以pb2+作为模板,环氧氯丙烷作为交联剂,MWNTs-CO/PEI作为功能单体,制备Pb2+-IIp材料.采用红外光谱和TEM对产物进行了表征.探讨了初始浓度、溶液pH值、吸附剂质量对吸附容量的影响.通过静态吸附实验研究Pb2+-IIP和Pb2+-NIP材料吸附实验的影响因素.结果表明,当吸附溶液的pH=5.0,吸附剂质量为0.03 g,pb2+的初始质量浓度为45 mg/L时,Pb2+-IIP的最大吸附量为37.50 mg/g,是Pb2+-NIP的2.47倍,40 min内即可达到吸附平衡,吸附速率较快,选择识别性好,重复使用率高.
参考文献
[1] | DHAenC .Environmental health risk assessment:Guidelines for assessing human health risks from environmental hazards[R].Department of Health and Aging and enHealth Council Canberra:ACT,2012. |
[2] | Hu X;Zhang Y;Ding Z H et al.Bioaccessibility and health risk of arsenic and heavy metals (Cd,Co,Cr,Cu,Ni,Pb,Zn and Mn) in TSP and PM2.5 in Nanjing,China[J].Atmospheric Environment,2012,57:146. |
[3] | 刘小桃 .几种新的用于环境污染修复处理与检测技术的研究[D].湖南大学,2009. |
[4] | 小宫山真;竹内俊之;务川高志.分子印迹学-从基础到应用[M].北京:科学出版社,2006 |
[5] | Tsukagoshi K;Yu K Y;Maeda M et al.Metal ionselective adsorbent prepared by surfaceimprinting polymerization[J].Bul l Chem Soc Japan,1993,66(01):114. |
[6] | Synthesis of core-shell magnetic molecular imprinted polymer by the surface RAFT polymerization for the fast and selective removal of endocrine disrupting chemicals from aqueous solutions[J].Environmental Pollution,2010(6):p.2317. |
[7] | Giorgio Ceoling;Fernando Navarro-Villoslada;Maria C. Moreno-Bondi .Accelerated Development Procedure for Molecularly Imprinted Polymers Using Membrane Filterplates[J].Journal of combinatorial chemistry,2009(4):645-652. |
[8] | Zhang, MS;Huang, JR;Yu, P;Chen, X .Preparation and characteristics of protein molecularly imprinted membranes on the surface of multiwalled carbon nanotubes[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,2010(1/2):162-166. |
[9] | Chi Wenhao;Shi Heguang;Shi Wang et al.4-Nitrophenol surface molecularly imprinted polymers based on multiwalled carbon nanotubes for the elimination of paraoxon pollution[J].Journal of Hazardous Materials,2012,227:243. |
[10] | 刘曦,张华斌,冷香,杨潇,张朝晖,聂利华.多壁碳纳米管表面大黄素印迹材料制备及吸附性能研究[J].化学通报,2012(01):51-57. |
[11] | 孙建民,于丽青,孙汉文.重金属废水处理技术进展[J].河北大学学报(自然科学版),2004(04):438-443. |
[12] | 安富强 .新型表面分子印迹技术的建立及其在环境保护中的应用研究[D].中北大学,2009. |
[13] | Lee, E;Park, DW;Lee, JO;Kim, DS;Lee, BH;Kim, BS.Molecularly imprinted polymers immobilized on carbon nanotube[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2008:202-206. |
[14] | Kan XW;Zhao Y;Geng ZR;Wang ZL;Zhu JJ .Composites of multiwalled carbon nanotubes and molecularly imprinted polymers for dopamine recognition[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(13):4849-4854. |
[15] | 李路娟,刘慧君,张磊.铅(Ⅱ)离子印迹聚合物的制备及其吸附性能的研究[J].化学通报(印刷版),2011(06):539-544. |
[16] | 范荣玉,郑细鸣.铅(Ⅱ)离子印迹复合膜对重金属离子的吸附热力学与吸附动力学[J].化工学报,2013(05):1651-1659. |
[17] | 李艳,康永锋,吴文惠,段吴平,康俊霞,谢晶.硅胶表面铜离子印迹聚合物的制备和性能研究[J].化学研究与应用,2012(06):873-878. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%