RPV模拟钢样品经过890℃水淬,660℃调质处理,然后在400℃时效13000h后,用高分辨透射电镜和能谱仪相结合的方法研究了RPV模拟钢中纳米富Cu析出相中的复杂晶体结构.纳米富Cu析出相的平均尺寸约为20nm,除了观察到常见的亚稳态9R结构、3R结构和稳态fcc结构外,还观察到同一富Cu析出相由3种不同的晶体结构组成,并分别分布在5个不同的区域中,包括1处9R、2处fcc和2处3R结构.9R结构与相邻的2个fco结构形成的界面都具有特定的晶体取向,呈半共格关系,是由非孪晶9R结构演化而来.2处3R结构互为孪晶关系,是由孪晶9R结构演化而来.这种状态反映了纳米富Cu析出相从亚稳态演化到稳态结构的复杂过程.
参考文献
[1] | ZHANG Z W;LIU C T;WANG X L et al.Effects of proton irradiation on nanocluster precipitation in ferritic steel containing fee alloying additions[J].ACTA MATERIALIA,2012,60(6-7):3034-3046. |
[2] | P.D. Styman;J.M. Hyde;K. Wilford;A. Morley;G.D.W. Smith.Precipitation in long term thermally aged high copper, high nickel model RPV steel welds[J].Progress in nuclear engergy,2012:86-92. |
[3] | Lambrecht, M.;Meslin, E.;Malerba, L.;Hernández-Mayoral, M.;Bergner, F.;Pareige, P.;Radiguet, B.;Almazouzi, A. .On the correlation between irradiation-induced microstructural features and the hardening of reactor pressure vessel steels[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2010(1):84-89. |
[4] | K. Fujii;H. Nakata;K. Fukuya;T. Ohkubo;K. Hono;Y. Nagai;M. Hasegawa;T. Yoshiie .Hardening and microstructural evolution in A533B steels under neutron irradiation and a direct comparison with electron irradiation[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2010(1):46-55. |
[5] | B. Radiguet;P. Pareige;A. Barbu .Irradiation induced clustering in low copper or copper free ferritic model alloys[J].Nuclear Instruments and Methods in Physics Research, Section B. Beam Interactions with Materials and Atoms,2009(8/9):1496-1499. |
[6] | 吕铮.核反应堆压力容器的辐照脆化与延寿评估[J].金属学报,2011(07):777-783. |
[7] | Niffenegger, M;Leber, HJ .Monitoring the embrittlement of reactor pressure vessel steels by using the Seebeck coefficient[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2009(1):62-67. |
[8] | F. Bergner;M. Lambrecht;A. Ulbricht;A. Almazouzi .Comparative small-angle neutron scattering study of neutron-irradiated Fe, Fe-based alloys and a pressure vessel steel[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2010(2/3):129-136. |
[9] | B. Timofeev .Assessment of the first generation RPV state after designed lifetime[J].International Journal of Pressure Vessels and Piping,2004(8):703-712. |
[10] | Ki-Hyoung Lee;Min-Chul Kim;Bong-Sang Lee;Dang-Moon Wee .Analysis of the master curve approach on the fracture toughness properties of SA508 Gr.4N Ni–Mo–Cr low alloy steels for reactor pressure vessels[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2010(15):3329-3334. |
[11] | CAMMELLI S;DEGUELDRE C;CERVELLINO A et al.Cluster formation,evolution and size distribution in Fe-Gu alloy:Analysis by XAES XRD and TEM[J].Nucl Instrum and Methods Phys Res B,2010,268:632-837. |
[12] | Schober, M.;Eidenberger, E.;Staron, P.;Leitner, H. .Critical consideration of precipitate analysis of Fe-1 at.% Cu using atom probe and small-angle neutron scattering[J].Microscopy and microanalysis: The official journal of Microscopy Society of America, Microbeam Analysis Society, Microscopical Society of Canada,2011(1):26-33. |
[13] | Kamada, Y;Takahashi, S;Kikuchi, H;Kobayashi, S;Ara, K;Echigoya, J;Tozawa, Y;Watanabe, K .Effect of pre-deformation on the precipitation process and magnetic properties of Fe-Cu model alloys[J].Journal of Materials Science,2009(4):949-953. |
[14] | R. Prakash Kolli;David N. Seidman .The temporal evolution of the decomposition of a concentrated multicomponent Fe-Cu-based steel[J].Acta materialia,2008(9):2073-2088. |
[15] | 张植权,周邦新,蔡琳玲,王均安,刘文庆.利用APT研究RPV模拟钢中相界面原子偏聚特征[J].材料工程,2014(09):89-93. |
[16] | H.R. Habibi .Atomic structure of the Cu precipitates in two stages hardening in maraging steel[J].Materials Letters,2005(14/15):1824-1827. |
[17] | Lee TH;Kim YO;Kim SJ .Crystallographic model for bcc-to-9R martensitic transformation of Cu precipitates in ferritic steel[J].Philosophical magazine: structure and properties of condensed matter,2007(2):209-224. |
[18] | H. R. Habibi-Bajguirani;M. L. Jenkins .High-resolution electron microscopy analysis of the structure of copper precipitates in a martensitic stainless steel of type PH 15-5[J].Philosophical Magazine Letters,1996(4):155-162. |
[19] | BLACKSTOCK J;ACKLA G .Phase transitions of copper precipitates in Fe-Cu alloys[J].Philosophical Magazine A:Physics of Condensed Matter Defects and Mechanical Properties,2001,81:2127-2148. |
[20] | 蔡琳玲,徐刚,冯柳,王均安,彭剑超,周邦新.核反应堆压力容器模拟钢中纳米富Cu相的变形特征[J].上海大学学报(自然科学版),2012(03):311-316. |
[21] | OTHEN P;JENKINS M;SMITH G et al.Transmission electron microscope investigations of the structure of copper precipitates in thermally aged Fe-Cu and Fe-Cu-Ni[J].Philosophical Magazine Letters,1991,64:383-391. |
[22] | DUPARC H;DOOLE R;JENKINSM et al.A high-resolution electron microscopy study of copper precipitation in Fe-1.5 wt% Cu under electron irradiation[J].Philosophical Magazine Letters,1995,71:325-333. |
[23] | MOZEN R;JENKINS M;SUTTON A .The bcc-to-9R martensitic transformation of Cu precipitates and the relaxation process of elastic strains in an Fe-Cu alloy[J].Philosophical Magazine A:Physics of Condensed Matter Defects and Mechanical Properties,2000,80(3):711-723. |
[24] | 徐刚,楚大锋,蔡琳玲,周邦新,王伟,彭剑超.RPV模拟钢中纳米富Cu相的析出和结构演化研究[J].金属学报,2011(07):905-911. |
[25] | HEO Y;KIM B Y;KIM J;etal .Phase transformation of Cu precipitates from bcc to fcc in Fe-3Si-2Cu alloy[J].ACTA MATERIALIA,2013,61:519-528. |
[26] | OTHEN P;JENKINS M;SMITH G .High resolution electron microscopy studies of the structure of Cu-precipitates in α-Fe[J].Philosophical Magazine A:Physics of Condensed Matter Defects and Mechanical Properties,1994,70:1-24. |
[27] | Fujii, K.;Ohkubo, T.;Fukuya, K. .Effects of solute elements on irradiation hardening and microstructural evolution in low alloy steels[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2011(1/3):949-952. |
[28] | M.K. Miller;B.D. Wirth;G.R. Odette .Precipitation in neutron-irradiated Fe-Cu and Fe-Cu-Mn model alloys: a comparison of APT and SANS data[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2003(1/2):133-139. |
[29] | 安治国,任慧平,刘宗昌,王海燕.1.18Cu高纯钢等温时效时富铜相的析出行为[J].特殊钢,2006(02):20-22. |
[30] | 王伟 .反应堆压力容器模拟钢中富Cu相的析出及晶体结构演化研究[D].上海:上海大学,2011. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%