催化生物乙醇制氢有望成为用清洁可再生能源替代化石能源的有效途径,近年来受到广泛关注.本文介绍了制氢的研究概况及燃料电池的相关应用,概括了生物乙醇制氢的优势及反应过程.重点综述了以Ce和La为代表的稀土金属在乙醇制氢反应中的催化效果,并对与制氢反应紧密相关的甲烷水蒸气变换反应、水汽变换反应、CO选择性氧化反应和黑碳氧化反应中稀土金属的催化作用进行了探讨.在综述相关研究进展的基础上为生物乙醇制氢催化剂的开发提供建议.
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