综述了锂硫电池硫/导电聚合物正极材料的研究进展.重点探讨了导电聚合物在硫基正极材料改性中的制备方法、结构设计,并对其中存在的问题进行了分析.最后对硫/导电聚合物正极材料的进一步发展及商业化应用进行了展望.
参考文献
[1] | Yan, Y.;Yin, Y.-X.;Xin, S.;Guo, Y.-G.;Wan, L.-J. .Ionothermal synthesis of sulfur-doped porous carbons hybridized with graphene as superior anode materials for lithium-ion batteries[J].Chemical communications,2012(86):10663-10665. |
[2] | Zhang S M;Zhang Q;Huang J Q et al.Composite cathodes containing SWCNT@S coaxial nanocables:Facile synthesis,surface modification,and enhanced performance for Li-ion storage[J].PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION,2013,30(02):158. |
[3] | Zhan Lin;Zengcai Liu;Wujun Fu;Nancy J. Dudney;Chengdu Liang .Phosphorous Pentasulfide as a Novel Additive for High-Performance Lithium-Sulfur Batteries[J].Advanced functional materials,2013(8):1064-1069. |
[4] | Yang, Y.;Zheng, G.;Misra, S.;Nelson, J.;Toney, M.F.;Cui, Y. .High-capacity micrometer-sized Li _2S particles as cathode materials for advanced rechargeable lithium-ion batteries[J].Journal of the American Chemical Society,2012(37):15387-15394. |
[5] | Jusef Hassoun;Bruno Scrosati .A High-Performance Polymer Tin Sulfur Lithium Ion Battery[J].Angewandte Chemie,2010(13):2371-2374. |
[6] | Zhou, G.;Yin, L.-C.;Wang, D.-W.;Li, L.;Pei, S.;Gentle, I.R.;Li, F.;Cheng, H.-M. .Fibrous hybrid of graphene and sulfur nanocrystals for high-performance lithium-sulfur batteries[J].ACS nano,2013(6):5367-5375. |
[7] | Zhang Y;Wang L Z;Zhang A Q et al.Novel V2O5/S composite cathode material for the advanced secondary lithium batteries[J].Solid State Ionicis,2010,181(17):835. |
[8] | Su, Y.-S.;Manthiram, A. .A new approach to improve cycle performance of rechargeable lithium-sulfur batteries by inserting a free-standing MWCNT interlayer[J].Chemical communications,2011(70):8817-8819. |
[9] | Xiao Liang;Zhaoyin Wen;Yu Liu;Hao Zhang;Lezhi Huang;Jun Jin .Highly dispersed sulfur in ordered mesoporous carbon sphere as a composite cathode for rechargeable polymer Li/S battery[J].Journal of Power Sources,2011(7):3655-3658. |
[10] | Xiangpeng Fang;Xianwei Guo;Ya Mao;Chunxiu Hua;Lanyao Shen;Yongsheng Hu;Zhaoxiang Wang;Feng Wu;Liquan Chen .Mechanism of Lithium Storage in MoS_(2) and the Feasibility of Using Li_(2)S/Mo Nanocomposites as Cathode Materials for Lithium-Sulfur Batteries[J].Chemistry, an Asian journal,2012(5):1013-1017. |
[11] | Ji, L.;Rao, M.;Zheng, H.;Zhang, L.;Li, Y.;Duan, W.;Guo, J.;Cairns, E.J.;Zhang, Y. .Graphene oxide as a sulfur immobilizer in high performance lithium/sulfur cells[J].Journal of the American Chemical Society,2011(46):18522-18525. |
[12] | Zheng, G.;Zhang, Q.;Cha, J.J.;Yang, Y.;Li, W.;Seh, Z.W.;Cui, Y. .Amphiphilic surface modification of hollow carbon nanofibers for improved cycle life of lithium sulfur batteries[J].Nano letters,2013(3):1265-1270. |
[13] | Nagao M;Imade Y;Narisawa H et al.All-solid-state Li-sulfur batteries with mesoporous electrode and thio-LISICON solid electrolyte[J].Journal of Power Sources,2013,222:237. |
[14] | Huang, J.-Q.;Liu, X.-F.;Zhang, Q.;Chen, C.-M.;Zhao, M.-Q.;Zhang, S.-M.;Zhu, W.;Qian, W.-Z.;Wei, F. .Entrapment of sulfur in hierarchical porous graphene for lithium-sulfur batteries with high rate performance from -40 to 60°C[J].Nano Energy,2013(2):314-321. |
[15] | Wang J L;Yao Z D;Monroe C W et al.Carbonyl@cyclodextrin as a novel binder for sulfur composite cathodes in rechargeable lithium batteries[J].Advanced Functional Materials,2013,10:1. |
[16] | Wang, H.;Yang, Y.;Liang, Y.;Robinson, J.T.;Li, Y.;Jackson, A.;Cui, Y.;Dai, H. .Graphene-wrapped sulfur particles as a rechargeable lithium-sulfur battery cathode material with high capacity and cycling stability[J].Nano letters,2011(7):2644-2647. |
[17] | Ran Elazari;Gregory Salitra;Arnd Carsuch;Alexander Panchenko;Doron Aurbach .Sulfur-Impregnated Activated Carbon Fiber Cloth as a Binder-Free Cathode for Rechargeable Li-S Batteries[J].Advanced Materials,2011(47):5641-5644. |
[18] | Kim J;Lee D J;Jung H G et al.An advanced lithium-sulfur battery[J].Advanced Functional Materials,2013,23(80):1076. |
[19] | Wang Y X;Chou S L;Liu H K et al.The electrochemical properties of high-capacity sulfur/reduced graphene oxide with different electrolyte systems[J].Journal of Power Sources,2013,244:240. |
[20] | Chaofeng Zhang;Hao Bin Wu;Changzhou Yuan .Confining Sulfur in Double-Shelled Hollow Carbon Spheres for Lithium-Sulfur Batteries[J].Angewandte Chemie,2012(38):9592-9595. |
[21] | Da-Wei Wang;Guangmin Zhou;Feng Li .A microporous-mesoporous carbon with graphitic structure for a high-rate stable sulfur cathode in carbonate solvent-based Li-S batteries[J].Physical chemistry chemical physics: PCCP,2012(24):8703-8710. |
[22] | Yuan Yang;Guangyuan Zheng;Yi Cui .Nanostructured sulfur cathodes[J].Chemical Society Reviews,2013(7):3018-3032. |
[23] | Xiulei Ji;Linda F. Nazar .Advances in Li-S batteries[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2010(44):9821-9826. |
[24] | Seh Z W;Li W Y;Cha J J et al.Sulphur-TiO2 yolk-shell nanoarchitecture with internal void space for long-cycle lithiumsulphur batteries[J].Nat Commun,2013,4:1331. |
[25] | Chong Wang;Jia-jia Chen;Yi-ning Shi;Ming-sen Zheng;Quan-feng Dong .Preparation and performance of a core-shell carbon/sulfur material for lithium/sulfur battery[J].Electrochimica Acta,2010(23):7010-7015. |
[26] | Xin, S.;Gu, L.;Zhao, N.-H.;Yin, Y.-X.;Zhou, L.-J.;Guo, Y.-G.;Wan, L.-J. .Smaller sulfur molecules promise better lithium'sulfur batteries[J].Journal of the American Chemical Society,2012(45):18510-18513. |
[27] | Guangmin Zhou;Da-Wei Wang;Feng Li;Peng-Xiang Hou;Lichang Yin;Chang Liu;Gao Qing (Max) Lu;Ian R. Gentle;Hui-Ming Cheng .A flexible nanostructured sulphur-carbon nanotube cathode with high rate performance for Li-S batteries[J].Energy & environmental science: EES,2012(10):8901-8906. |
[28] | Zheng, G.;Yang, Y.;Cha, J.J.;Hong, S.S.;Cui, Y. .Hollow carbon nanofiber-encapsulated sulfur cathodes for high specific capacity rechargeable lithium batteries[J].Nano letters,2011(10):4462-4467. |
[29] | 黎文路,蒲薇华,何向明,任建国,王莉,姜长印,万春荣.锂离子电池正极材料硫化聚丙烯腈的研究进展[J].化工新型材料,2008(10):28-30. |
[30] | 何向明,蒲薇华,王久林,姜长印,万春荣.硫化聚合物锂离子电池正极材料的研究进展[J].功能高分子学报,2005(03):517-521. |
[31] | Li Wang;Xiangming He;Jianjun Li .Analysis of the synthesis process of sulphur-poly(acrylonitrile)-based cathode materials for lithium batteries[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2012(41):22077-22081. |
[32] | 赵海鹏,何向明,姜长印,万春荣,李江伟.聚丙烯腈的热解特性及在锂离子电池中的应用[J].高分子材料科学与工程,2007(06):11-15. |
[33] | 于黄中,陈明光,贝承训,黄河.导电聚苯胺的特性,应用及进展[J].高分子材料科学与工程,2003(04):18-21,26. |
[34] | 胡宗倩,谢凯.锂硫电池硫正极材料研究现状与展望[J].材料导报,2011(17):46-50. |
[35] | 刘丹丹,宁平,夏林.导电聚苯胺的研究进展及应用开发前景[J].合成材料老化与应用,2004(03):43-47. |
[36] | Li G C;Li G R;Ye S H et al.A polyaniline-coated sulfur/carbon composite with an enhanced high-rate capability as a cathode material for lithium/sulfur batteries[J].Adv Energy Mater,2012,2(10):1238. |
[37] | Zhang Y G;Bakenov Z;Zhao Y et al.One-step synthesis of branched sulfur/polypyrrole nanocomposite cathode for lithium rechargeable batteries[J].Journal of Power Sources,2012,208:1. |
[38] | 马萍,张宝宏,徐宇虹,巩桂英.聚苯胺包覆对提高单质硫正极材料的性能研究[J].现代化工,2007(03):30-33. |
[39] | Zhao X H;Kim J K;Ahn H J et al.A ternary sulfur polyaniline carbon composite as cathode material for lithium sulfur batteries[J].Electrochimica Acta,2013,109:145. |
[40] | 蔡本慧,曹雷,王肇君.导电聚合物聚吡咯的制备、性质及其应用[J].化工科技市场,2010(05):11-16. |
[41] | Zhang XT;Zhang J;Song WH;Liu ZF .Controllable synthesis of conducting polypyrrole nanostructures[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2006(3):1158-1165. |
[42] | Nam L D;Mah G;Zhao Y et al.Binding mechanism of sulfur and dehydrogenated polyacrylonitrile in sulfur polymer composite cathode[J].Journal of Power Sources,2013,241:61. |
[43] | Yongguang Zhang;Yan Zhao;Aishuak Konarov;Denise Gosselink;Hayden Greentree Soboleski;P. Chen .A novel nano-sulfur/polypyrrole/graphene nanocomposite cathode with a dual-layered structure for lithium rechargeable batteries[J].Journal of Power Sources,2013(Nov.1):517-521. |
[44] | Zhou, W.;Yu, Y.;Chen, H.;Disalvo, F.J.;Abru?a, H.D. .Yolk-shell structure of polyaniline-coated sulfur for lithium-sulfur batteries[J].Journal of the American Chemical Society,2013(44):16736-16743. |
[45] | Linlin Qiu;Shichao Zhang;Lan Zhang;Mingming Sun;Weikun Wang .Preparation and enhanced electrochemical properties of nano-sulfur/poly(pyrrole-co-aniline) cathode material for lithium/sulfur batteries[J].Electrochimica Acta,2010(15):4632-4636. |
[46] | Duo Li;Fei Han;Shuai Wang .High Sulfur Loading Cathodes Fabricated Using Peapodlike, Large Pore Volume Mesoporous Carbon for Lithium-Sulfur Battery[J].ACS applied materials & interfaces,2013(6):2208-2213. |
[47] | Yongzhu Fu;Arumugam Manthiram .Orthorhombic Bipyramidal Sulfur Coated with Polypyrrole Nanolayers As a Cathode Material for Lithium-Sulfur Batteries[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2012(16):8910-8915. |
[48] | Wang C;Wan W;Chen J T et al.Dual core-shell structured sulfur cathode composite synthesized by one-pot route for lithium sulfur battery[J].J Mater Chem A,2013,1(05):1716. |
[49] | Liang, X.;Wen, Z.;Liu, Y.;Wang, X.;Zhang, H.;Huang, M.W.L. .Preparation and characterization of sulfur-polypyrrole composites with controlled morphology as high capacity cathode for lithium batteries[J].Solid state ionics,2011(1):347-350. |
[50] | Liang X;Liu Y;Wen Z Y et al.A nano-structured and highly ordered polypyrrole-sulfur cathode for lithium-sulfur batteries[J].Journal of Power Sources,2010,196(16):6951. |
[51] | Guo, J.;Yang, Z.;Yu, Y.;Abru?a, H.D.;Archer, L.A. .Lithium-sulfur battery cathode enabled by lithium-nitrile interaction[J].Journal of the American Chemical Society,2013(2):763-767. |
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