表面自由能是材料表面能量状态的一种描述，对材料的诸多性能有很大的影响。用于表面自由能计算的方法主要包括：Fowkes 法、Owens-Wendt-Kaelble 法、van Oss 法以及 Wu 法等，每种方法都有其特点和计算形式。目前，表面自由能的计算方法多数是基于 Young 方程推导而来，其中的基本物理量接触角θ是表征自由能的一个重要指标。对于接触角θ的测量，同样存在多种方式，如量角法、量高法以及测力法等。从表面自由能计算方法出发，系统地总结了表面自由能对材料结合强度、润湿性能及其他性能的影响，综述了国内外学者对材料表面自由能的研究现状。最后对表面自由能未来的研究方向提出了展望。
Surface free energy is a represent of the materials′energy states,for the properties of materials there is a great influence.The ways of calculation for the surface free energy include Fowkesequation,Owens-Wendt-Kael-bleequation,van Oss equation and Wu equation.Each method has its features and forms.At present,the evaluated methods of the surface free energy are based on the Young equation.The contact angleθ is an important physical quantity.For the contact angleθ,there are also many ways to measure.For example,it can be evaluated by angle-measurement method,height-measurement method or force-measurement method.Started with the aspect of calcula-tion methods,the effects of surface free energy on the materials′adhesive strength,wetting character and other prop-erties are summarized systematically,and the research progress of surface free energy of material is summarized.Fi-nally,the research direction of surface free energy is put forward.
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