聚甲基三氟丙基硅氧烷合成的研究进展

材料导报, 2015, 29(5): 73-77. doi: 10.11896/j.issn.1005-023X.2015.05.012

聚甲基三氟丙基硅氧烷合成的研究进展

张国栋 ^1, , 邬继荣 ^2, , 胡应乾 ^3, , 厉嘉云 ^4, , 来国桥 ^5, , 钟明强 ^6,

1.浙江工业大学化学工程与材料学院,杭州310014;杭州师范大学有机硅化学及材料技术教育部重点实验室,杭州310012

2.杭州师范大学有机硅化学及材料技术教育部重点实验室,杭州,310012

3.杭州师范大学有机硅化学及材料技术教育部重点实验室,杭州,310012

4.杭州师范大学有机硅化学及材料技术教育部重点实验室,杭州,310012

5.浙江工业大学化学工程与材料学院,杭州310014;杭州师范大学有机硅化学及材料技术教育部重点实验室,杭州310012

6.浙江工业大学化学工程与材料学院,杭州,310014

基金项目: 国家自然科学基金(21274131,21203049) 浙江省钱江人才计划项目(2009R10021)

关键词：氟硅聚合物 , 阴离子聚合 , 开环聚合 , 聚合机理 , 聚甲基三氟丙基硅氧烷

Research Progress on the Synthesis of Poly[methyl(trifluoropropyl)siloxane]

Keywords： fluorosilicone polymer , anionic polymerization , ring-opening polymerization , polymerization mechanism , poly[methyl(trifluoropropyl) siloxane]

聚甲基三氟丙基硅氧烷(PMTFPS)可通过1,3,5-三甲基-1,3,5-三(3 ',3',3'-三氟丙基)环三硅氧烷(D3F)的阴离子开环聚合制备.归纳总结了PMTFPS合成方法的最新研究进展,主要从聚合机理、工艺条件的研究进行了总结与分析;并对合成方法目前存在的问题和发展方向进行了展望.

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材料期刊网

聚甲基三氟丙基硅氧烷合成的研究进展

Research Progress on the Synthesis of Poly[methyl(trifluoropropyl)siloxane]

参考文献