高温质子交换膜能解决传统燃料电池电极催化剂CO中毒、复杂的水热管理等问题,成为当今燃料电池发展研究的焦点.结合质子交换膜的结构与性能之间的关系,分析了分子结构设计对膜性能的重要影响,总结了接枝型、复合型质子交换膜、新型耐热交换膜的研究现状.对有机/无机粒子复合膜材料,磷酸掺杂聚苯并咪唑(PBI)、聚芳硫醚砜(PASS)等类型膜材料进行了评述,为高温质子交换膜的研究指明了方向.
参考文献
[1] | 贺高红;焉晓明;吴雪梅;胡正文;杜立广.燃料电池非氟质子交换膜的研究进展[J].膜科学与技术,2011(3):140-144,155. |
[2] | Gebel G.;Lambard J..SMALL-ANGLE SCATTERING STUDY OF WATER-SWOLLEN PERFLUORINATED IONOMER MEMBRANES[J].Macromolecules,199725(25):7914-7920. |
[3] | Kobayashi T.;Sanui K.;Ogata N.;Rikukawa M..Proton-conducting polymers derived from poly(ether-etherketone) and poly(4-phenoxybenzoyl-1,4-phenylene)[J].Solid state ionics,19983/4(3/4):219-225. |
[4] | Sankir M;Bhanu VA;Harrison WL;Ghassemi H;Wiles KB;Glass TE;Brink AE;Brink MH;McGrath JE.Synthesis and characterization of 3,3 '-disulfonated-4,4 '-dichlorodiphenyl sulfone (SDCDPS) monomer for proton exchange membranes (PEM) in fuel cell applications[J].Journal of Applied Polymer Science,20066(6):4595-4602. |
[5] | Yan Yin;Yoshiki Suto;Takaaki Sakabe;Shouwen Chen;Shunsuke Hayashi.Water Stability of Sulfonated Polyimide Membranes[J].Macromolecules,20063(3):1189-1198. |
[6] | Jinhui Pang;Haibo Zhang;Xuefeng Li.Novel Wholly Aromatic Sulfonated Poly(arylene ether) Copolymers Containing Sulfonic Acid Groups on the Pendants for Proton Exchange Membrane Materials[J].Macromolecules,200726(26):9435-9442. |
[7] | A review on water balance in the membrane electrode assembly of proton exchange membrane fuel cells[J].International journal of hydrogen energy,200923(23):9461. |
[8] | Erik van de Ven;Anisa Chairuna;Geraldine Merle;Sergio Pacheco Benito;Zandrie Borneman;Kitty Nijmeijer.Ionic liquid doped polybenzimidazole membranes for high temperature Proton Exchange Membrane fuel cell applications[J].Journal of Power Sources,2013Jan.15(Jan.15):202-209. |
[9] | Ko, Taeyun;Kim, Kihyun;Kim, Sung-Kon;Lee, Jong-Chan.Organic/inorganic composite membranes comprising of sulfonated Poly(arylene ether sulfone) and core-shell silica particles having acidic and basic polymer shells[J].Polymer: The International Journal for the Science and Technology of Polymers,2015:70-81. |
[10] | Saswata Bose;Tapas Kuila;Thi Xuan Hien Nguyen.Polymer membranes for high temperature proton exchange membrane fuel cell: Recent advances and challenges[J].Progress in Polymer Science,20116(6):813-843. |
[11] | Dong Won Shin;Na Rae Kang;Kang Hyuck Lee;Doo Hee Cho;Ji Hoon Kim;Won Hyo Lee;Young Moo Lee.Proton conducting, composite sulfonated polymer membrane for medium temperature and low relative humidity fuel cells[J].Journal of Power Sources,2014Sep.15(Sep.15):162-168. |
[12] | Jay Pandey;Anupam Shukla.PVDF supported silica immobilized phosphotungstic acid membrane for DMFC application[J].Solid state ionics,2014:811-814. |
[13] | Jean-Michel Thomassin;Christophe Pagnoulle;Giuseppe Caldarella;Albert Germain;Robert Jerome.Contribution of nanoclays to the barrier properties of a model proton exchange membrane for fuel cell application[J].Journal of Membrane Science,20061/2(1/2):50-56. |
[14] | Bai ZW;Durstock MF;Dang TD.Proton conductivity and properties of sulfonated polyarylenethioether sulfones as proton exchange membranes in fuel cells[J].Journal of Membrane Science,20061/2(1/2):508-516. |
[15] | Zongwu Bai;Marlene D. Houtz;Peter A. Mirau.Structures and properties of highly sulfonated poly(arylenethioethersulfone)s as proton exchange membranes[J].Polymer: The International Journal for the Science and Technology of Polymers,200722(22):6598-6604. |
[16] | Yoonessi, M;Dang, TD;Heinz, H;Wheeler, R;Bai, ZW.Investigation of nanostructures and properties of sulfonated poly(arylenethioethersulfone) copolymer as proton conducting materials by small angle neutron scattering[J].Polymer: The International Journal for the Science and Technology of Polymers,20107(7):1585-1592. |
[17] | Jong-Heon Seol;Ji-Hye Won;Kyung-Suk Yoon;Young Taik Hong;Sang-Young Lee.SiO_2 ceramic nanoporous substrate-reinforced sulfonated poly(arylene ether sulfone) composite membranes for proton exchange membrane fuel cells[J].International journal of hydrogen energy,20127(7):6189-6198. |
[18] | Zhenyu Liu;Jesse S. Wainright;Morton H. Litt;Robert F. Savinell.Study of the oxygen reduction reaction (ORR) at Pt interfaced with phosphoric acid doped polybenzimidazole at elevated temperature and low relative humidity[J].Electrochimica Acta,200619(19):3914-3923. |
[19] | Qingfeng Li;Jens Oluf Jensen;Robert F. Savinell.High temperature proton exchange membranes based on polybenzimidazoles for fuel cells[J].Progress in Polymer Science,20095(5):449-477. |
[20] | David Aili;Lars N. Cleemann;Qingfeng Li.Thermal curing of PBI membranes for high temperature PEM fuel cells[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201212(12):5444-5453. |
[21] | David Aili;Qingfeng Li;Erik Christensen.Crosslinking of polybenzimidazole membranes by divinylsulfone post-treatment for high-temperature proton exchange membrane fuel cell applications[J].Polymer international,20118(8):1201-1207. |
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