman.Supercritical propanol, a possible route to composite carbon[J].Composites, Part A. Applied science and manufacturing,200611(11):2171-2175. |
[20] | El Gersifi K;Durand G;Tersac G.Solvolysis of bisphenol A diglycidyl ether/anhydride model networks[J].Polymer Degradation and Stability,20064(4):690-702. |
[21] | Yongping Bai.Chemical recycling of carbon fibers reinforced epoxy resin composites in oxygen in supercritical water[J].Materials & design,20102(2):999-1002. |
[22] | Hua Yan;Chun-xiang Lu;De-qi Jing;Xiang-lin Hou.Chemical Degradation of Amine-cured DGEBA Epoxy Resin in Supercritical 1-Propanol for Recycling Carbon Fiber from Composites[J].高分子科学(英文版),2014(11):1550-1563. |
[23] | Hua Yan;Chunxiang Lu;Deqi Jing;Xianglin Hou.Chemical degradation of TGDDM/DDS epoxy resin in supercritical 1-propanol: Promotion effect of hydrogenation on thermolysis[J].Polymer Degradation and Stability,201312(12):2571-2582. |
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