以硝酸铋、钨酸铵为起始原料,采用水热法合成介孔Bi2WO6光催化剂,借助X射线粉末衍射(XRD)、固体紫外-可见吸收光谱(UV-Vis)、电子扫描电镜(FE-SEM)和透射电镜(TEM)对催化剂的物相组成、形貌和光吸收特性进行表征,并推测三维球状介孔Bi2WO6的形成机理;研究溶液pH值和环境水体中常见无机离子对Bi2WO6光催化降解亚甲基蓝的影响.结果表明:在强酸条件下,Bi2WO6表现出更高的光催化活性;环境水体中的无机离子对亚甲基蓝的光催化降解影响显著,阳离子如Fe3+,NH4+以及阴离子如卤素离子对其光催化降解具有很强的促进作用,Cu2+和NO2-几乎无影响,而Fe2+对其则具有明显抑制作用.
参考文献
[1] | 吴祖望;杨威.21世纪20年代我国的染料工业与染料学科展望[J].染料与染色,2007(1):1-4,58. |
[2] | 赵荣祥;李秀萍;徐铸德.离子液辅助水热法合成树枝状硫化镉及光催化性能[J].材料工程,2014(2):7-12. |
[3] | 杨丽丽;都玲;于杨;张文杰.磷酸处理HZSM-5负载TiO2光催化降解活性艳红X-3B[J].材料工程,2014(9):94-99. |
[4] | Nagirnyi V.;Kirm M.;Kotlov A.;Lushchik A.;Jonsson L..Separation of excitonic and electron-hole processes in metal tungstates[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,20030(0):597-603. |
[5] | Kato H;Matsudo N;Kudo A.Photophysical and photocatalytic properties of molybdates and tungstates with a scheelite structure[J].Chemistry Letters,20049(9):1216-1217. |
[6] | WU Yan;ZHANG Shi-cheng;ZHANG Li-wu;ZHU Yong-fa.Photocatalytic Activity of Nanosized ZnWO4 Prepared by the Sol-gel Method[J].高等学校化学研究(英文版),2007(04):465-468. |
[7] | Junwang Tang;Zhigang Zou;Jinhua Ye.Photocatalytic decomposition of organic contaminants by Bi_2WO_6 under visible light irradiation[J].Catalysis Letters,20041/2(1/2):53-56. |
[8] | Chunxiao Xu;Xiao Wei;Yanmin Guo;Hanqi Wu;Zhaohui Ren;Gang Xu;Ge Shen;Gaorong Han.Surfactant-free synthesis of Bi_2WO_6 multilayered disks with visible-light-induced photocatalytic activity[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,20098(8):1687-1691. |
[9] | Yue Tian;Guomin Hua;Wei Xu.Bismuth tungstate nano/microstructures: Controllable morphologies, growth mechanism and photocatalytic properties[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,20113(3):724-730. |
[10] | S. Obregon Alfaro;A. Martinez-de la Cruz.Synthesis, characterization and visible-light photocatalytic properties of Bi2WO6 and Bi2W2O9 obtained by co-precipitation method[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,20101/2(1/2):128-133. |
[11] | Yu Huang;Zhihui Ai;Wingkei Ho.Ultrasonic Spray Pyrolysis Synthesis of Porous Bi2WO6 Microspheres and Their Visible-Light-Induced Photocatalytic Removal of NO[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201014(14):6342-6349. |
[12] | Zhang, C;Zhu, YF.Synthesis of square Bi2WO6 nanoplates as high-activity visible-light-driven photocatalysts[J].Chemistry of Materials,200513(13):3537-3545. |
[13] | Meng Shang;Wenzhong Wang;Songmei Sun.Bi2WO6 Nanocrystals with High Photocatalytic Activities under Visible Light[J].The journal of physical chemistry, C. Nanomaterials and interfaces,200828(28):10407-10411. |
[14] | Zhang LS;Wang WZ;Zhou L;Xu HL.Bi2WO6 nano- and microstructures: Shape control and associated visible-light-driven photocatalytic activities[J].Small,20079(9):1618-1625. |
[15] | Danjun Wang;Yanzhong Zhen;Ganglin Xue.Synthesis of mesoporous Bi2WO6 architectures and their gas sensitivity to ethanol[J].Journal of Materials Chemistry, C. materials for optical and electronic devices,201326(26):4153-4162. |
[16] | Danjun Wang;Ganglin Xue;Yanzhong Zhen.Monodispersed Ag nanoparticles loaded on the surface of spherical Bi2WO6 nanoarchitectures with enhanced photocatalytic activities[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201211(11):4751-4758. |
[17] | 王丹军;岳林林;郭莉;张洁;付峰;薛岗林.Fe3+掺杂三维分级纳米Bi2WO6的合成及其光催化活性增强机理[J].无机化学学报,2014(4):961-968. |
[18] | Lisha Zhang;Wenzhong Wang;Zhigang Chen.Fabrication of flower-like Bi2WO6 superstructures as high performance visible-light driven photocatalysts[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,200724(24):2526-2532. |
[19] | Dekun Ma;Shaoming Huang;Wenxiu Chen.Self-Assembled Three-Dimensional Hierarchical Umbilicate Bi2WO6 Microspheres from Nanoplates: Controlled Synthesis, Photocatalytic Activities, and Wettability[J].The journal of physical chemistry, C. Nanomaterials and interfaces,200911(11):4369-4374. |
[20] | Li YY;Liu JP;Huang XT;Li GY.Hydrothermal synthesis of Bi2WO6 uniform hierarchical microspheres[J].Crystal growth & design,20077(7):1350-1355. |
[21] | CHUNYING WANG;HAO ZHANG;FANG LI.Degradation and Mineralization of Bisphenol A by Mesoporous Bi2WO6 under Simulated Solar Light Irradiation[J].Environmental Science & Technology: ES&T,201017(17):6843-6848. |
[22] | 王丹军;李东升;郭莉;付峰;齐广才;王尧宇.球形α-Fe2O3纳米粉体的超声水解法合成与表征[J].无机化学学报,2006(7):1317-1320. |
[23] | Jia Ren;Wenzhong Wang;Songmei Sun.Enhanced photocatalytic activity of Bi2WO6 loaded with Ag nanoparticles under visible light irradiation[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,20091/2(1/2):50-55. |
[24] | 吕学钧;许宜铭;王智;赵进才;吴烨铤.Fe(Ⅲ)参与TiO2光催化降解X3B的反应机理研究[J].化学学报,2004(16):1455-1459. |
[25] | 刘祥虎 .金属离子与染料分子相互作用对染料分子催化降解的影响[D].同济大学环境科学与工程学院,2008. |
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