采用磁控溅射技术在石英衬底上制备出(Ge/SiO2)15多层膜,并在不同温度下对其进行退火处理.XRD和Raman结果表明:溅射态的薄膜为非晶态,当退火温度为500℃时开始出现明显的结晶衍射峰,随后晶化率明显增大,当600℃后,薄膜的晶化率几乎不变.FESEM和小角度X射线衍射结果表明:溅射态薄膜的层与层之间存在明显的界面,具有良好的周期性,升高退火温度,晶粒尺寸增大,但仍保持周期性结构.薄膜的紫外可见光吸收光谱表明:随着退火温度的升高,吸收边发生红移,光学带隙从溅射态的1.86eV减小到600℃时的1.59eV.
参考文献
[1] | 王懿喆,马小凤,周呈悦,曹萌.硅基纳米结构太阳电池研究新进展[J].功能材料与器件学报,2010(05):483-489. |
[2] | ROLVER R;BERGHOFF B;BATZNER D L et al.Lateral Si/SiO2 quantum well solar cells[J].Applied Physics Letters,2008,92(212108):1-3. |
[3] | Zheng TH;Li ZQ .The present status of Si/SiO2 superlattice research into optoelectronic applications[J].Superlattices and microstructures,2005(4):227-247. |
[4] | 何明霞,刘劲松,李子全,曹安,刘建宁,丛孟启,蒋维娜,彭洁,余乐.(Si/Ge)n多层薄膜的设计制备及光吸收性能[J].电子器件,2012(01):1-6. |
[5] | TSUTSUMI T;TOMIZAWA K;ISHII K .Fabrication technology of ultrathin SiO2 masks and Si nanowires using oxidation of vertical side walls of plotFSi layer[J].Journal of Vacuum Science and Technology B:Microelectronics and Nanometer Structures,1999,17(01):77-81. |
[6] | YOSHID T;TAKEYAMA S;YAMADARY et al.Nanometersized silicon crystallites prepared by excimer laser ablation in constant pressure inert gas[J].Applied Physics Letters,1996,68(13):1772-1774. |
[7] | SUN Y;MIYASATO T;WIGMOR J K .Self-growth of zeroon,and two-dimentional nanoscale SiC structures by oxygen-enhanced hydrogen plasma sputtering[J].Journal of Applied Physics,1999,86(06):3076-3082. |
[8] | PAVESI L;NEGRO L D;MAZZOLENI C et al.Optical gain in siliconnanocrystals[J].NATURE,2000,408(6811):440-444. |
[9] | Qin GG.;Zhang BR.;Li BC.;Li AP. .VISIBLE ELECTROLUMINESCENCE FROM SEMITRANSPARENT AU FILM EXTRA THIN SI-RICH SILICON OXIDE FILM P-SI STRUCTURE[J].Journal of Applied Physics,1995(3):2006-2009. |
[10] | G.Franzo;A.Irrera;E.C.Moreira;M.Miritello;F.Iacona;D.Sanfilippo;G.Di Stefano;P.G.Fallica;F.Priolo .Electroluminescence of silicon nanocrystals in MOS structures[J].Applied physics, A. Materials science & processing,2002(1):1-5. |
[11] | 张兴旺;陈光华 .非晶态Ge/SiO2超晶格结构与特性[J].材料研究学报,1998,12(05):512-514. |
[12] | ZHANG B;SHRESTHA S;HUANG S J et al.Structural studies of multilayered Ge nanocrystals embedded in SiO2 matrix fabricated using magnetron sputtering[J].Energy Procedia,2010,2(01):243-250. |
[13] | Characterisation of size-controlled and red luminescent Ge nanocrystals in multilayered superlattice structure[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2010(19):P.5483. |
[14] | VIEIRA E M F;MARTIN S J;ROLO A G et al.Structural and electrical studies of ultrathin layers Si0.7 Ge0.3 nanocrystals confined in a SiGe/SiO2 superlattice[J].Journal of Applied Physics,2012,111(104323):1-9. |
[15] | Shihua Huang;Hong Xiao;Sha Shou .Annealing Temperature Dependence Of Raman Scattering In Si/sio_2 Superlattice Prepared By Magnetron Sputtering[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2009(8):4547-4550. |
[16] | ABDUL F K;MAZHAR M;ANWAR M R et al.Effect of annealing on structural,optical and electrical properties of nanostructured Ge thin films[J].Applied Surface Science,2010,256(07):2031-2037. |
[17] | 余乐,刘劲松,李子全,陈建康,何明霞,彭洁,曹安,刘建宁,蒋维娜,万龙.Ge/SiO2和Ge/ZnO/SiO2薄膜的磁控溅射制备及电学性能[J].化工新型材料,2012(04):103-105. |
[18] | Houben L.;Hapke P.;Carius R.;Finger F.;Wagner H.;Luysberg M. .Structural properties of microcrystalline silicon in the transition from highly crystalline to amorphous growth[J].Philosophical Magazine.A.Physics of condensed matter, defects and mechanical properties,1998(6):1447-1460. |
[19] | 冯仕猛,赵海鹰,窦晓鸣,范正修,邵建达.多层膜周期厚度的精确计算[J].中国激光,2002(11):1027-1030. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%