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采用中心复合设计(CCD)方法研究活化剂浓度、活化温度及时间等对甘蔗叶活性炭得率及吸附性能的影响;运用Design Expert软件建立活性炭得率和碘吸附值的预测模型,优化甘蔗叶活性炭的制备工艺;并采用FT-IR、SEM和XRD等方法对甘蔗叶及其活性炭的表面官能团、微观形貌和晶体结构进行分析.结果表明,甘蔗叶活性炭最优制备工艺:活化剂浓度为2.50%(质量分数)、活化温度为705℃、活化时间为65min,样品得率和碘吸附值分别为29.33%、987.69 mg/g,与模型预测值误差分别为7.88%、2.68%;甘蔗叶活性炭的孔径范围为735.1nm~7.16 μm,微晶层距d(002)为0.3559nm,微晶尺度La、Lc分别为0.3054 nm、0.1420 nm,表面官能团主要有羧基、酚羟基、醇羟基、胺基等.

参考文献

[1] Anna Merritt;Ramakrishnan Rajagopalan;Henry C. Foley .High performance nanoporous carbon membranes for air separation[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(6):1267-1278.
[2] AL-Othrnan Z A;Ali R;Naushad M .Hexavalent chromium removal from aqueous medium by activated carbon prepared from peanut shell:Adsorption kinetics,equilibrium and thermodynamic studies[J].CHEMICAL ENGINEERING JOURNAL,2012,184(01):238.
[3] J.N. Sahu;Jyotikusum Acharya;B.C. Meikap .Optimization of production conditions for activated carbons from Tamarind wood by zinc chloride using response surface methodology[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2010(6):1974-1982.
[4] Tonghua Wang;Suxia Tan;Changhai Liang .Preparation and characterization of activated carbon from wood via microwave-induced ZnCl2 activation[J].Carbon: An International Journal Sponsored by the American Carbon Society,2009(7):1880-1883.
[5] Liu, Qing-Song;Zheng, Tong;Wang, Peng;Guo, Liang .Preparation and characterization of activated carbon from bamboo by microwave-induced phosphoric acid activation[J].Industrial Crops and Products,2010(2):233-238.
[6] 廖钦洪,刘庆业,蒙冕武,赵永明,计晓梅,康彩艳,黄思玉.稻壳基活性炭的制备及其对亚甲基蓝吸附的研究[J].环境工程学报,2011(11):2447-2452.
[7] Liu Y;Guo Y P;Zhu Y C et al.A sustainable route for the preparation of activated carbon and silica from rice husk ash[J].Journal of Hazardous Materials,2011,186(2-3):1314.
[8] Yong Sun;Paul A. Webley .Preparation of activated carbons from corncob with large specific surface area by a variety of chemical activators and their application in gas storage[J].Chemical engineering journal,2010(3):883-892.
[9] Murat Kilic;Esin Apaydin-Varol;Ay§e E. Pütün .Adsorptive removal of phenol from aqueous solutions on activated carbon prepared from tobacco residues: Equilibrium, kinetics and thermodynamics[J].Journal of hazardous materials,2011(1/2):397-403.
[10] Wei L;Peng J H;Zhang L B et al.Investigations on carbonization processes of plain tobacco stems and H3 PO4-impregnated tobacco stems used for the preparation of activated carbons with H3PO4 activation[J].Industrial Crops and Products,2008,28(01):73.
[11] 蒙冕武,蒋治良.微波法制备甘蔗渣活性炭及表征[J].林产化学与工业,2000(03):22-26.
[12] 赵永明,蒙冕武,刘庆业,廖钦洪,计晓梅,黄颖,江恩源.甘蔗渣活性炭的制备及其活化剂的回收利用[J].材料导报,2011(06):116-119.
[13] 刘庆业,艾浩,蒙冕武,魏跃林,刘明登,邓希敏.甘蔗叶活性炭的制备[J].化工环保,2012(06):561-564.
[14] 艾浩,蒙冕武,刘庆业,魏跃林,康彩艳,黄思玉.磷酸活化甘蔗叶制备活性炭的工艺研究[J].材料导报,2013(06):112-114,127.
[15] 艾浩 .甘蔗叶活性炭的清洁制备方法、性能及其应用研究[D].桂林:广西师范大学,2013.
[16] Cullity B D.Elements of X-ray Diffraction[M].New York:Addison-Wesley,1967:99.
[17] 谢志刚,吉芳英,邱雪敏,黄鹤.柑橘皮中孔活性炭的制备及性能表征[J].功能材料,2009(04):645-649.
[18] Andre L. Cazetta;Alexandra M.M. Vargas;Eurica M. Nogami .NaOH-activated carbon of high surface area produced from coconut shell: Kinetics and equilibrium studies from the methylene blue adsorption[J].Chemical engineering journal,2011(1):117-125.
[19] 马承愚,毛宇,徐鹏飞,刘建奇,宋新山.KOH/NaOH活化法辣椒秸秆制备高表面积活性炭与表征[J].功能材料,2013(05):704-708.
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