氧化石墨烯／壳聚糖复合材料是近几年发展的一种新型生物复合材料，具有独特的力学性能、吸附性能、电化学性能以及抗菌性能等。本文综述了近几年来氧化石墨烯／壳聚糖复合材料的研究进展，简单介绍了该复合材料的制备方法，详细阐述了该复合材料在高机械强度材料、废水处理、电化学传感器、生物医学材料等领域的应用研究，最后对氧化石墨烯／壳聚糖复合材料在低成本、大规模制备，复合材料的结构性质以及在新领域的应用等方面进行了展望。
Graphene oxide/chitosan is a new type of biocomposites which was developed in recent years ,it possesses the unique mechanical ,adsorptive ,electrochemical and antibacterial properties . The research progress of graphene oxide/chitosan composites was summarized in this paper . The preparation methods of the biocomposites were introduced briefly .Meanwhile ,the application of the biocomposites in the field of high mechanical strength of materials ,waste water treatment ,electro‐chemical sensor and biomedical materials were illustrated in details .At last ,the low cost and large scale preparation ,structure and properties of composite materials and its application in new areas of graphene oxide/chitosan biocomposites were prospected .
参考文献
| [1] | Geim AK;Novoselov KS.The rise of graphene[J].Nature materials,20073(3):183-191. |
| [2] | Robert J. Young;Ian A. Kinloch;Lei Gong;Kostya S. Novoselov.The mechanics of graphene nanocomposites: A review[J].Composites science and technology,201212(12):1459-1476. |
| [3] | Sitko, R.;Zawisza, B.;Malicka, E..Graphene as a new sorbent in analytical chemistry[J].TrAC: Trends in Analytical Chemistry,2013:33-43. |
| [4] | 杜彦;季铁正;张教强;唐婷;杨建锋;郑星卓.石墨烯/高密度聚乙烯导电复合材料的制备与表征[J].航空材料学报,2013(1):68-71. |
| [5] | CHUL CHUNG;YOUNG-KWAN KIM;DOLLY SHIN.Biomedical Applications of Grapheme and Graphene Oxide[J].Accounts of Chemical Research,201310(10):2211-2224. |
| [6] | Qiu, L.;Yang, X.;Gou, X.;Yang, W.;Ma, Z.-F.;Wallace, G.G.;Li, D..Dispersing carbon nanotubes with graphene oxide in water and synergistic effects between graphene derivatives[J].Chemistry: A European journal,201035(35):10653-10658. |
| [7] | Park, S.;Lee, K.-S.;Bozoklu, G.;Cai, W.;Nguyen, S.B.T.;Ruoff, R.S..Graphene oxide papers modified by divalent ions - Enhancing mechanical properties via chemical cross-linking[J].ACS nano,20083(3):572-578. |
| [8] | SURAJIT KONWER;RATAN BORUAH;SWAPAN K. DOLUI.Studies on Conducting Polypyrrole/Graphene Oxide Composites as Supercapacitor Electrode[J].Journal of Electronic Materials,201111(11):2248-2255. |
| [9] | Characterization and electrical properties of conductive polymer/colloidal graphite oxide nanocomposites[J].Composites science and technology,20097/8(7/8):1231-1237. |
| [10] | Prashanth, K V H;Tharanathan, R N.Chitin/chitosan: modifications and their unlimited application potential - an overview.[J].Trends in food science & technology,20073(3):117-131. |
| [11] | No HK;Park NY;Lee SH;Meyers SP.Antibacterial activity of chitosans and chitosan oligomers with different molecular weights[J].International Journal of Food Microbiology,20021/2(1/2):65-72. |
| [12] | Carlos Peniche;Waldo Arguelles-Monal;Hazel Peniche;Niuris Acosta.Chitosan: An Attractive Biocompatible Polymer for Microencapsulation[J].Macromolecular bioscience,200310(10):511-520. |
| [13] | Donglin Han;Lifeng Yan;Wufeng Chen.Preparation of chitosan/graphene oxide composite film with enhanced mechanical strength in the wet state[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,20112(2):653-658. |
| [14] | Qiuju Du;Jiankun Sun;Yanhui Li.Highly enhanced adsorption of congo red onto graphene oxide/chitosan fibers by wet-chemical etching off silica nanoparticles[J].Chemical engineering journal,2014:99-106. |
| [15] | Lim, H.N.;Huang, N.M.;Loo, C.H..Facile preparation of graphene-based chitosan films: Enhanced thermal, mechanical and antibacterial properties[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,20123(3):525-530. |
| [16] | Wang, Ying;Xia, Guangmei;Wu, Cong;Sun, Jing;Song, Rui;Huang, Wei.Porous chitosan doped with graphene oxide as highly effective adsorbent for methyl orange and amido black 10B[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,2015:686-693. |
| [17] | Liu, L.;Li, C.;Bao, C.;Jia, Q.;Xiao, P.;Liu, X.;Zhang, Q..Preparation and characterization of chitosan/graphene oxide composites for the adsorption of Au(III) and Pd(II)[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,2012:350-357. |
| [18] | Ye, Nengsheng;Xie, Yali;Shi, Pengzhi;Gao, Ting;Ma, Jichao.Synthesis of magnetite/graphene oxide/chitosan composite and its application for protein adsorption[J].Materials science & engineering, C. Materials for Biogical applications,2014:8-14. |
| [19] | Ying Wang;Xu Liu;Hongfang Wang;Guangmei Xia;Wei Huang;Rui Song.Microporous spongy chitosan monoliths doped with graphene oxide as highly effective adsorbent for methyl orange and copper nitrate (Cu(NO3_)_2) ions[J].Journal of Colloid and Interface Science,2014:243-251. |
| [20] | Eric M.Arndt;Matthew D.Gawryla;David A.Schiraldi.Elastic,low density epoxy/clay aerogel composites[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,200733(33):3525-3529. |
| [21] | Nana Zhang;Haixia Qiu;Youmiao Si.Fabrication of highly porous biodegradable monoliths strengthened by graphene oxide and their adsorption of metal ions[J].Carbon: An International Journal Sponsored by the American Carbon Society,20113(3):827-837. |
| [22] | Yong Qiang He;Na Na Zhang;Xiao Dong Wang.Adsorption of graphene oxide/chitosan porous materials for metal ions[J].中国化学快报（英文版）,2011(07):859-862. |
| [23] | Yanhui Li;Jiankun Sun;Qiuju Du.Mechanical and dye adsorption properties of graphene oxide/chitosan composite fibers prepared by wet spinning[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,2014:755-761. |
| [24] | Yongzheng Pan;Tongfei Wu;Hongqian Bao.Green fabrication of chitosan films reinforced with parallel aligned graphene oxide[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,20114(4):1908-1915. |
| [25] | Xiaoming Yang;Yingfeng Tu;Liang Li.Well-Dispersed Chitosan/Graphene Oxide Nanocomposites[J].ACS applied materials & interfaces,20106(6):1707-1713. |
| [26] | Andreea Madalina Pandele;Mariana Ionita;Livia Crica.Synthesis, characterization, and in vitro studies of graphene oxide/chitosan-polyvinyl alcohol films[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,2014:813-820. |
| [27] | Li, Xueying;Zhou, Haihui;Wu, Wenqin;Wei, Shudan;Xu, Yan;Kuang, Yafei.Studies of heavy metal ion adsorption on Chitosan/Sulfydryl-functionalized graphene oxide composites[J].Journal of Colloid and Interface Science,2015:389-397. |
| [28] | Fan, L.;Luo, C.;Sun, M.;Li, X.;Qiu, H..Highly selective adsorption of lead ions by water-dispersible magnetic chitosan/graphene oxide composites[J].Colloids and Surfaces, B. Biointerfaces,2013:523-529. |
| [29] | Li, L.;Fan, L.;Sun, M.;Qiu, H.;Li, X.;Duan, H.;Luo, C..Adsorbent for chromium removal based on graphene oxide functionalized with magnetic cyclodextrin-chitosan[J].Colloids and Surfaces, B. Biointerfaces,2013:76-83. |
| [30] | Yunqiang Chen;Libin Chen;Hua Bai.Graphene oxide-chitosan composite hydrogels as broad-spectrum adsorbents for water purification[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,20136(6):1992-2001. |
| [31] | Xiuli Niu;Wu Yang;Jie Ren;Hao Guo;Shijia Long;Jiaojiao Chen;Jinzhang Gao.Electrochemical behaviors and simultaneous determination of guanine and adenine based on graphene-ionic liquid-chitosan composite film modified glassy carbon electrode[J].Electrochimica Acta,2012:346-353. |
| [32] | 周文姝;赵波;黄晓华;杨小弟.基于石墨烯-壳聚糖修饰电极电化学测定4-壬基酚[J].分析化学,2013(5):675-680. |
| [33] | Rajabzadeh, Somayeh;Rounaghi, Gholam Hossein;Arbab-Zayar, Mohammad Hossein;Ashraf, Narges.Development of a dimethyl disulfide electrochemical sensor based on electrodeposited reduced graphene oxide-chitosan modified glassy carbon electrode[J].Electrochimica Acta,2014:543-549. |
| [34] | Shieh, Yeong-Tarng;Jiang, Huei-Fang.Graphene oxide-assisted dispersion of carbon nanotubes in sulfonated chitosan-modified electrode for selective detections of dopamine, uric acid, and ascorbic acid[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,2015:132-138. |
| [35] | Lu, W.;Luo, Y.;Chang, G.;Sun, X..Synthesis of functional SiO_2-coated graphene oxide nanosheets decorated with Ag nanoparticles for H_2O_2 and glucose detection[J].Biosensors & Bioelectronics: The International Journal for the Professional Involved with Research, Technology and Applications of Biosensers and Related Devices,201112(12):4791-4797. |
| [36] | Devi, R.;Relhan, S.;Pundir, C.S..Construction of a chitosan/polyaniline/graphene oxide nanoparticles/ polypyrrole/Au electrode for amperometric determination of urinary/plasma oxalate[J].Sensors and Actuators, B. Chemical,2013:17-26. |
| [37] | Xue Liu;Lingling Xie;Hongli Li.Electrochemical biosensor based on reduced graphene oxide and Au nanoparticles entrapped in chitosan/silica sol–gel hybrid membranes for determination of dopamine and uric acid[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,2012:158-163. |
| [38] | Tiwari, Ida;Singh, Monali;Pandey, Chandra Mouli;Sumana, Gajjala.Electrochemical geno sensor based on graphene oxide modified iron oxide-chitosan hybrid nanocomposite for pathogen detection[J].Sensors and Actuators, B. Chemical,2015:276-283. |
| [39] | 汪雪;李辉;吴敏;葛淑丽;朱妍;王清江;何品刚;方禹之.石墨烯-壳聚糖/金纳米粒子修饰电极同时测定亚硫酸根和亚硝酸根[J].分析化学,2013(8):1232-1237. |
| [40] | Hu, W.;Peng, C.;Luo, W.;Lv, M.;Li, X.;Li, D.;Huang, Q.;Fan, C..Graphene-based antibacterial paper[J].ACS nano,20107(7):4317-4323. |
| [41] | Huilan Hu;Cui Tang;Chunhua Yin.Folate conjugated trimethyl chitosan/graphene oxide nanocomplexes as potential carriers for drug and gene delivery[J].Materials Letters,2014Jun.15(Jun.15):82-85. |
| [42] | Ardeshirzadeh, Behnaz;Anaraki, Nadia Aboutalebi;Irani, Mohammad;Rad, Leila Roshanfekr;Shamshiri, Soodeh.Controlled release of doxorubicin from electrospun PEO/chitosan/graphene oxide nanocomposite nanofibrous scaffolds[J].Materials science & engineering, C. Materials for Biogical applications,2015:384-390. |
| [43] | Bao, H.;Pan, Y.;Ping, Y.;Sahoo, N.G.;Wu, T.;Li, L.;Li, J.;Gan, L.H..Chitosan-functionalized graphene oxide as a nanocarrier for drug and gene delivery[J].Small,201111(11):1569-1578. |
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