欢迎登录材料期刊网

材料期刊网

高级检索

最近实现建筑幕墙的自清洁已经受到了人们的极大关注.首先使用Ti(SO4)2作为原料,采用H2O2解胶法在回流条件下合成了具有光催化活性的TiO2中性光触媒溶胶.同时将TiO2溶胶在玻璃纤维增强水泥基材料(GRC)表面涂覆成膜,研究了其光催化降解罗丹明B的能力.通过实验证明:制备的二氧化钛水溶胶光触媒活性组分TiO2的粒径仅为几纳米且分布均匀,溶胶的稳定性很好,长时间存放后不会沉淀.合成的纳米二氧化钛水溶胶呈中性,可以很好地涂覆于GRC表面,并且在紫外光下具有较好的光催化能力和自清洁性能.

参考文献

[1] Legrini O;Oliveros E;Braun A M .Photochemical processes for water treatment[J].CHEMICAL REVIEWS,1993,93(2):671.
[2] Michael R. Hoffmann;Scot T. Martin;Wonyong Choi;Detlef W. Bahnemann .Environmental Applications of Semiconductor Photocatalysis[J].Chemical Reviews,1995(1):69-96.
[3] Wang R.;Fujishima A.;Chikuni M.;Kojima E.;Kitamura A. Shimohigoshi M.;Watanabe T.;Hashimoto K. .Photogeneration of highly amphiphilic TiO2 surfaces[J].Advanced Materials,1998(2):135-13+.
[4] Amy L. Linsebigler;Guangquan Lu;John T. Yates Jr. .Photocatalysis on TiO_2 Surfaces: Principles, Mechanisms, and Selected Results[J].Chemical Reviews,1995(3):735-758.
[5] 杨贞妮;赵宗彦;辛官增 等.可见光诱导纳米TiO2超亲水薄膜的研究进展[J].材料导报,2007,21(专辑Ⅸ):57.
[6] Clemens Burda;Xiaobo Chen;Radha Narayanan;Mostafa A.EI-Sayed .Chemistry and Properties of Nanocrystals of Different Shapes[J].Chemical Reviews,2005(4):1025-1102.
[7] Ichinose H;Katsuki H .Photocatalytic activities of coating films prepared from peroxotitanic acid solution-derived anatase sols[J].Journal of the Ceramic Society of Japan,1998,106(3):344.
[8] Lee C K;Kim D K;Lee J H et al.Preparation and characterization of peroxo titanic acid solution using TiCl3[J].Journal of Sol-Gel Science and Technology,2004,31:67.
[9] Gao YF.;Masuda Y.;Peng ZF.;Yonezawa T.;Koumoto K. .Room temperature deposition of a TiO2 thin film from aqueous peroxotitanate solution[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2003(3):608-613.
[10] 罗仲宽;宋力昕;李明 .水性溶胶制备TiO2薄膜及其亲水性研究[J].元机材料学报,2004,19(6):1397.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%