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采用共沉淀法制备Mn-Al双金属氢氧化物吸附剂,优化了合成条件,并利用扫描电子显微镜(Scanning electron microscope,SEM)及能谱分析仪(Energy dispersive spectrometer,EDS)、X射线衍射仪(X-ray diffraction,XRD)、热重分析仪(Thermogravimetric analyzer,TGA)、比表面积分析仪(Brunauer-Emmett-Teller surface area,BET)等对吸附材料进行表征探讨.研究结果表明pH值和共存离子等因素对Mn-Al双金属氢氧化物吸附剂除氟效能有一定的影响,在pH为6时,达到最大吸附容量,为44.15 mg·g-1,氯离子和硝酸根离子能够提高吸附剂除氟效率,磷酸根离子与氟离子有一定的竞争吸附.

参考文献

[1] Ikuo Abe;Satoshi Iwasaki;Toshimitsu Tokimoto;Naohito Kawasaki;Takeo Nakamura;Seiki Tanada .Adsorption of fluoride ions onto carbonaceous materials[J].Journal of Colloid and Interface Science,2004(1):35-39.
[2] 赵梦华,霍亚坤,丁文明,黄霞.铁-镧复合氧化物颗粒吸附剂除氟特性的研究[J].北京化工大学学报(自然科学版),2012(06):90-94.
[3] 孙殿军,高彦辉.我国地方性氟中毒防治研究进展与展望[J].中华地方病学杂志,2013(02):119-120.
[4] Amit Bhatnagar;Eva Kumar;Mika Sillanpaa .Fluoride removal from water by adsorption—A review[J].Chemical engineering journal,2011(3):811-840.
[5] 边艳芳,李响.饮用水除氟技术研究现状与新进展[J].天津建设科技,2013(05):79-80.
[6] Luo F;Inoue K .The removal of fluoride ion by using metal (Ⅲ)-Loaded amberlite resins[J].Sol Extra Ion Exch,2004,22(02):305.
[7] Viswanathan N;Meenakshi S .Role of metal ion incorporation in ion exchange resin on the selectivity of fluoride[J].Journal of Hazardous Materials,2009,162(2-3):920.
[8] Sehn P .Fluoride removal with extra low energy reverse osmosis membranes:Three years of large scale field experience in finland[J].DESALINATION,2008,223(1-3):73.
[9] Mohapatra, M;Anand, S;Mishra, BK;Giles, DE;Singh, P .Review of fluoride removal from drinking water[J].Journal of Environmental Management,2009(1):67-77.
[10] Elazhar F;Tahaikt M;Zouahri A et al.Defluoridation of moroccan groundwater by nanofiltration and electrodialysis:Performances and cost comparison[J].World Appl Sci J,2013,22(06):844.
[11] 孟范平,李永富,周游,杜秀萍.EGDE交联的载镧壳聚糖微球对氟离子的静态和动态吸附[J].化工学报,2011(11):3192-3200.
[12] Wu X M;Zhang Y;Dou X M et al.Fluoride adsorption on an Fe-Al-Ce trimetal hydrous oxide:Characterization of adsorption sites and adsorbed fluorine complex species[J].CHEMICAL ENGINEERING JOURNAL,2013,223:364.
[13] Ma W;Lv T F;Song X Y et al.Characteristics of selective fluoride adsorption by biocarbon-Mg/Al layered double hydroxides composites from protein solutions:Kinetics and equilibrium isotherms study[J].Journal of Hazardous Materials,2014,268(15):166.
[14] 成娅,周家斌,王磊,张忠,刘艳丽.焙烧态锂铝水滑石对水中氟离子吸附性能研究[J].环境污染与防治,2012(02):34-38.
[15] Nahum A.Medellin-Castillo;Roberto Leyva-Ramos;Raul Ocampo-Perez .Adsorption of Fluoride from Water Solution on Bone Char[J].Industrial & Engineering Chemistry Research,2007(26):9205-9212.
[16] López Valdivieso A;Reyes Bahena J L;Song S et al.Temperature effect on the zeta potential and fluoride adsorption at the α-Al2O3/aqueous solution interface[J].Journal of Colloid and Interface Science,2006,298(01):1.
[17] Sujana M G;Anand S .Fluoride removal studies from contaminated ground water by using bauxite[J].Desalin,2011,267(2-3):222.
[18] Tor A .Removal of fluoride from an aqueous solution by using montmorillonite[J].DESALINATION,2006,201(1-3):267.
[19] Meenakshi S;Sundaram C S;Sukumar R .Enhanced fluoride sorption by mechano-chemically activated kaolinites[J].Journal of Hazardous Materials,2008,153(1-2):164.
[20] 李腾,魏妍,朱迟,杨娇艳,赵良元,王鸣涛,杨劭.新型饮用水除氟材料Bio-F除氟机制研究[J].环境化学,2010(04):705-709.
[21] S.V.Ramanaiah;S.Venkata Mohan;P.N.Sarma .Adsorptive removal of fluoride from aqueous phase using waste fungus (Pleurotus ostreatus 1804) biosorbent:Kinetics evaluation[J].Ecological engineering: The Journal of Ecotechnology,2007(1):47-56.
[22] Venkata Mohan S;Ramanaiah S V;Rajkumar B et al.Biosorption of fluoride from aqueous phase onto algal Spirogyra IO1 and evaluation of adsorption kinetics[J].Bioresour Techn,2007,98(05):1006.
[23] 许兆杰,张雅君.农村及偏远地区饮用水除氟研究[J].北京建筑工程学院学报,2006(02):33-37.
[24] Liu H;Deng S B;Li Z et al.Preparation of Al-Ce hybrid adsorbcnt and its application for defluoridation of drinking water[J].Journal of Hazardous Materials,2010,179(1-3):424.
[25] Deng S B;Liu H;Zhou W et al.Mn-Ce oxide as a high-capacity adsorbent for fluoride removal from water[J].Journal of Hazardous Materials,2011,186(2-3):1360.
[26] Biswas K;Gupta K;Ghosh U C .Adsorption of fluoride by hydrous iron (Ⅲ)-tin (Ⅳ) bimetal mixed oxide from the aqueous solutions[J].CHEMICAL ENGINEERING JOURNAL,2009,149(1-3):196.
[27] Zhao B;Zhang Y;Dou X et al.Granulation of Fe-Al-Ce trimetal hydroxide as a fluoride adsorbent using the extrusion method[J].CHEMICAL ENGINEERING JOURNAL,2012,185-186:211.
[28] Biswas K;Bandhoyapadhyay D;Ghosh U .Adsorption kinetics of fluoride on iron (Ⅲ)-zirconium (Ⅳ) hybrid oxide[J].ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY,2007,13(01):83.
[29] Wu X;Zhang Y;Dou X;Yang M .Fluoride removal performance of a novel Fe-Al-Ce trimetal oxide adsorbent[J].Chemosphere: Environmental toxicology and risk assessment,2007(11):1758-1764.
[30] 肖益鸿,李桂平,郑瑛,蔡国辉,魏可镁.ZrO_2-Al_2O_3复合氧化物的合成及其性能研究[J].无机化学学报,2010(01):61-66.
[31] 杨通在,罗顺忠,许云书.氮吸附法表征多孔材料的孔结构[J].炭素,2006(01):17-22.
[32] Shihabudheen M. Maliyekkal;Atul Kumar Sharma;Ligy Philip .Manganese-oxide-coated alumina: A promising sorbent for defluoridation of water[J].Water research: A journal of the international water association,2006(19):3497-3506.
[33] Chang, Q.;Zhu, L.;Luo, Z.;Lei, M.;Zhang, S.;Tang, H. .Sono-assisted preparation of magnetic magnesium-aluminum layered double hydroxides and their application for removing fluoride[J].Ultrasonics sonochemistry,2011(2):553-561.
[34] Chen, N.;Zhang, Z.;Feng, C.;Sugiura, N.;Li, M.;Chen, R. .Fluoride removal from water by granular ceramic adsorption[J].Journal of Colloid and Interface Science,2010(2):579-584.
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